Temporal behaviour of artificial small-scale ionospheric irregularities: Review of experimental results

Features of artificial small-scale ionospheric irregularities (ASI) induced at F-region heights by powerful HF waves are discussed. The investigations presented here were performed during the past two decades at the Zimenki and Sura heating facilities, located at middle latitudes near Nizhniy Novgorod, Russia, as well as at the Gissar facility located at a lower latitude near Dushanbe, Tadzhikistan. The measurements were made by a variety of diagnostic methods employing artificial field-aligned scattering of HF and VHF radio waves, sounding of the disturbed region by means of low-power probing waves and testing of the artificial turbulence by means of stimulated electromagnetic emission (SEE). The dependence of ASI on such parameters as transverse scale length of the artificial irregularities, their location in the disturbed region, the power of the heating wave, the duration of HF radiation, geophysical conditions, aftereffects of the preceding modification, and the schedule of heater operation is considered for both the development stage after pump turn-on and the decay stage after pump turn-off. The temporal evolution of ASI spectral characteristics during the heater period is discussed. An empirical model for the ASI, based on the data available, was elaborated and verified by computer simulation of SEE generation.     

Temporal evolution of HF-excited plasma waves, measured at different pump frequencies by stimulated electromagnetic emission (SEE)

Experimental results concerning the growth and decay times of different spectral components of stimulated electromagnetic emission (SEE) are presented. A new method of measurement, employing a special pulsed pump scheme for the ionospheric plasma modification, has been elaborated and applied for studying HF-induced processes with high time resolution. The measurements performed show that the development and relaxation of different SEE features have an intricate pattern which depends on the emission frequency shift from the pump frequency, on the proximity of the pump frequency to the gyroharmonic frequencies, on the intensity of artificial ionospheric turbulence, and on the ionospheric conditions. The scope of this method for studies of HF plasma turbulence is discussed.     

Qualitätsanforderungen an Oberflächengewässer: Zielvorgaben,Qualitätsziele und chemische Gewässergüteklassifizierung

Quality Requirements for Fresh Waters: Water Quality Targets, Water Quality Objectives, and Chemical Water Quality Classification In the Federal Republic of Germany, water quality requirements for the protection of inland surface waters against hazardous substances are formulated on the basis of a quality targets derivation concept developed jointly by the Federal Government and the Federal States. The quality requirements were termed “water quality targets” in order to make it clear that the values derived are orientational values rather than legally binding limit values. The international comparison of quality requirements for surface waters shows that, on the whole, the national quality targets ensure a high level of protection. According to present scientific knowledge, impairments of uses, such as supply of drinking water, or risks to aquatic communities need not to be expected if the quality targets are complied with. A comparison of water quality data with the water quality targets makes it possible, on the one hand, to identify those substances whose inputs must be further reduced; on the other hand, it also shows that, for a number of substances, there is no need at present for concern over their adversely water quality. A further differentiation of the aquatic hazard potential of pollutants allows a water quality classification system to be developed on the basis of the quality targets derivation concept. The basic elements of this water quality classification system are presented, and its application is explained by way of examples.     

Untersuchung der Sorptionseigenschaften des Kationenaustauschers KB-2M mit Makronetzstruktur zur Abtrennung von Zinkionen aus Ab- und Spülwässern

Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn²⁺-ions from sewage and rinsing water.     

Remote sensing detection of atmospheric pollutants by differential absorption LIDAR 510M/SODAR PA2 mobile system

Summary Air pollution problem in the Czech Republic is very complex due to large number of factors as turbulent dispersion and chemical reactions concurring in the status of the PBL. For this 3D distribution of pollutants is a key information that cannot be given by conventional monitoring stations. Combined use of DIAL lidar and sodar can give access to such information. Case studies of air pollutants transport are presented using 3D concentration fields of NO₂ and ozone measured by lidar and meteorological conditions monitored by Doppler Sodar.     

Radiative Exchange in an Urban Street Canyon

The influence of building geometry on the radiation terms ofthe surface energy balance is a principal reason for surfacetemperature differences between rural and urban areas.Methods exist to calculate the radiation balance in an urban area,but their validity across the range of urban geometries andmaterials has not been carefully considered.Here the exchange of diffuse radiation in an urban street canyon isinvestigated using a method incorporating all reflections of radiation.This exact solution is compared to two commonly used approximationsthat retain either no reflections, or just one reflection of radiation.The area-averaged net radiative flux density from the facets of the canyondecreases in magnitude monotonically as the canyon aspect ratio increases.The two approximate solutions possess unphysical differences from thismonotonic decrease for high canyon aspect ratios or low materialemissivities/high material albedos.The errors of the two approximate solutions are small for near blackbodymaterials and small canyon aspect ratios but can be an order ofmagnitude for intermediate material properties and deep street canyons.Urban street canyon models need to consider at least one reflectionof radiation and multiple reflections are desirable for full applicability.     

Long-range propagation and scattering of low-frequency sound pulses in the middle atmosphere

Summary A short historical review and an analysis of the current status of both theoretical and experimental studies of long-range sound propagation in the atmosphere are given. Basic results are given on the atmospheric fine-layered structure that significantly affects the infrasonic pulse propagation and scattering in the lower and middle atmosphere. The effect of time variations (seasonal changes, tides, and both planetary and internal gravity waves) in the effective acoustic speed profile on the characteristics of infrasonic signals from different pulsed sources is discussed. The results of the studies of partial reflection (scattering) of low-frequency acoustic pulses from the fine-layered inhomogeneities of the middle atmosphere are presented. The results of the corresponding theoretical studies are also given. The potentialities of the method of long-range acoustic sounding of large-scale anisotropic turbulence in the middle atmosphere are discussed. The problems of infrasonic monitoring of nuclear low-energy explosions are also considered.     

A Simple Parameterisation for Flux Footprint Predictions

Flux footprint functions estimate the location and relative importance of passive scalar sources influencing flux measurements at a given receptor height. These footprint estimates strongly vary in size, depending on receptor height, atmospheric stability, and surface roughness. Reliable footprint calculations from, e.g., Lagrangian stochastic models or large-eddy simulations are computationally expensive and cannot readily be computed for long-term observational programs. To facilitate more accessible footprint estimates, a scaling procedure is introduced for flux footprint functions over a range of stratifications from convective to stable, and receptor heights ranging from near the surface to the middle of the boundary layer. It is shown that, when applying this scaling procedure, footprint estimates collapse to an ensemble of similar curves. A simple parameterisation for the scaled footprint estimates is presented. This parameterisation accounts for the influence of the roughness length on the footprint and allows for a quick but precise algebraic footprint estimation.