Performance evaluation of a ground-source heat pump system utilizing a flowing well and estimation of suitable areas for its installation in Aizu Basin,Japan

Development of a ground-source heat pump (GSHP) system with higher efficiency, and evaluation of its operating performance, is essential to expand the growth of GSHP systems in Japan. A closed-loop GSHP system was constructed utilizing a flowing (artesian) well as a ground heat exchanger (GHE). The system was demonstrated for space-heating and space-cooling of a room (area 126.7 m²) in an office building. The average coefficient of performance was found to be 4.5 for space-heating and 8.1 for space-cooling. The maximum heat exchange rate was 70.8 W/m for space-heating and 57.6 W/m for space-cooling. From these results, it was determined that a GSHP system with a flowing well as a GHE can result in higher performance. With this kind of highly efficient system, energy saving and cost reduction can be expected. In order to assess appropriate locations for the installation of similar kinds of GSHP systems in Aizu Basin, a suitability map showing the distribution of groundwater up-flowing areas was prepared based on the results of a regional-scale three-dimensional analytical model. Groundwater up-flowing areas are considered to be suitable because the flowing well can be constructed at these areas. Performance evaluation of the GSHP system utilizing the flowing well, in conjunction with the prepared suitability map for its installation, can assist in the promotion of GSHP systems in Japan.     

High temperature infrared spectra of hydrous microcrystalline quartz

A series of in-situ high temperature infrared (IR) measurements of water in an agate sample and in a milky quartz has been conducted in order to understand the nature of water in silica at high temperatures (50–700?°C) and the dehydration behavior. IR absorption bands of water molecules trapped in the milky quartz showed a systematic decrease in intensities and a shift from 3425?cm^?1 at 50?°C toward 3590?cm^?1 at 700?°C without any loss of water. This indicates a change in IR absorption coefficients corresponding to different polymeric states of water at different temperatures. The broad 3430?cm^?1 band in the agate sample also showed a systematic decrease in IR intensity and a band shift toward higher frequency with increasing temperature (～700?°C). This indicates that the agate sample also contains fluid inclusion-like water. For this agate sample, a dehydration of loosely hydrogen-bonded molecular water occurred at lower temperatures (<200?°C). At higher temperatures (>400?°C), sharp bands around 3660 and 3725?cm^?1 (3740?cm^?1 at 50?°C) due to surface silanols, appeared. This indicates dehydration of H₂O molecules that are hydrogen bonded to surface silanols. SiOH species in the agate are divided into three groups, namely SiOH group located at structural defects, surface silanols hydrogen bonded to each other and free surface silanols. Former two dehydrate below 700?°C and the dehydration rate of the SiOH at structural defects is faster than the other. IR spectra show that SiOH species decrease continuously even after the dehydration of most of H₂O molecules. All these results provide realistic bases for the change in physicochemical states of different OH species in silica at high temperatures.     

Resistivity mapping using the VLF-MT method around surface fault ruptures of the 1995 Hyogo-ken Nanbu earthquake, Japan

Abstract Distinctive fault ruptures, the Nojima Fault and Ogura Fault, appeared along the northwestern coast of Awaji Island at the time of the 1995 Hyogo-ken Nanbu earthquake (Kobe earthquake). In order to delineate the shallow resistivity structures around the faults just after they formed, Very Low Frequency Magnetotelluric (VLF-MT) surveys were made at five sites along the Nojima Fault and at one site along the Ogura Fault. Fourteen transects were made at the one site on the Ogura Fault, and another transect covers the area between the two faults. Changes in apparent resistivity or phase, or both, commonly occur when crossing the surface location of one of the faults, except for the northern transects at OGR-0 on the Ogura Fault. Apparent resistivity values of less than 100 Ωm were observed for Tertiary and Quaternary sediments and values larger than 200 Ωm for granitic rocks. The resistivity structures are related to the morphological characteristics of the fault ruptures. Remarkably conductive zones (less than 10 Ωm in apparent resistivity and 30–40 m in width) were found where the surface displacement is distinct and prominent along a single fault plane. If remarkably conductive zones were formed at the time of the 1995 Hyogo-ken Nanbu earthquake, the results provide a good constraint on the dimensions of a conductive zone near the surface that was made by one earthquake. Alternatively, if characteristic resistivity structures existed prior to the earthquake, the conductive zone was probably formed by some tens of earthquakes in relatively modern times. In this case, this phenomenon is inferred to be a concentration of fracturing in a narrow zone and is associated with the formation of clay minerals, which enhance rock conductivity.     

Hydrodynamical models of the Orion-KL Nebula

The interaction between an isotropic protostellar wind and an ambient molecular cloud is investigated by two-dimensional hydrodynamic computations. The wind-cloud interaction model is promising for explanation of the observed properties of the Orion-KL Nebula.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.     

Summer Water Balance Characteristics of Koryto Glacier, Kamchatka Peninsula, Russia

The daily water balance for the drainage basin of Koryto Glacier, Kamchatka Peninsula, Russia, was calculated during the period from August to September 2000. The result shows that 14×10⁶ m³ of meltwater and 2×10⁶ m³ of rainwater entered the basin, while 26×10⁶ m³ of water drained from the basin through proglacial streams. Thus, about ?9×10⁶ m³ of water storage reduction occurred in the basin. Vertical displacements of the glacier surface showed that the volume change due to contraction of subglacial cavities was nearly 20% of the total storage change. The remaining fraction of water storage during the period is thought to be stored in englacial and supraglacial locations. The estimate of water balance components in the early ablation season in 2000 indicates that meltwater was already stored within the glacier before the spring, even during the previous year, and that the stored water drained through the ablation season.     

