Increasing temperature and flow management alter mercury dynamics in East Fork Poplar Creek

East Fork Poplar Creek (EFPC) is a mercury (Hg) contaminated creek in east Tennessee, USA. Stream restoration activities included the initiation of a flow management programme in 1996 in which water from a nearby lake was pumped to the head of the creek. We conducted regular water sampling for 2 years along the length of EFPC during active flow management and for 5 years after flow management stopped. Total Hg and total monomethylmercury (MMHg) concentration and flux decreased in the uppermost reaches of EFPC that were closest to the point of water addition. Most water quality parameters, including DOC concentration, remained unchanged after flow management termination. Nevertheless, SUVA₂₅₄, a measure of dissolved organic matter (DOM) composition, increased and coincided with increased dissolved Hg (Hg_D) concentration and flux and decreased Hg solid-water partitioning coefficients throughout EFPC. Higher SUVA₂₅₄ and Hg_D concentration have potential implications for bioavailability and MMHg production. Total and dissolved MMHg concentrations increased in lower reaches of EFPC after the end of flow management and these increases were most pronounced during spring and early summer when biota are more susceptible to exposure and uptake. A general warming trend in the creek after active flow management ended likely acted in concert with higher Hg_D concentration to promote higher MMHg concentration. Total and dissolved MMHg concentrations were positively correlated with water temperature above a threshold value of 10°C. Concentration changes for Hg and MMHg could not be accounted for by changes in creek discharge that accompanied the cessation of flow management. In addition to the changing DOM composition in-stream, other watershed-scale factors likely contributed to the observed patterns, as these changes occurred over months rather than instantaneously after flow management stopped. Nevertheless, similar changes in MMHg have not been observed in a tributary to EFPC.     

Dating the Kawakawa/Oruanui eruption: Comment on “Optical luminescence dating of a loess section containing a critical tephra marker horizon,SW North Island of New Zealand” by R. Grapes et al.

An IRSL age of 17.0 ± 2.2 ka (and a “mean age” of ca. 19 ka) reported by Grapes et al. [Grapes, R., Rieser, U., Wang, N. Optical luminescence dating of a loess section containing a critical tephra marker horizon, SW North Island of New Zealand. Quaternary Geochronology 5(2-3), 164–169.] for the Kawakawa/Oruanui tephra, and other ages associated with a loess section in New Zealand are untenable: age data presented are inconsistent, no formal statistical treatments or error determinations were undertaken in age analysis, and the ages proposed are seriously at odds with multiple radiocarbon age determinations on tephra sequences bracketing the Kawakawa/Oruanui tephra and with palaeoenvironmental evidence elsewhere for the time period concerned. We suggest that the bulk polymineral IRSL ages on the tephra and encapsulating loess deposits were underestimated in part because of contamination of the loess by the integration of younger materials during slow deposition and continuous modification by upbuilding pedogenesis. Single-grain luminescence assays may reveal such contamination. A ¹⁴C-based age of ca. 27 ± 1 ka cal BP (2σ), reported in 2008, currently remains the best estimate for the age of eruption of the Kawakawa/Oruanui tephra.     

Enhanced Acoustic Backscatter Due to High Abundance of Sand Dollars,Dendraster excentricus

Abstract

Detailed acoustic surveys of benthic sediments were conducted in July 1995 and September 1998 in the vicinity of Humboldt Bay, California. During these surveys, a band of enhanced acoustic backscatter was observed offshore from the bay entrance, approximately parallel to the isobaths, in water depths ranging from 16–24 m. In order to assess the cause of the increase in backscatter levels, a more comprehensive study was conducted in August and September 1999 using 100 kHz side-scan sonar, bottom grab sampling and underwater video recording. New observations indicated that a dense population of sand dollars (Dendraster excentricus) coincided with the enhanced backscatter band. Compared to the two previous acoustic studies, the central section of the band expanded westward by 180 m and the southern section of the band shifted eastward by 160 m, possibly resulting from a change in the biological or physical factors which influence the location and breadth of sand dollars.

The relationship between high sand dollar abundance and enhanced acoustic backscatter was further verified in the near shore region off Samoa Beach California, where a dense, banded population of sand dollars was previously observed. Video footage confirmed the presence of a band of sand dollars, also nominally parallel to the isobaths, in water depths of 8–15 m. A band of enhanced backscatter coincided with the dense sand dollar population. The identification of dense aggregations of sand dollars through enhanced acoustic backscatter could lead to the use of acoustic techniques to study sand dollar distributions and abundance.     

