A conceptual review of regional-scale controls on the composition of clastic sediment and the co-evolution of continental blocks and their sedimentary cover

Both sediment recycling and first-cycle input influence the composition of clastic material in sedimentary systems. This paper examines conceptually the roles played by these processes in governing the composition of clastic sediment on a regional scale by outlining the expected effects on sediment composition of protracted sediment recycling and of continuous first-cycle input on a maturing continental block. Generally speaking, long-term recycling tends to enrich sediments in the most chemically and mechanically stable components: quartz in the sand and silt size fractions, and illite among the clay minerals. Sandstones trend towards pure quartz arenites, and mudrocks become more potassic and aluminous. The average grain size of clastic sediment decreases by a combination of progressive attrition of sand grains and ongoing breakdown of primary silicate minerals to finer-grained clay minerals and oxides. Sandstones derived by continuous first-cycle input from an evolving continental crustal source also become increasingly rich in quartz, but in addition become more feldspathic as the proportion of granitic material in the upper continental crust increases during crustal stabilization. Associated mudrocks also become richer in potassium and aluminum, but will have higher K2O/Al2O3 ratios than recycled muds. The average grain size of the sediment may increase with time as the proportion of sand-prone granitic source rocks increases at the expense of more mud-prone volcanic sources. In general, except in instances where chemical weathering is extreme, first-cycle sediments lack the compositional maturity of recycled detritus, and are characterized by the presence of a variety of primary silicate minerals. Sedimentary systems are not usually completely dominated by either recycling or first-cycle detritus. Generally, however, sedimentary systems associated with the earliest phases of formation and accretion of continental crust are characterized by first-cycle input from igneous and metamorphic rocks, whereas those associated with more mature cratons tend to be dominated by recycled sedimentary material.     

Responses of two trophic levels to patch enrichment along a New Zealand stream continuum

We carried out a benthic survey and two experiments in runs at eight sites down the Kakanui River (South Island, New Zealand) during summer low flows, to investigate the interaction between nutrients, periphyton, and macro‐grazers. Benthic periphytic biomass was generally low (< 20 mg m^‐2 chlorophyll a) at most sites, but high densities of macro‐grazers (mainly snails) were observed at six of the eight sites. Chlorophyll a and cellular P concentrations were generally higher on artificial substrates in the first‐ to third‐order tributaries, compared with downstream. Macro‐grazer densities (mainly snails) were also highest in the second‐ and third‐order tributaries. Enrichment of patches with N and P did not translate into significant increases in chlorophyll a concentrations. Instead there was a general increase in macro‐grazers, and an increase in the relative abundance of Cocconeis placentula. In a second experiment, the chlorophyll a level was five‐fold higher on the substrates where macro‐grazers were excluded and there was no significant response of chlorophyll a to nutrient addition on these substrates. On the grazed substrates, densities of snails and caddis‐larvae were two‐fold higher with N+P enrichment. These experiments provided evidence for a tight coupling between first and second trophic levels, and strong grazer control of periphyton, in this river.     

The effects of aggressive mitigation on steric sea level rise and sea ice changes

With an increasing political focus on limiting global warming to less than 2 °C above pre-industrial levels it is vital to understand the consequences of these targets on key parts of the climate system. Here, we focus on changes in sea level and sea ice, comparing twenty-first century projections with increased greenhouse gas concentrations (using the mid-range IPCC A1B emissions scenario) with those under a mitigation scenario with large reductions in emissions (the E1 scenario). At the end of the twenty-first century, the global mean steric sea level rise is reduced by about a third in the mitigation scenario compared with the A1B scenario. Changes in surface air temperature are found to be poorly correlated with steric sea level changes. While the projected decreases in sea ice extent during the first half of the twenty-first century are independent of the season or scenario, especially in the Arctic, the seasonal cycle of sea ice extent is amplified. By the end of the century the Arctic becomes sea ice free in September in the A1B scenario in most models. In the mitigation scenario the ice does not disappear in the majority of models, but is reduced by 42 % of the present September extent. Results for Antarctic sea ice changes reveal large initial biases in the models and a significant correlation between projected changes and the initial extent. This latter result highlights the necessity for further refinements in Antarctic sea ice modelling for more reliable projections of future sea ice.     