Photosynthesis-irradiance relationship of phytoplankton and primary production in the vicinity of Kuroshio warm core ring in spring

The light-saturated maximum value (P ^B _max) and initial slope (α) of the photosynthesis-irradiance (P-E) curve were examined in a warm streamer, a cold streamer and a warm core ring off the Sanriku area in the subarctic western North Pacific Ocean during an ADEOS/OCTS Sanriku field campaign in early May 1997. BothP ^B _max and α were within the ranges of temperate populations. A regional difference was apparent inP ^B _max: populations in the warm streamer tended to show higher value ranging between 1.92 and 4.74 mgC (mgChla)⁻¹h⁻¹ than those in the cold streamer and the warm core ring (1.35–2.87 mgC (mgChla)⁻¹h⁻¹). A depth variation was also observed in α in both the warm streamer and the warm core ring: shallow populations tended to have lower α than deep populations. The depth variations in bothP ^B _max and α resulted in a lower light intensity of the light saturation in a deeper population than that of a shallower one. These depth-related variations in the P-E parameters were likely a manifestation of “shade-adaptation” of photosynthesis. Photoinhibition was not observed over in situ surface light intensity varying below ca 1600 μmol photon m⁻²s⁻¹. Water-column primary productivity was biooptically estimated to be 233 to 949 mgC m⁻²d⁻¹ using vertical distributions of the P-E parameters, chlorophylla, phytoplankton light absorption and underwater irradiance. Applicability of surface data sets for estimation of water-column productivity is discussed.     

Does heavy oil pollution induce bacterial diseases in Japanese flounder Paralichthys olivaceus?

As basic research for the effect of heavy oil on the fish immune system, in this study, the number of leukocyte was counted in Japanese flounder Paralichthys olivaceus, after exposure to heavy oil at a concentration of 30 g/8L for 3 days. To compare the numbers of bacteria in the skin mucus between oil-exposed and control fish, viable bacteria were enumerated by counting colony forming unit (CFU). Compared with 5.79+/-1.88 x 10(7)leukocytes/mL in the controls, the exposed fish demonstrated higher counts, averaging 1.45+/-0.45 x 10(8)cells/mL. The bacterial numbers of control fish were 4.27+/-3.68 x 10(4)CFU/g, whereas they were 4.58+/-1.63 x 10(5)CFU/g in the exposed fish. The results suggest that immune suppression of the fish occurred due to heavy oil stressor, and bacteria could invade in the mucus, resulting in the increasing leukocyte number to prevent infectious disease.     

Adsorption of extracellular proteases in seawater onto filters during size fractionation

In aquatic environments extracellular enzymes are bound to microbial cells or exist in a free and adsorbed state. Various filters have been used to fractionate these enzymatic activities, but enzymes may be readily adsorbed onto some materials, and such adsorption can induce errors in the estimation of enzymatic activity. In this study we examined three filters to determine the most suitable filter for fractionation when estimating proteolytic enzyme activity in seawater. We found that the polycarbonate Nuclepore membrane, widely used for size fractionation because of its pore-size accuracy, was the most favorable for this purpose, even though it adsorbed slightly more enzymes than the low-protein-binding polyethersulfone membrane. We also found that trypsin-and chymotrypsin-type enzymes were more easily adsorbed than aminopeptidases.     

Aeromonas veronii, a tributyltin (TBT)-degrading bacterium isolated from an estuarine environment, Ria de Aveiro in Portugal

Organotin compounds are used in a variety of industrial processes therefore their subsequent discharge into the environment is widespread. Bacteria play an important role in biogeochemical transformations acting as natural decontamination agents. Therefore, screening for tributyltin (TBT)-resistant and -degrading bacteria is relevant for the selection of isolates with decontamination ability of these polluted areas. With this purpose, 50 strains were isolated from sediment and water from Ria de Aveiro and their tolerance to TBT, up to 3mM, was evaluated. Generally, occurrence of highly TBT-resistant bacteria was observed, and Gram negative bacteria exhibited more tolerance to TBT than Gram positive bacteria. A memory response was observed when bacteria were progressively exposed to increasingly higher TBT concentrations. One isolate, Aeromonas veronii Av27, highly resistant to TBT (3mM) uses this compound as carbon source and degrades it to less toxic compounds.     

Spatial distribution of organic matter in the Bells CM2 chondrite using near‐field infrared microspectroscopy

Abstract– Distributions of organic functional groups as well as inorganic features were analyzed in the Bells (CM2) carbonaceous chondrite using near‐field infrared (NFIR) spectroscopy. NFIR spectroscopy has recently been developed to enable infrared spectral mapping beyond the optical diffraction limit of conventional Fourier transform infrared microspectroscopy. NFIR spectral mapping of the Bells 300 nm thick sections on Al plates for 7.5 × 7.5 μm² areas showed some C‐H‐rich areas which were considered to represent the organic‐rich areas. Heterogeneous distributions of organic matter as well as those of inorganic phases such as silicates (Si‐O) were observed with 1 μm spatial resolution. The NFIR mappings of aliphatic C‐H (2960 and 2930 cm^?1) and structural OH (3650 cm^?1) confirm that organic matter is associated with phyllosilicates as previously suggested. The NFIR mapping method can provide 1 μm spatial distribution of organic functional groups and their association with minerals. High local sensitivity of NFIR enables us to find organic‐rich areas and to characterize them by their aliphatic CH₂/CH₃ ratios. The aliphatic CH₂/CH₃ ratio of Bells is slightly higher than Murchison, similar to Orgueil, and lower than literature values of IDPs and cometary dust particles.