Palaeogeography and diachronous infill of an ancient deep‐marine foreland basin,Upper Cretaceous Cerro Toro Formation,Magallanes Basin

The details of how narrow, orogen‐parallel ocean basins are filled with sediment by large axial submarine channels is important to understand because these depositional systems commonly form in through‐like basins in various tectonic settings. The Magallanes foreland basin is an excellent location to study an orogen‐parallel deep‐marine system. Conglomerate lenses of the Upper Cretaceous Cerro Toro Formation have been previously interpreted to represent the fill of a single submarine channel (4–8 km wide, >100 km long) that funneled coarse detritus southward along the basin axis. This interpretation was based on lithologic correlations. New U/Pb dating of zircons from volcanic ashes and sandstones, coupled with strontium isotope stratigraphy, refine the controls on depositional ages and provenance. Results demonstrate that north‐south oriented conglomerate lenses are contemporaneous within error limits (ca. 84–82 Ma) supporting that they represent parts of an axial channel belt. Channel deposits 20 km west of the axial location are 87–82 Ma in age. These channels are partly contemporaneous with the ones within the axial channel belt, making it likely that they represent feeders to the axial channel system. The northern Cerro Toro Formation spans a Turonian to Campanian interval (ca. 90–82 Ma) whereas the formation top, 70 km to the south, is as young as ca. 76 Ma. Kolmogorov–Smirnoff statistical analysis on detrital zircon age distributions shows that the northern uppermost Cerro Toro Formation yields a statistically different age distribution than other samples from the same formation but shows no difference relative to the overlying Tres Pasos Formation. These results suggest the partly coeval deposition of both formations. Integration of previously acquired geochronologic and stratigraphic data with new data show a pronounced southward younging pattern in all four marine formations in the Magallanes Basin. Highly diachronous infilling may be an important depositional pattern for narrow, orogen‐parallel ocean basins.     

Artificial neural network assisted Bayesian calibration of climate models

We demonstrate and validate a Bayesian approach to model calibration applicable to computationally expensive General Circulation Models (GCMs) that includes a posterior estimate of the intrinsic structural error of the model. Bayesian artificial neural networks (BANNs) are trained with output from a GCM and used as emulators of the full model to allow a computationally efficient Markov Chain Monte Carlo (MCMC) sampling of the posterior for the GCM parameters calibrated against seasonal climatologies of temperature, pressure, and humidity. We validate the methodology by calibrating to targets produced by a model run with added noise. We then demonstrate a calibration of five GCM parameters against an observational data set. The approach accounts for both parametric and structural uncertainties of the model as well as uncertainties associated with the observational calibration data. This enables the generation of statistically rigorous probabilistic forecasts for future climate states. All calibration experiments are performed with emulators trained using a maximum of one hundred model runs, in accord with typical resource restrictions imposed by computationally expensive models. We conclude by summarizing remaining issues to address in order to create a complete and validated operational methodology for objective calibration of computationally expensive models.     

The cytology and occurrence of granulocytomas in mussels

A non-neoplastic inflammatory cellular condition in the marine mussel Mytilus edulis is described and a possible relationship drawn between its incidence and water quality as effected by chronic insult by domestic and industrial waste products. This condition, termed a granulocytoma owing to its dominant constituent cell type, is capable of overcoming host encapsulation and inducing atrophy and autolysis of the digestive gland and may therefore represent a terminal condition.     

A critical evaluation of pollen-stratigraphic investigations of pre-Late Devensian sites in Scotland

This paper reviews pollen-stratigraphic evidence from proposed interglacial and pre-Late Devensian interstadial sites in Scotland. The paper has two major parts. In the first the stratigraphic details of each of the sites are summarised and discussed. The sites are classified as ‘interglacial’ or ‘interstadial’ according to the interpretations adopted by recent authors, though as discussed in later sections such distinction is problematic and somewhat arbitrary.In the second part general problems of interpretation are discussed in the light of the stratigraphic details. Problems of dating and correlation are severe since most of the sediments lie close to or beyond the limit of conventional radiocarbon dating. Thus the normal approach has been to use pollen-stratigraphic comparisons with type-sites in southern or eastern England. This practice is considered questionable. Problems of assessing the provenance of pollens and spores are perhaps even more important, and at some sites are so severe as to render pollen assemblages of limited value. The problems discussed are: (a) secondary reworking of pollen; (b) long-distance wind transport of nonregional pollen; (c) pollen deterioration and (d) low pollen concentrations.Many of the problems discussed are of general significance being applicable to late Quaternary pollen diagrams from other regions. In the concluding section of the paper certain procedures are proposed that may permit a clearer assessment of potential problems of taphonomy in pollen stratigraphy.