Color measurements of volcanic ash deposits from three different styles of summit activity at Sakurajima volcano,Japan: Conduit processes recorded in color of volcanic ash

We measured quantitatively colors of volcanic ash deposits erupted from three different styles of summit activity (Strombolian activity, Vulcanian explosions and continuous ash venting activity) at Sakurajima volcano from 1974 to 1985. Colors of Strombolian ash samples have larger yellow components of their visible spectra (b^? values) than those of explosion and continuous venting ash samples. Colors of explosion ash samples show larger variation in both red and yellow components of their visible spectra (a^? and b^? values, respectively), while colors of continuous venting ash samples are in the narrow ranges within colors of explosion ash samples. Colors of components with lower densities than 3.1 g/cm³ (groundmass and phenocrystic plagioclase) obtained by magnetic and heavy liquid separation methods are similar to the unseparated bulk ash samples. This result suggests that the color variations of ash deposits are mainly originated from the particles composed of groundmass. The particles can be classified into three different types of particles with different vesicularity and crystallinity (vesicular particle [VP], dense particle with vesicles [DPV] and dense particle without vesicles [DP]). Analytical results of component proportions, chemical compositions of groundmass glasses, ferrous iron contents and surface ferric materials show that (1) VP has larger yellow components of the visible spectrum (b^? values) and high ferrous iron content, and is less crystallized than the DP and DPV, (2) DP has larger red and yellow components of its visible spectrum (a^? and b^? values, respectively) and involves ferric materials on the surfaces produced by oxidation process, and (3) DPV has smaller red and yellow components of its visible spectrum (a^? and b^? values, respectively) and involves less ferric materials on the ash surfaces. Color differences of ash deposits from three different activity styles can be explained by the different mixing ratios of VP, DPV and DP. During the Strombolian activity, the VP is a main component in the ash, which is formed from relatively less degassed and crystallized magma. In the Vulcanian explosion and continuous ash venting activity, the proportions of DPV and DP in ash are larger than that in the Strombolian activity. The highly crystallized DP may correspond to a vent cap, and DPV to a magma below the cap. The color measurements of ash deposits provide information on the pre-eruptive processes at the shallower levels of a conduit.     

Sea surface temperature distribution and its variability across the Tsushima Strait

The sea surface temperature distribution across the Tsushima Strait was monitored over a one-year period on board the ferry Kampu which runs between Shimonoseki, Japan and Pusan, Korea. A cold water region is always observed just near the Korean Coast, and a sharp temperature front is always present in the western channel. A temperature maximum or a warm core is usually found just on the southeast side of the front. The position of the warm core exhibits large short period fluctuations, but no significant seasonal variation is found. Sudden temperature increases followed by sudden temperature decreases are frequently observed in the temporal variation curves at fixed positions during the warming season from April to August. Such events are related to temperature maxima found sporadically in the temperature distribution in the eastern channel during this season, and seem to be caused by warm water intrusion into the Tsushima Strait from the East China Sea.     

Calcium-alkalinity relationship in the North Pacific

The dissolution of calcium carbonate in deep ocean water causes variation in calcium concentration (Ca) and alkalinity (TA) in the ratio of one to two. The decomposition of organic matter generates nitric acid, phosphoric acid and sulfuric acid. A proton flux which is derived from this process also changes alkalinity. Using the variation in nitrate concentration (NO₃) as an index of the proton flux, the relationship betweenCa,TA andNO₃ is expressed asCa=0.5TA+0.63NO₃ The values of Ca obtained from direct measurements in the North Pacific are in good agreement with the values estimated from this equation.     

A numerical study on the formation and variation of a clockwise-circulation during winter in the Yellow Sea

In the Yellow Sea, the north-westerly wind dominates in winter and the existence of horizontal clockwise circulation has been suggested (Yanagi and Takahashi, 1993). The formation and variation mechanisms of this clockwise circulation is investigated using the wind forced numerical model which has a simplified basin configuration of the Yellow Sea. The model results show that two vortices (an anticlockwise vortex off Chinese coast and a clockwise vortex off Korean coast) are generated by the uniform north-westerly wind. Both vortices propagate along the shelf slope as the first mode shelf waves. An anti-clockwise vortex can not grow because it does not balance to the wind forcing. On the other hand, a clockwise vortex can grow and it reaches to the equilibrium condition at the northern part of the Yellow Sea, because this circulation can balance to the wind forcing. The time scale to become into the equilibrium condition is about 2 days. From this fact, it is ascertained that a clockwise circulation in the basin is generated periodically according to the variable wind forcing with 4 days period. The steady part of the current field exists with the fluctuating one which is induced by the periodical north-westerly wind.     