Modelling chemistry in the nocturnal boundary layer above tropical rainforest and a generalised effective nocturnal ozone deposition velocity for sub-ppbv NOx conditions

Measurements of atmospheric composition have been made over a remote rainforest landscape. A box model has previously been demonstrated to model the observed daytime chemistry well. However the box model is unable to explain the nocturnal measurements of relatively high [NO] and [O₃], but relatively low observed [NO₂]. It is shown that a one-dimensional (1-D) column model with simple O₃-NO_x chemistry and a simple representation of vertical transport is able to explain the observed nocturnal concentrations and predict the likely vertical profiles of these species in the nocturnal boundary layer (NBL). Concentrations of tracers carried over from the end of the night can affect the atmospheric chemistry of the following day. To ascertain the anomaly introduced by using the box model to represent the NBL, vertically-averaged NBL concentrations at the end of the night are compared between the 1-D model and the box model. It is found that, under low to medium [NO_x] conditions (NO_x?<?1 ppbv), a simple parametrisation can be used to modify the box model deposition velocity of ozone, in order to achieve good agreement between the box and 1-D models for these end-of-night concentrations of NO_x and O₃. This parametrisation would could also be used in global climate-chemistry models with limited vertical resolution near the surface. Box-model results for the following day differ substantially if this effective nocturnal deposition velocity for ozone is implemented; for instance, there is a 9% increase in the following days peak ozone concentration. However under medium to high [NO_x] conditions (NO_x > 1 ppbv), the effect on the chemistry due to the vertical distribution of the species means no box model can adequately represent chemistry in the NBL without modifying reaction rate coefficients.     

The Final Stage of Silicic Island Arc Magmatism in the Northern Urals

Doklady Earth Sciences - The date of cessation of calc-alkaline volcanic complex accumulation within the Devonian (Frasnian) island arc in the Northern Urals was determined for the first time. It...     

Textural trends in turbidites and slurry beds from the Oligocene flysch of the East Carpathians, Romania

Deep‐water sandstone beds of the Oligocene Fusaru Sandstone and Lower Dysodilic Shale, exposed in the Buz?u Valley area of the East Carpathian flysch belt, Romania, can be described in terms of the standard turbidite divisions. In addition, mud‐rich sand layers are common, both as parts of otherwise ‘normal’ sequences of turbidite divisions and as individual event beds. Eleven units, interpreted as the deposits of individual flows, were densely sampled, and 87 thin sections were point counted for grain size and mud content. S₃/T_a divisions, which form the bulk of most sedimentation units, have low internal textural variability but show subtle vertical trends in grain size. Most commonly, coarse‐tail normal grading is associated with fine‐tail inverse grading. The mean grain size can show inverse grading, normal grading or a lack of grading, but sorting tends to improve upward in most beds. Fine‐tail inverse grading is interpreted as resulting from a decreasing effectiveness of trapping of fines during rapid deposition from a turbidity current as the initially high suspended‐load fallout rate declines. If this effect is strong enough, the mean grain size can show subtle inverse grading as well. Thus, thick inversely graded intervals in deep‐water sands lacking traction structures do not necessarily imply waxing flow velocities. If the suspended‐load fallout rate drops to zero after the deposition of the coarse grain‐size populations, the remaining finer grained flow bypasses and may rework the top of the S₃ division, forming well‐sorted, coarser grained, current‐structured T_t units. Alternatively, the suspended‐load fallout rate may remain high enough to prevent segregation of fines, leading to the deposition of significant amounts of mud along with the sand. Mud content of the sandstones is bimodal: either 3–13% or more than 20%. Two types of mud‐rich sandstones were observed. Coarser grained mud‐rich sandstones occur towards the upper parts of S₃/T_a divisions. These units were deposited as a result of enhanced trapping of mud particles in the rapidly deposited sediment. Finer grained mud‐rich units are interbedded with ripple‐laminated very fine‐grained sandy T_c divisions. During deposition of these units, mud floccules were hydraulically equivalent to the very fine sand‐ and silt‐sized sediment. The mud‐rich sandstones were probably deposited by flows that became transitional between turbidity currents and debris flows during their late‐stage evolution.     

Coupling Suspension Feeders to the Chesapeake Bay Eutrophication Model

A model predicting suspension-feeding bivalve biomass and its interactions with water quality has been developed and coupled with the Chesapeake Bay Eutrophication Model. This coupling included deposition of filtered particulate matter to the sediments and the recycling of inorganic nutrients back to the water column. Because individual size is a crucial determinant of bivalve filtration and respiration rates, an empirical function, was developed from data, relating computed areal biomass to size, which was then used to adjust these rates during the simulation. Biomass was strongly related to the eutrophication model's predictions of organic and total solids distributions, as well as to bottom water dissolved oxygen. The tight coupling between seasonal organic matter concentration and biomass suggested that food, or the ability of suspension feeders to ingest it given present total solids loadings, is a limiting factor baywide. Hypoxia and anoxia also reduced benthic biomass in affected locations. High site-specific temporal variability observed in the data may contain a large component of spatial patchiness, on scales below which the present estuarine eutrophication model could resolve. Further insights will be needed to incorporate the effects of patchiness, as well as other important spatial and temporal signals, such as predation and recruitment.