Ultrafiltration by a compacted clay membrane—II. Sodium ion exclusion at various ionic strengths

Several recent laboratory studies and field investigations have indicated that shales and compacted clay minerals behave as semipermeable membranes. One of the properties of semipermeable membranes is to retard or prevent the passage of charged ionic species through the membrane pores while allowing relatively free movement of uncharged species. This phenomenon is termed salt filtering, reverse osmosis, or ultrafiltration.This paper shows how one can proceed from the ion exchange capacity of clay minerals and, by means of Donnan membrane equilibrium concept and the Teorell-Meyer-Siever theory, develop a theory to explain why and to what extent ultrafiltration occurs when solutions of known concentration are forced to flow through a clay membrane. Reasonable agreement between theory and laboratory results were found. The concentration of the ultrafiltrate was always greater than predicted because of uncertainty in values of some parameters in the equations.Ultrafiltration phenomena may be responsible for the formation of some subsurface brines and mineral deposits. The effect should also be taken into consideration in any proposal for subsurface waste emplacement in an environment containing large quantities of clay minerals.     

Theory of radio occultation by Saturn's rings

The radio occultation technique is developed here as a new method for the study of the physical properties of planetary ring systems. Particular reference is made to geometrical and system characteristics of the Voyager dual-wavelength (13 and 3.6 cm) experiment at Saturn. The rings are studied based on the perturbations they introduce in the spectrum of coherent sinusoidal radio signals transmitted through the rings from a spacecraft in the vicinity of the planet to Earth. Two separate signal components are identified in a perturbed spectrum: a sinusoidal component that remains coherent with the incident signal but is reduced in intensity and possibly changed in phase, and a Doppler-broadened incoherent component whose spectral shape and strength are determined by the occultation geometry and the radial variation of the near-forward radar cross section of illuminated ringlets. Both components are derived in terms of the physical ring properties starting from a conventional radar formulation of the problem of single scattering on ensembles of discrete scatterers, which is then generalized to include near-forward multiple scattering. The latter is accomplished through special solutions of the equation of transfer for particles that are larger than the wavelength. When the occultation geometry is optimized, contributions of an individual ringlet to a perturbed spectrum can be identified with radial resolution on the order of a few kilometers for the coherent component and a few hundred kilometers for the incoherent one, thus permitting high-resolution reconstruction of the radial profile of the optical depth, as well as reconstruction of the radar cross section of resolved ringlets. Simultaneous estimates of the optical depth and radar cross section of a ringlet at 3.6 cm-gl allow separation of its aerial density and particle size, if the particles are of known material and form a narrow size distibution with radii greater than several tens of centimeters. This separation is also achieved for radii ?10 cm from differential effects on the coherent signal parameters at 3.6- and 13-cm wavelengths. For the more general case of a broad size distribution modeled by a power law, the absence of differential effects on the coherent signal binds the minimum size to be ?10 cm. In this case, the radius inferred from an estimate of the radar cross section represents an equivalent radius, which is strongly controlled by the maximum size of the distribution provided that the power index is in the range 3 to 4. On the other hand, detection of differential coherent signal extinction determines an upper bound on the maximum size and a lower bound on the power index, assuming water-ice particles. These bounds, together with an inferred equivalent size, constrain the size distribution at both its small and large ends.     

Zur Tektonik des Gebietes westlich des Königssees/Berchtesgadener Alpen

Facies and tectonic features have been analyzed in the area between Berchtesgaden and Funtensee (to the west of the Königssee) by use of modern methods (e.g. terrestrial photogrammetry, lineament analysis) and conventional geologic field work. Basing on the presentation of different examples, a model of the tectonic evolution is described consisting of six phases. They describe tectonical events from older Cimmerian to recent. It is shown that the manifold stress systems often reactivate older structures, a fact, which complicates the tectonik work significantly. Special emphasize is put to a strike-slip-fault system in 110° pointing to the recent principal stress component (140°) in the Northern Calcareous Alps.     

Modeling Situation Factors Used in MCE Procedures for Raster GIS

Multi‐criteria evaluation (MCE) procedures are widely used in raster‐based geographic information systems (GIS) to perform a variety of land use siting applications. Many of the criteria used in an MCE analysis are based on spatial relationships or situation characteristics. Situation factors measure the accessibility that each raster cell is to resources or land uses that generate spatial externalities for the activity being sited. This accessibility can be measured either in terms of distance to the nearest target cell containing resources or the overall level of resource availability as measured by a spatial interaction model. This paper examines the spatial structure of these situation factors to identify the set of critical target cells for which distance estimates are most sensitive. Critical target cells are especially important in the case of positive externalities in which an activity would be inclined to locate near these cells to use or consume the resources there. Critical target cells are useful for evaluating the utility of the final site selection with respect to resource/activity ratios.     

