Mantle dynamics and mantle melting beneath Niuafo’ou Island and the northern Lau back-arc basin

A suite of young volcanic basaltic lavas erupted on the intra-plate island of Niuafo’ou and at active rifts and spreading centres (the King’s Triple Junction and the Northeastern Lau Spreading Centre) in the northern Lau Basin is used to examine the pattern of mantle flow and the dynamics of melting beneath this complex back-arc system. All lavas contain variable amounts of a subduction related component inherited from the Tonga subduction zone to the east. All lavas have higher ⁸⁷Sr/⁸⁶Sr, lower ¹⁴³Nd/¹⁴⁴Nd and more radiogenic Pb isotope compositions than basalts erupted at the Central Lau Spreading Centre in the central Lau Basin, and are interpreted as variable mixtures of subduction-modified, depleted upper mantle, and mantle residues derived from melting beneath the Samoan Islands which has leaked through a tear in the subducting Pacific Plate beneath the Vitiaz Lineament at the northern edge of the Lau Basin. Our data can be used to map out the present-day distribution of Samoan mantle in this region, and show that it influences the compositions of lavas erupted as far as 400 km from the Samoan Islands. The distribution of Samoan-influenced lavas implies south- and southwest-wards mantle flow rates of >4 cm/year. U-series disequilibria in historic Niuafo’ou lavas have average (²³⁰Th/²³⁸U) = 1.13, (²³¹Pa/²³⁵U) = 2.17, (²²⁶Ra/²³⁰Th) = 2.11, and together with major and trace element data require ∼5% partial melting of mantle at between 2 and 3 GPa, with a residual porosity of 0.002 and an upwelling rate of 1 cm year⁻¹. We suggest that intraplate magmatism in the northern Lau Basin results from decompression melting during southward flow of mantle from beneath old (110–120 Ma), relatively thick Pacific oceanic lithosphere to beneath young (<5 Ma), thinner oceanic lithosphere beneath the northern Lau Basin.     

Book Reviews

The UK Hydrographic Office (UKHO)-sponsored Vertical Offshore Reference Frames (VORF) project aims to develop tidal level transformation models that are referenced to the GRS80 ellipsoid and thus compatible with GNSS positioning; in particular, heighting. Benefits include increasing the efficiency of hydrographic surveying, providing a stable consistent reference frame and enabling integration with land data in the coastal zone. Seven contemporary global ocean tide models are used to derive Lowest Astronomical Tide (LAT) surfaces which are each assessed by comparison with LAT values from the 7,389-strong UKHO tide gauge database, with the results correlated with distance from land. The proportion of truly offshore and pelagic gauges is relatively limited; however, the transition zone whereby the global ocean tide models commence to deteriorate in accuracy is evident at approximately 30km from the coast. The DTU10 model was selected as the strongest candidate overall. Subsequently, a thin plate spline method is used with the tide gauge dataset to enhance the DTU10 LAT surface in the coastal zone, creating a high resolution global LAT surface with respect to mean sea level. It is seen by cross-validation that the method may be used to predict LAT in near-shore locations with a standard error of 0.23 m.     

Diagenetic magnetization of the Caerfai Bay Shales (Cambrian), South Wales

Summary. The Lower Cambrian Caerfai Bay Shales in Dyfed, South Wales, are marine red beds which have been reddened by the diagenetic alteration of volcanic detritus. The pole position of their dominant component of magnetization coincides with those from Lower Ordovician igneous rocks in Great Britain. There is also a subordinate antiparallel component, and some indication of magnetization spanning the folding of the strata, implying a relatively slow acquisition of CRM in a predominantly reversed field. This is consistent with our observation that the magnetization of these marine beds is carried by authigenic haematite.     

A hydrochemical approach to quantify the role of return flow in a surface flow‐dominated catchment

Stormflow generation in headwater catchments dominated by subsurface flow has been studied extensively, yet catchments dominated by surface flow have received less attention. We addressed this by testing whether stormflow chemistry is controlled by either (a) the event‐water signature of overland flow, or (b) the pre‐event water signature of return flow. We used a high‐resolution hydrochemical data set of stormflow and end‐members of multiple storms in an end‐member mixing analysis to determine the number of end‐members needed to explain stormflow, characterize and identify potential end‐members, calculate their contributions to stormflow, and develop a conceptual model of stormflow. The arrangement and relative positioning of end‐members in stormflow mixing space suggest that saturation excess overland flow (26–48%) and return flow from two different subsurface storage pools (17–53%) are both similarly important for stormflow. These results suggest that pipes and fractures are important flow paths to rapidly release stored water and highlight the value of within‐event resolution hydrochemical data to assess the full range and dynamics of flow paths.     

