Contaminated groundwater in fractured bedrock can expose ecosystems to undesired levels of risk for extended periods due to prolonged back-diffusion from rock matrix to permeable fractures. Therefore, it is key to characterize the diffusive mass loading (intrusion) of contaminants into the rock matrix for successful management of contaminated bedrock sites. Even the most detailed site characterization techniques often fail to delineate contamination in rock matrix. This study presents a set of analytical solutions to estimate diffusive mass intrusion into matrix blocks, it is recovered by pumping and concentration rebound when pumping ceases. The analytical models were validated by comparing the results with (1) numerical model results using the same model parameters and (2) observed chloride mass recovery, rebound concentration, and concentration in pumped groundwater at a highly fractured bedrock site in Alberta, Canada. It is also demonstrated that the analytical solutions can be used to estimate the total mass stored in the fractured bedrock prior to any remediation thereby providing insights into site contamination history. The predictive results of the analytical models clearly show that successful remediation by pumping depends largely on diffusive intrusion period. The results of initial mass from the analytical model was used to successfully calibrate a three-dimensional discrete fracture network numerical model further highlighting the utility of the simple analytical solutions in supplementing the more detailed site numerical modeling. Overall, the study shows the utility of simple analytical methods to support long-term management of a contaminated fractured bedrock site including site investigations and complex numerical modeling. 相似文献
Newly metamorphosed Evechinus chloroticus (Val.) were observed in three larval cultures 36, 30, and 28 days after fertilisation, indicating that the free swimming larval life may last about 1 month. 相似文献
The precise application of risk assessment can lead to different conclusions about risk depending on how species are grouped in the assessment. We compared the use of different risk assessment methods for three different classes of pesticide, the herbicide diuron, the fungicide chlorothalonil, and the insecticide permethrin for marine and estuarine species. Permethrin was the most toxic pesticide to marine and estuarine crustaceans. Diuron was the most toxic pesticide to algae, and chlorothalonil was most toxic to early life stages of molluscs and other invertebrates. Toxicity data (96 h LC50/EC50 values) were analyzed using a probability distribution on the ranked toxicity values and 10th centile values were calculated based on different groups of species and for all species combined. Our results indicate that an assessment of risk based on smaller taxonomic groups can be informative, especially for pesticides of less specific modes of action such as chlorothalonil. 相似文献
Understanding the Changing Planet is the latest in a long line of reports that makes the case for the relevance of the discipline of geography by invoking big “S” science. My commentary argues that this model of science, with its celebration of large data sets, sophisticated methodological techniques, and various material tools and hardware, is only one model of geography's contribution. Instead, I suggest that the strength of geography is in its pluralism and methodological variety, and in the end that will do more for understanding the changing planet than anything else. 相似文献
Dubovikov and Canuto (Dubovikov, M.S. and Canuto, V.M., Complete Eulerian-mean tracer equation for coarse resolution OGCMs. Geophys. Astrophys. Fluid Dyn., 2006, 100, 197–214), after averaging the tracer conservation equation in density coordinates and transforming to height coordinates, concluded that present ocean models are missing important terms in their mean tracer equations. Here we point out some errors made by Dubovikov and Canuto (2006Dubovikov, MS and Canuto, VM. 2006. Complete Eulerian-mean tracer equation for coarse resolution OGCMs. Geophys. & Astrophys. Fluid Dynam., 100: 197–214. [Taylor & Francis Online], [Web of Science ®], [Google Scholar]) in their isopycnal averaging procedure. We draw on the temporal-residual-mean (TRM) theory and show that when the isopycnal averaging and coordinate transformation are performed correctly, the tracer equations of present ocean circulation models are recovered. We therefore conclude that present ocean circulation models are not neglecting the leading order terms identified by Dubovikov and Canuto (2006Dubovikov, MS and Canuto, VM. 2006. Complete Eulerian-mean tracer equation for coarse resolution OGCMs. Geophys. & Astrophys. Fluid Dynam., 100: 197–214. [Taylor & Francis Online], [Web of Science ®], [Google Scholar]). 相似文献