Temporal and Spatial Variabilities of Chemical and Physical Parameters on the Heron Island Coral Reef Platform

Globally, coral reefs are threatened by ocean warming and acidification. The degree to which acidification will impact reefs is dependent on the local hydrodynamics, benthic community composition, and biogeochemical processes, all of which vary on different temporal and spatial scales. Characterizing the natural spatiotemporal variability of seawater carbonate chemistry across different reefs is critical for elucidating future impacts on coral reefs. To date, most studies have focused on select habitats, whereas fewer studies have focused on reef scale variability. Here, we investigate the temporal and spatial seawater physicochemical variability across the entire Heron Island coral reef platform, Great Barrier Reef, Australia, for a limited duration of six days. Autonomous sensor measurements at three sites across the platform were complemented by reef-wide boat surveys and discrete sampling of seawater carbonate chemistry during the morning and evening. Variability in both temporal and spatial physicochemical properties were predominantly driven by solar irradiance (and its effect on biological activity) and the semidiurnal tidal cycles but were influenced by the local geomorphology resulting in isolation of the platform during low tide and rapid flooding during rising tides. As a result, seawater from previous tidal cycles was sometimes trapped in different parts of the reef leading to unexpected biogeochemical trends in space and time. This study illustrates the differences and limitations of data obtained from high-frequency measurements in a few locations compared to low-frequency measurements at high spatial resolution and coverage, showing the need for a combined approach to develop predictive capability of seawater physicochemical properties on coral reefs.

     

Evaporation from three water bodies of different sizes and climates: Measurements and scaling analysis

Evaporation from small reservoirs, wetlands, and lakes continues to be a theoretical and practical problem in surface hydrology and micrometeorology because atmospheric flows above such systems can rarely be approximated as stationary and planar-homogeneous with no mean subsidence (hereafter referred to as idealized flow state). Here, the turbulence statistics of temperature (T) and water vapor (q) most pertinent to lake evaporation measurements over three water bodies differing in climate, thermal inertia and degree of advective conditions are explored. The three systems included Lac Léman in Switzerland (high thermal inertia, near homogeneous conditions with no appreciable advection due to long upwind fetch), Eshkol reservoir in Israel (intermediate thermal inertia, frequent strong advective conditions) and Tilopozo wetland in Chile (low thermal inertia, frequent but moderate advection). The data analysis focused on how similarity constants for the flux-variance approach, C_T/C_q, and relative transport efficiencies R_wT/R_wq, are perturbed from unity with increased advection or the active role of temperature. When advection is small and thermal inertia is large, C_T/C_q < 1 (or R_wT/R_wq > 1) primarily due to the active role of temperature, which is consistent with a large number of studies conducted over bare soil and vegetated surfaces. However, when advection is significantly large, then C_T/C_q > 1 (orR_wT/R_wq < 1). When advection is moderate and thermal inertia is low, then C_T/C_q ∼ 1. This latter equality, while consistent with Monin–Obukhov similarity theory (MOST), is due to the fact that advection tends to increase C_T/C_q above unity while the active role of temperature tends to decrease C_T/C_q below unity. A simplified scaling analysis derived from the scalar variance budget equation, explained qualitatively how advection could perturb MOST scaling (assumed to represent the idealized flow state).     

Secondary Hydrogeologic Regions of the Conterminous United States

The U.S. Geological Survey (USGS) previously identified and mapped 62 Principal Aquifers (PAs) in the U.S., with 57 located in the conterminous states. Areas outside of PAs, which account for about 40% of the conterminous U.S., were collectively identified as “other rocks.” This paper, for the first time, subdivides this large area into internally-consistent features, defined here as Secondary Hydrogeologic Regions (SHRs). SHRs are areas of other rock within which the rocks or deposits are of comparable age, lithology, geologic or physiographic setting, and relationship to the presence or absence of underling PAs or overlying glacial deposits. A total of 69 SHRs were identified. The number and size of SHRs identified in this paper are comparable to the number and size of PAs previously identified by the USGS. From a two-dimensional perspective, SHRs are complementary to PAs, mapped only where the PAs were not identified on the USGS PA map and not mapped where the PAs were identified. SHRs generally consist of low permeability rocks or deposits, but can include locally productive aquifers. The two maps, taken together, provide a comprehensive, national-scale hydrogeologic framework for assessing and understanding groundwater systems.     

Normal modes and resonance in Ontario Lacus: a hydrocarbon lake of Titan

Ocean Dynamics - The natural modes of Ontario Lacus surface oscillations, the largest lake in Titan’s southern hemisphere, are simulated and analyzed as they are potentially of broad interest...