Sequentially sampled gas hydrate water,coupled with pore water and bottom water isotopic and ionic signatures at the Kukuy mud volcano,Lake Baikal: ambiguous deep-rooted source of hydrate-forming water

The isotopic and ionic composition of pure gas hydrate (GH) water was examined for GHs recovered in three gravity cores (165–193 cm length) from the Kukuy K-9 mud volcano (MV) in Lake Baikal. A massive GH sample from core St6GC4 (143–165 cm core depth interval) was dissociated progressively over 6 h in a closed glass chamber, and 11 sequentially collected fractions of dissociated GH water analyzed. Their hydrogen and oxygen isotopic compositions, and the concentrations of Cl^– and HCO₃ ^– remained essentially constant over time, except that the fraction collected during the first 50 minutes deviated partly from this pattern. Fraction #1 had a substantially higher Cl^– concentration, similar to that of pore water sampled immediately above (135–142 cm core depth) the main GH-bearing interval in that core. Like the subsequent fractions, however, the HCO₃ ^– concentration was markedly lower than that of pore water. For the GH water fractions #2 to #11, an essentially constant HCO₃ ^–/Cl^– ratio of 305 differed markedly from downcore pore water HCO₃ ^–/Cl^– ratios of 63–99. Evidently, contamination of the extracted GH water by ambient pore water probably adhered to the massive GH sample was satisfactorily restricted to the initial phase of GH dissociation. The hydrogen and oxygen isotopic composition of hydrate-forming water was estimated using the measured isotopic composition of extracted GH water combined with known isotopic fractionation factors between GH and GH-forming water. Estimated δD of ?126 to ?133‰ and δ¹⁸O of ?15.7 to ?16.7‰ differed partly from the corresponding signatures of ambient pore water (δD of ?123‰, δ¹⁸O of ?15.6‰) and of lake bottom water (δD of ?121‰, δ¹⁸O of ?15.8‰) at the St6GC4 coring site, suggesting that the GH was not formed from those waters. Observations of breccias in that core point to a possible deep-rooted water source, consistent with published thermal measurements for the neighboring Kukuy K-2 MV. By contrast, the pore waters of core St6GC4 and also of the neighboring cores GC2 and GC3 from the Kukuy K-9 MV show neither isotopic nor ionic evidence of such a source (e.g., elevated sulfate concentration). These findings constrain GH formation to earlier times, but a deep-rooted source of hydrate-forming water remains ambiguous. A possible long-term dampening of key deep-water source signatures deserves further attention, notably in terms of diffusion and/or advection, as well as anaerobic oxidation of methane.     

The effect of health benefits on climate change mitigation policies

This paper studies the interplay between climate, health, and the economy in a stylized world with eleven heterogeneous regions, with special emphasis on USA, Europe, China, India, and Africa. We introduce health impacts into a simple economic integrated assessment model where both the local cooling effect of SO ₂ and the global warming effect of CO ₂ are endogenous, and investigate how these factors affect the equilibrium path. Regions do not respond in the same way to climate change. In particular, emission abatement rates and health costs depend on the economic and geographical characteristics of each region. Two policy scenarios are considered, Nash and Optimal, for which we present both global and regional results. Results for Africa and China are highlighted.     

High-Resolution Analysis of Debris Flow–Induced Channel Changes in a Headwater Stream,Ashio Mountains,Japan∗

Coupled hillslope and channel processes in headwater streams (HWS) lead to rapid changes in channel dimensions. Changes in channel size and shape caused by a debris flow event along the length of a headwater stream in the Ashio Mountains, Japan, were captured with the aid of repeat high-definition surveys using terrestrial laser scanning (TLS) techniques. The HWS was classified into three distinct reaches below the debris flow initiation zone. A large knickpoint separated an upper bedrock reach from a colluvial reach along the midsection of the drainage. The colluvial reach transitioned to a lower bedrock reach that terminated at the master stream. Cross-sectional and morphometric analyses revealed no statistically significant changes in channel size or shape along the upper bedrock reach. Debris flow erosion generated significant differences in channel size and shape along a colluvial reach. Sediment bulking associated with erosion along the colluvial reach led to increases in channel size along the lower bedrock reach, but no statistical differences in channel shape. Morphometric analyses from the TLS point cloud revealed that debris flow erosion produced a distinct nonlinear change in channel dimensions in the downstream direction within the HWS. Variations in channel substrate along the length of HWS contributed directly to this nonlinear response. The episodic nature and nonlinearity of erosion associated with the current debris flow event highlights the importance of debris flows in general in understanding the transport of sediment, coarse to fine particulate organic material, and large woody debris, which are critical to the long-term management of riverine environments. TLS sampling methods show promise as one component of a multianalytical approach needed to continuously monitor and manage the dynamics of HWS.     