Degradation of outer membrane proteins of <Emphasis Type="Italic">Synechococcus</Emphasis> sp. <Emphasis Type="Italic">in vitro</Emphasis> and <Emphasis Type="Italic">in situ</Emphasis>

To examine the possibility that outer membrane proteins (OMP) of Synechococcus sp. remain in seawater, we investigated the stability of OMPs in vitro and in situ. Some fractions prepared from Synechococcus sp. CSIRO-94 were treated with trypsin and proteinase K. Four tightly bound OMPs were separated from Synechococcus. We designated the two major OMPs of 52 kDa and 48 kDa as Omp52Sy and Omp48Sy, respectively. Degradation of the OMP in natural seawater was monitored in microcosms to which intact Synechococcus cells and outer membrane (OM) were added. Omp52Sy and Omp48Sy were the most stable against trypsin and proteinase K among the OMPs when they were embedded in the OM. However, in the microcosm experiment using intact cells, Omp52Sy and Omp48Sy were detected in the particulate fraction only during the first 4 days, after which they could not longer be detected. Omp52Sy and Omp48Sy were the most stable proteins among the Synechococcus OMPs in vitro, but they might be degraded in situ. This indicates that stability of Synechococcus porin differs depending on complex formation with other membrane molecules, which might cause different preservation of microbial membrane proteins in the dissolved protein pool in the ocean. This study suggests that Gram negative bacterial OM with thin peptidoglycan forms a lipid bilayer that proptects OMP, but Synechococcus OM with thick peptidoglycan cannot form a lipid bilayer. The incomplete bilayer might not be able to protect from protease attack in the natural environment.     

Shipboard calibration of an infrared absorption gas analyser for total carbon dioxide determination in sea water

A new method for shipboard calibration of an infrared absorption carbon dioxide analyser was devised, utilizing the oxidative decomposition reaction of oxalic acid by permanganate in acid solution. With the present method, shipboard analysis of total carbon dioxide in 2 ml of sea water can be carried out with an error of less than 0.5 %. Some improvements in the analyser system are also presented.     

Hydration of rhyolitic glass during weathering as characterized by IR microspectroscopy

The mechanism and rate of hydration of rhyolitic glass during weathering were studied. Doubly polished thin sections of two rhyolites with different duration of weathering (Ohsawa lava: 26,000 yr, Awanomikoto lava: 52,000 yr) were prepared. Optical microscope observation showed that altered layers had developed along the glass surfaces. IR spectral line profile analysis was conducted on the glass sections from the surface to the interior for a length of 250 μm and the contents of molecular H₂O (H₂O_m), OH species (OH) and total water (H₂O_t) were determined. The diffusion profile of H₂O_m in Ohsawa lava extends beyond the layer observed by optical microscope. The content of H₂O_m in the hydrated region is much higher than that of OH species. Thus, the reaction from H₂O_m to OH appears to be little and H₂O_m is the dominant water species moving into the glass during weathering. Based on the concentration profiles, the diffusion coefficients of H₂O_m(D_H2Om) and H₂O_t(D_H2Ot) were determined to be 2.8 × 10⁻¹⁰ and 3.4 × 10⁻¹⁰ μm² s⁻¹ for Ohsawa lava, and 5.2 × 10⁻¹¹ and 4.1 × 10⁻¹¹ μm² s⁻¹ for Awanomikoto lava, respectively. The obtained D_H2Om during weathering are more than 2-3 orders of magnitude larger than the diffusion coefficient at ∼20 °C that is extrapolated from the diffusivity data for >400 °C. This might suggest that the mechanism of water transport is different at weathering conditions and >400 °C.     

Water and heat fluxes above a lowland dipterocarp forest in Peninsular Malaysia

We measured the fluxes of sensible and latent heat between a low‐land dipterocarp forest in Peninsular Malaysia and the atmosphere. No clear seasonal or interannual changes in latent heat flux were found from 2003 to 2005, while sensible heat flux sometimes fluctuated depending on the fluctuation of incoming radiation between wet and dry seasons. The evapotranspiration rates averaged for the period between 2003 and 2005 were 2·77 and 3·61 mm day^?1 using eddy covariance data without and with an energy balance correction, respectively. Average precipitation was 4·74 mm day^?1. Midday surface conductance decreased with an increasing atmospheric water vapour pressure deficit and thus restricted the excess water loss on sunny days in the dry season. However, the relationship between the surface conductance and vapour pressure deficit did not significantly decline with an increase in volumetric soil water content even during a period of extremely low rainfall. Copyright © 2009 John Wiley & Sons, Ltd.     

越南东北部Cat Ba岛泥盆系-石炭系过渡层的初探

The Pho Han Formation is exposed on southern Cat Ba Island, Hai Phong Province in northeastern Vietnam, and intercalates the Devonian and Carbonif-erous (D-C) boundary (Ta and Doan, 2007; Komatsu et al., 2012). The D-C boundary section consists mainly of limestone beds, numbered from 1 to 167, interca-lated with alternating black organic-rich shales. The limestone yields abundant brachiopods, crinoid-stems and conodonts. Preliminary investigations on strati-graphy (conodont biostratigraphy and δ13C) and sedi-mentology of beds 113-133 were undertaken in this study.