A softer look at MCG–6-30-15 with XMM–Newton

We present the analysis and first results from the Reflection Grating Spectrometer (RGS) during the 320-ks XMM–Newton observation of the Seyfert 1 galaxy MCG–6-30-15. The spectrum is marked by a sharp drop in flux at 0.7 keV which has been interpreted by Branduardi-Raymont et al. using RGS spectra from an earlier and shorter observation as the blue wing of a strong relativistic O  viii emission line and by Lee et al. using a Chandra spectrum as due to a dusty warm absorber. We find that the drop is well explained by the Fe  i L_2,3 absorption edges and obtain reasonable fits over the 0.32–1.7 keV band using a multizone, dusty warm absorber model constructed using the photoionization code cloudy . Some residuals remain which could be due to emission from a relativistic disc, but at a much weaker level than from any simple model relying on relativistic emission lines alone. A model based on such emission lines can be made to fit if sufficient (warm) absorption is added, although the line strengths exceed those expected. In order to distinguish further whether the spectral shape is dominated by absorption or emission, we examined the difference spectrum between the highest and lowest flux states of the source. The EPIC pn data indicate that this is a power law in the 3–10 keV band which, if extrapolated to lower energies, reveals the absorption function acting on the intrinsic spectrum, provided that any emission lines do not scale exactly with the continuum. We find that this function matches our dusty warm absorber model well if the power law steepens below 2 keV. The soft X-ray spectrum is therefore dominated by absorption structures, with the equivalent width of any individual emission lines in the residuals being below approximately 30 eV.     

Trace metals in harbour and slipway sediments from the island of Malta, central Mediterranean

Sediment samples collected from large harbours and public slipways on the island of Malta have been analysed for geochemically important metals (Al, Ca, Fe, Mn) and contaminant metals (As, Cd, Co, Cr, Cu, Ni, Pb, Sn, Zn) following fractionation (<63 μm) and digestion in aqua regia. Absolute and Al-normalised concentrations of contaminant metals exhibited relatively little dispersion both among different samples from the same location and between samples from different locations, notable exceptions including lower concentrations of Cr and Sn on the slipways than in the harbours. Sources of contaminant metals are attributed to diffuse and specific waste inputs from urban surroundings and boating and shipping activities. Overall, concentrations are similar to those reported for other large harbours in urban settings where equivalent sample fractionation-digestion has been performed. Relative to various sediment quality guidelines, Pb is predicted to exert the greatest threat to the marine environment of Malta.     

Integral Field Spectroscopy with Gemini: Support for IFU data in the Gemini IRAF package

We present a brief overview of facilities for Integral Field Spectroscopy at the Gemini Observatory. These include four optical and near-infrared IFUs suitable for high spatial resolution work and a suite of tasks for handling IFU data in the Gemini IRAF package. We describe the tools for data reduction that are available now or planned in the near future, helping investigators make productive use of these ground-breaking instruments. Further details on the individual IFUs, specific science applications and reduction examples are given in associated presentations by Beck et al., Carrasco et al., Trancho et al. and Winge et al.     

Bioaccessibility and mobilisation of copper and zinc in estuarine sediment contaminated by antifouling paint particles

Clean estuarine sediment amended with antifouling paint particles has been digested in biologically relevant reagents in order to evaluate the bioaccessibilities of Cu and Zn to deposit feeders in coastal environments where boat maintenance is important. Concentrations of Cu and Zn in the estuarine sediment of about 20 and 70 μg g⁻¹, respectively, increased to about 930 and 330 μg g⁻¹, respectively, on addition of 1.3% of a composite of fractionated paint particles collected from a boat repair facility. Seawater containing the vertebrate bile salt, sodium taurocholate, representative of surfactants in the digestive environment of deposit feeders, mobilised significantly greater quantities of metal (up to about 2 μg g⁻¹ of both Cu and Zn) than seawater alone, presumably through complexation and exchange reactions. Seawater solutions of the protein, bovine serum albumin (BSA), a surrogate for proteinaceous material and amino acids encountered in the digestive tract, mobilised even greater quantities of metal (up to about 80 and 40 μg g⁻¹ of Cu and Zn, respectively) via strong complexation, although addition of taurocholate reduced this capacity through interactions between the two reagents. Overall, and through feeding, burrowing and bioirrigation, infaunal invertebrates are predicted to greatly accelerate the rate of mobilisation and local dispersal of metals in sediment contaminated by antifouling paint particles.