Three‐dimensional structures and elemental distributions of Stardust impact tracks using synchrotron microtomography and X‐ray fluorescence analysis

Abstract— Three‐dimensional structures and elemental abundances of four impact tracks in silica aerogel keystones of Stardust samples from comet 81P/Wild 2 (bulbous track 67 and carrot‐type tracks 46, 47, and 68) were examined non‐destructively by synchrotron radiation‐based microtomography and X‐ray fluorescence analysis. Track features, such as lengths, volumes and width as a function of track depth, were obtained quantitatively by tomography. A bulbous portion was present near the track entrance even in carrot‐type tracks. Each impact of a cometary dust particle results in the particle disaggregated into small pieces that were widely distributed on the track walls as well as at its terminal. Fe, S, Ca, Ni, and eight minor elements are concentrated in the bulbous portion of track 68 as well as in terminal grains. It was confirmed that bulbous portions and thin tracks were formed by disaggregation of very fine fragile materials and relatively coarse crystalline particles, respectively. The almost constant ratio of whole Fe mass to track volume indicates that the track volume is almost proportional to the impact kinetic energy. The size of the original impactor was estimated from the absolute Fe mass by assuming its Fe content (CI) and bulk density. Relations between the track sizes normalized by the impactor size and impact conditions are roughly consistent with those of previous hypervelocity impact experiments.     

Baroclinic circulation and its high frequency variability in Otsuchi Bay on the Sanriku ria coast,Japan

Hydrographic observations were made in Otsuchi Bay on the Sanriku ria coast, Japan, to provide clear images of the baroclinic circulation extending over the bay together with the associated intrusion of lower-layer water (bottom water) from outside the bay. In summer, a prominent baroclinic circulation with flow speeds \({>} 0.1\ \text{ m }\ \text{ s }^{-1} \) extends over the greater part of the bay. A main pycnocline (thermocline), which separates the upper and lower layers, is located at a depth of 15–40 m in and around the bay. The direction of the lower-layer flow (inflow into and outflow from the bay) is opposite to that of the upper-layer flow, which are baroclinically coupled to each other. Moreover, with regard to the lower-layer flow, the inflow tends to occur mainly through the northwestern part of the bay mouth, whereas the outflow tends to occur mainly through the southeastern part. The inflow and outflow alternate on time scales of several to a few tens of hours, and the flow directions are sometimes related to the tidal ones, although the relationship is not applied persistently. In winter, the baroclinic circulation is considerably weaker than in summer, because the stratification breaks down.     

Four-dimensional variational ocean reanalysis: a 30-year high-resolution dataset in the western North Pacific (FORA-WNP30)

We produced a four-dimensional variational ocean re-analysis for the Western North Pacific over 30 years (FORA-WNP30). It is the first-ever dataset covering the western North Pacific over 3 decades at eddy-resolving resolution. The four-dimensional variational analysis scheme version of the Meteorological Research Institute Multivariate Ocean Variational Estimation system (MOVE-4DVAR) is employed to conduct a long-term reanalysis experiment during 1982–2012. After evaluating the basic performance of FORA-WNP30, the interannual to decadal variability is analyzed. Overall, FORA-WNP30 reproduces basic features in the western North Pacific well. One of outstanding features in FORA-WNP30 is that anomalous events such as the Kuroshio large meander and anomalous intrusion of the Oyashio in the 1980s, when there were no altimeter data, are successfully reproduced. FORA-WNP30 is therefore a valuable dataset for a variety of oceanographic research topics and potentially for related fields such as climate study, meteorology and fisheries.     

Impacts of climate change on growth, migration and recruitment success of Japanese sardine (Sardinops melanostictus) in the western North Pacific

We developed a multi-trophic level ecosystem model by coupling physical, biogeochemical-plankton and fish models. An oceanic general circulation model was coupled with a lower trophic level ecosystem model and a Japanese sardine migration model, and applied to the western North Pacific. To investigate the impact of global warming on the pelagic fish ecosystem, such as Japanese sardine, we conducted numerical experiments of growth and migration of Japanese sardine using physical fields for the present day and future with a global warming scenario simulated by a high-resolution climate model. The model results demonstrated possible impacts of global warming on the growth and migration pattern of Japanese sardine. The growths of fish in the current main spawning region under the global warming scenario were significantly slower than those under the present climate scenario. Fish in this region will be at disadvantage for their recruitment under the global warming condition. Prey conditions in the spawning region were projected not to markedly change under global warming condition while water temperature increased. As a result sardine spawning ground was projected to shift towards more north areas. During the feeding migration period in summer, geographical distribution of juveniles fish was projected to shift northwards by one to two degrees latitude under the global warming condition following the change in the distribution of optimal temperature region for feeding. However, this northwards shift of the optimal temperature for feeding was minimized adjacent to the western North Pacific by the cooler water supply by the intensification of the Oyashio.     