TIMS and SHRIMP U–Pb analyses of zircons from Milford Orthogneiss metadiorite (P = 1–1.4 GPa; T ≥ 750°C) of the Arthur River Complex of northern Fiordland reveal a bimodal age pattern. Zircons are predominantly either
Paleozoic (357.0 ± 4.2 Ma) and prismatic with oscillatory zoning, or Cretaceous (133.9 ± 1.8 Ma) and ovoid with sector or
patchy zoning. The younger age component is not observed overgrowing older grains. Most grains of both ages are overgrown
by younger Cretaceous (~120 Ma) metamorphic zircon with very low U and Th/U (0.01). We interpret the bimodal ages as indicating
initial igneous emplacement and crystallisation of a dioritic protolith pluton at ~357 Ma, followed by Early Cretaceous granulite-facies
metamorphism at ~134 Ma, during which a significant fraction (~60%) of the zircon grains dissolved, and subsequently reprecipitated,
effectively in situ, in partial melt pockets. The remaining ~40% of original Paleozoic grains were apparently not in contact
with the partial melt, remained intact, and show only slight degrees of Pb loss. Sector zoning of the Cretaceous grains discounts
their origin by solid state recrystallisation of Paleozoic grains. The alternative explanation—that the Paleozoic component
represents a 40% inherited component in an Early Cretaceous transgressive dioritic magma—is considered less likely given the
relatively high solubility of zircon in magma of this composition, the absence of 134 Ma overgrowths, the single discrete
age of the older component, equivalent time-integrated 177Hf/176Hf compositions of both age groups, and the absence of the Cambrian-Proterozoic detrital zircon that dominates regional Cambro-Ordovician
metasedimentary populations. Similar bimodal Carboniferous-Early Cretaceous age distributions are characteristic of the wider
Arthur River Complex; 8 of 12 previously dated dioritic samples have a Paleozoic component averaging 51%. Furthermore, the
age and chemical suite affinity of these and several more felsic rocks can be matched with those of the relatively unmetamorphosed
Carboniferous plutonic terrane along the strike of the Mesozoic margin in southern Fiordland, also supporting the in situ
derivation of the Carboniferous “inherited” component. 相似文献
We present an Atlas of ShakeMaps and a catalog of human population exposures to moderate-to-strong ground shaking (EXPO-CAT)
for recent historical earthquakes (1973–2007). The common purpose of the Atlas and exposure catalog is to calibrate earthquake
loss models to be used in the US Geological Survey’s Prompt Assessment of Global Earthquakes for Response (PAGER). The full
ShakeMap Atlas currently comprises over 5,600 earthquakes from January 1973 through December 2007, with almost 500 of these
maps constrained—to varying degrees—by instrumental ground motions, macroseismic intensity data, community internet intensity
observations, and published earthquake rupture models. The catalog of human exposures is derived using current PAGER methodologies.
Exposure to discrete levels of shaking intensity is obtained by correlating Atlas ShakeMaps with a global population database.
Combining this population exposure dataset with historical earthquake loss data, such as PAGER-CAT, provides a useful resource
for calibrating loss methodologies against a systematically-derived set of ShakeMap hazard outputs. We illustrate two example
uses for EXPO-CAT; (1) simple objective ranking of country vulnerability to earthquakes, and; (2) the influence of time-of-day
on earthquake mortality. In general, we observe that countries in similar geographic regions with similar construction practices
tend to cluster spatially in terms of relative vulnerability. We also find little quantitative evidence to suggest that time-of-day
is a significant factor in earthquake mortality. Moreover, earthquake mortality appears to be more systematically linked to
the population exposed to severe ground shaking (Modified Mercalli Intensity VIII+). Finally, equipped with the full Atlas
of ShakeMaps, we merge each of these maps and find the maximum estimated peak ground acceleration at any grid point in the
world for the past 35 years. We subsequently compare this “composite ShakeMap” with existing global hazard models, calculating
the spatial area of the existing hazard maps exceeded by the combined ShakeMap ground motions. In general, these analyses
suggest that existing global, and regional, hazard maps tend to overestimate hazard. Both the Atlas of ShakeMaps and EXPO-CAT
have many potential uses for examining earthquake risk and epidemiology. All of the datasets discussed herein are available
for download on the PAGER Web page ().
T. I. Allen and M. G. Hearne—contracted through Synergetics Incorporated. 相似文献
The purposes of the paper are to provide a historical and thematic review of some of the variants of American philosophical pragmatism (old and new), and to point to its potential relevance for geography. The paper is divided into three sections. The first, discusses the origins of American pragmatism focussing on four figures: John Dewey, Oliver Wendell Holmes, William James, and Charles Sanders Peirce. Following the argument of Louis Menand (2001) in The Metaphysical Club, I will suggest that pragmatism took on its peculiar American character as a response to the deep fissures and wounds caused by that country’s Civil War. That war produced a loss of faith, undermining notions of universal progress and absolute truth. Pragmatism was the reaction. The second section brings pragmatism to the present, by focussing on three connected contemporary American pragmatists: Richard Rorty, Richard Bernstein, and Richard Shusterman. The hallmark of their work, and which justifies treating them as a group, is a willingness to stretch pragmatism: first, by making linkages with other anti-foundational, practice-based philosophical traditions, especially those within Continental European philosophy, and which had been shut out of Anglo-American philosophy after the Second World War by the rise of analytic philosophy; and second, by applying pragmatist ideas to issues like the body and popular culture to which it had never been applied. Finally, in the conclusion the paper reflects on the prospects of tethering pragmatism to the work of human geographers. Given the anti-architectonic impulses of pragmatism, such a project cannot simply be one of holus-bolus transferring pragmatism to geography. A different approach is needed, and which is schematically outlined and briefly illustrated using the idea of place. 相似文献
Agriculture is responsible for approximately 25% of anthropogenic global GHG emissions. This significant share highlights the fundamental importance of the agricultural sector in the global GHG emissions reduction challenge. This article develops and tests a methodology for the integration of agricultural and energy systems modelling. The goal of the research is to extend an energy systems modelling approach to agriculture in order to provide richer insights into the dynamics and interactions between the two (e.g. in competition for land-use). We build Agri-TIMES, an agricultural systems module using the TIMES energy systems modelling framework, to model the effect of livestock emissions and explore emissions reduction options. The research focuses on Ireland, which is an interesting test case for two reasons: first, agriculture currently accounts for about 30% of Ireland's GHG emissions, significantly higher than other industrialized countries yet comparable with global levels (here including emissions associated with other land-use change and forestation); second, Ireland is both a complete and reasonably sized agricultural system to act as a test case for this new approach. This article describes the methodology used, the data requirements, and technical assumptions made to facilitate the modelling. It also presents results to illustrate the approach and provide associated initial insights.
Policy relevance
Most of the policy focus with regard to climate mitigation targets has been on reducing energy-related CO2 emissions, which is understandable as they represent by far the largest source of emissions. Non-energy-related GHG emissions – largely from agriculture, industrial processes, and waste – have received significantly less attention in policy discourse. Going forward, however, if significant cuts are made in energy-related CO2 emissions, the role of non-energy-related GHG emissions will grow in importance. It is therefore crucial that climate mitigation analyses and strategies are not limited to the energy system. This article shows the value of using integrated energy and agriculture techno-economic modelling techniques to draw evidence for new comprehensive climate policy strategies able to discern between the full range of technical solutions available. It enables the production of economy-wide least-cost climate mitigation pathways. 相似文献