Gas dynamics and structure of galaxies

Between gas dynamics and structure of galaxies is a two-way relation. On one hand, gas dynamics in a galaxy is largely determined by the structure of the galaxy, and on the other hand, gas dynamics can gradually alter the galaxy structure through redistribution of mass and angular momentum within the galaxy. The first half of this relation should mostly determine gas distribution and regulate star formation in undisturbed spirals, and the second half has been suggested to cause secular evolution of spiral galaxies—a slow mode of galaxy evolution in the absence of major mergers. Our knowledge on this relation is going to be greatly deepened by the ALMA. Focusing on the galaxy evolution through gas dynamics, I briefly review what we know about the subject. Then I try to look out what the ALMA can do to answer open questions in the field. It is pointed out that the ALMA will be able to fully map all the spiral galaxies between 1 and 25 Mpc at 1″ resolution in 1000 hours.     

Sequential Chemical Separation of Cr and Ti from a Single Digest for High‐Precision Isotope Measurements of Planetary Materials

Combined determination of Cr and Ti isotopes of planetary materials offers a means with which to investigate their genetic relationship and the evolution of the protoplanetary disk. Here, we report the new sequential chemical separation procedure for combined Cr and Ti isotope ratio measurements. It comprises three steps: (a) Fe removal using AG1‐X8 anion exchange resin, (b) Ti separation using TODGA resin and (c) Cr separation using AG50W‐X8 cation exchange resin (with one additional step of Ti purification using AG1‐X8 anion exchange resin for samples having high Cr/Ti and Ca/Ti ratios). We applied the proposed procedure to terrestrial and meteorite samples with various compositions. Typical recovery rates of 90–100% were achieved with total procedural Cr and Ti blanks of 3–5 and 2–3 ng, respectively. We measured the Cr and Ti isotope compositions of the separated samples using thermal ionisation mass spectrometry and multiple collector‐inductively coupled plasma‐mass spectrometry, respectively. Our Cr and Ti isotope data were found to be consistent with those of previous studies of individual Cr and Ti isotopic compositions of the meteorites. These results demonstrate the capability of our separation method when applied to combined high‐precision Cr and Ti isotope analyses for single digests of planetary materials.     

Detection and hydrologic modeling of aquifers in unconsolidated alluvial plains through combination of borehole data sets: a case study of the Arao area, Southwest Japan

In addition to spatial distribution of groundwater-flow parameters, aquifer properties of location and shape are also significant for assessing groundwater resources because they strongly affect water flow. We present a selection of geologic data suitable for aquifer analysis, a mathematical method of processing them, and a combination of several maps produced by it. The data used in the analysis are typically obtained by borehole investigation. Our targets are the areas underlain by geologic bodies with different ages and lithologies; the spatial correlation structures of geologic data over the areas tend to change locally. The processing method should be a versatile one that is applicable to areas where geostatistical stationarity is not satisfied. The aquifer analysis consistent with that requirement consists of two steps: the first is the transformation of screen locations, locations of sand and gravel layers, and resistivity by electric logging into indicator values, and the second is three-dimensional interpolation of these using the optimization principle method to produce three kinds of distribution models. A stochastic simulation is also used for modeling the resistivity distribution. The three distribution models are integrated to generate a value for evaluating the possibility of aquifer existence. A case study of an alluvial coastal plain, situated in southwest Japan, describes an aquifer model that contains three permeable layers. Each layer has about 10-m thickness and is lens shaped. To confirm the validity of the model, we have drilled two wells that reached one of the middle and bottom permeable layers, observing the water level change. Low correlation of the temporal changes of levels between the wells indicates that the two layers are hydrologically independent of each other. Additionally, groundwater-flow patterns have been estimated by transforming the simulation model parameter into hydraulic conductivity through a simple function and using a finite difference method for flow analysis. The procedure proposed by this study can be applied to other areas by changing the weights assigned to each geologic and geotechnical factor in the generation of the coefficient for aquifer existence, considering the reliability of each factor and hydrologic properties of study area.