Ultrahigh-pressure metamorphic rocks and the thermal evolution of continent collision belts

Abstract Coesite-bearing eclogites exposed in the Alpine, Qinling-Dabie (China), Caledonian, and Ural orogenic belts provide insight into the time-dependent thermal structure of continent collision belts. Coesite-bearing eclogites record peak metamorphic temperatures of 550-900°C at pressures ≥ 2.5 GPa reflecting anomalously cool conditions at depths of 90 km or more. The low temperatures recorded by coesite-bearing eclogites strongly suggest formation in a convergent plate margin where the downward advection of cool lithosphere depresses isotherms on a regional scale. Subduction zone pressure-temperature (P-T) paths calculated using a two-dimensional finite-difference model predict steady-state temperatures of 450-650°C at 100 km depth at the slab-mantle interface for convergence rates of 10 to 100 mm/yr. Coesite-bearing eclogites record peak temperatures ~100-250°C higher, possibly reflecting (i) formation during the early stages of convergence prior to the achievement of thermal steady state; (ii) attainment of peak metamorphic temperatures during decompression (exhumation); (iii) formation during slow, <10 mm/yr, convergence; or (iv) uncertainties in the modeling parameters. Retrograde P-T paths determined for coesite-bearing eclogites from the western Alps and China indicate cooling during decompression from depths of ~100 km. Cooling of eclogite terrains during exhumation requires loss of heat downward into lithosphere that continues to subduct beneath the eclogites, loss of heat upward into the cooler hanging wall of a large-scale normal fault/shear zone, or a combination of the two scenarios.     

Seismic velocities in fractured rocks: an experimental verification of Hudson's theory1

Flow of fluids in many hydrocarbon reservoirs and aquifers is enhanced by the presence of cracks and fractures. These cracks could be detected by their effects on propagation of compressional and shear waves through the reservoir: several theories, including Hudson's, claim to predict the seismic effects of cracks. Although Hudson's theory has already been used to calculate crack densities from seismic surveys, the predictions of the theory have not yet been tested experimentally on rocks containing a known crack distribution. This paper describes an experimental verification of the theory. The rock used, Carrara marble, was chosen for its uniformity and low porosity, so that the effect of cracks would not be obscured by other influences. Cracks were induced by loading of laboratory specimens. Velocities of compressional and shear waves were measured by ultrasound at 0.85 MHz in dry and water-saturated specimens at high and low effective pressures. The cracks were then counted in polished sections of the specimens. In ‘dry’ specimens with both dry and saturated cracks, Hudson's theory overpredicted observed crack densities by a constant amount that is attributed to the observed value being systematically underestimated. The theory made poor predictions for fully saturated specimens. Shear-wave splitting, caused by anisotropy due to both crystal and crack alignment, was observed. Cracks were seen to follow grain boundaries rather than the direction of maximum compression due to loading. The results demonstrate that Hudson's theory may be used in some cases to determine crack and fracture densities from compressional- and shear-wave velocity data.     

Serpentinization and infiltration metasomatism in the Trinity peridotite,Klamath province,northern California: implications for subduction zones

The Trinity peridotite was emplaced over metabasalts and metasedimentary rocks of the central metamorphic belt along the Devonian Trinity thrust zone. Three metamorphic events can be recognized in the Trinity peridotite: (1) antigorite (D= –63 to –65%.) formation related to regional underthrusting of the central metamorphic belt; (2) contact metamorphism associated with Mesozoic dioritic plutons; and (3) late-stage formation of lizardite ± brucite and chrysotile (D= –127 to –175%.) due to infiltration of meteoric waters. Abundant relict phases indicate incomplete reactions and strongly suggest that the availability of H₂O was a controlling factor during serpentinization.Antigorite (event 1) formed as a result of infiltration into the Trinity peridotite of mixed H₂O-CO₂ fluids derived from the underlying central metamorphic belt. Foliation defined by magnetite veins and shear zones within antigorite serpentinites are subparallel to the Trinity thrust. The assemblage Fo + Atg + Chl + Mag ± Tr ± Carb reflects partial hydration of peridotite at 425–570° C. Talc-rich serpentinite formed along the thrust as a result of the infiltration of silica-bearing fluids. Metasomatic mass-balance calculations based on silica solubilities and the extent of antigorite serpentinization suggest that 80–175 volumes of fluid have passed through a given volume of original peridotite at the Trinity thrust.The Trinity thrust probably represents a Devonian subduction zone. Thermodynamic calculations suggest that hydration reactions account for 30–35% of the total heat released by the cooling Trinity peridotite. By analogy, similar hydration reactions are to be expected in the overlying mantle wedge of a subduction zone which act to retard cooling of the hanging wall, just as dehydration reactions delay heating of the downgoing slab. Metasomatic zones formed in peridotite at the Trinity thrust may reflect similar metasomatic processes to those proposed to occur in the mantle wedge above a subducting slab.     

The solar coronal green line as an index of cosmic ray modulation

In recent years several papers have indicated that the solar coronal green line emission (λ=5303Å) is the ‘best’ indicator of cosmic ray modulation. This paper questions this result for the following reasons: (a) the problems of green line measurement obscure the true meaning of the resulting observations; (b) there is a lack of any direct physical mechanism relating green line intensity and modulation; (c) a negative result came from a careful attempt to relate the cosmic ray diurnal variation and green line emission.     

Glacigenic rafting at Castle Hill,Gardenstown, and its significance for the glacial history of northern Banffshire,Scotland

Reinvestigation of the lower part of the key Quaternary section at Castle Hill, Gardenstown, has shown that the sediments are not in stratigraphical order, but consist chiefly of glaciotectonites, including rafts of soft sediments, which were deposited by ice moving southeastwards from the Moray Firth. Sedimentary structures are preserved in some of the rafts, which are separated by subhorizontal shears. The rafts accreted subglacially under conditions of moderate to high strain, the final glacial event being the deposition of a thin, discontinuous sheet of till, probably derived from a more westerly direction. It is proposed that interbedded dark grey shelly clay, till and sand elsewhere in northern Banffshire were emplaced, at least in part, by a similar mechanism during either the Middle Devensian, or more likely, the Late Devensian. Sand and clay with paired bivalve shells, which were formerly exposed within the Quaternary successions at Castle Hill and inland at King Edward, some 12 km to the south, are interpreted to be within glacigenic rafts, and are not in situ deposits formed during a widespread marine transgression. It is suggested that the alternation of phases of constructional and excavational deformation within a single glacial event rather than discrete glaciations provides a useful model for glacial deposition in northern Banffshire, and more generally in northeast Scotland. © 1997 John Wiley & Sons, Ltd.     

Oil well produced water discharges to the North Sea. Part I: comparison of deployed mussels (Mytilus edulis), semi-permeable membrane devices, and the DREAM model predictions to estimate the dispersion of polycyclic aromatic hydrocarbons

The oil companies operating in the Norwegian sector of the North Sea have conducted field studies since the mid-1990s to monitor produced water discharges to the ocean. These studies have been used to refine monitoring methods, and to develop and validate a dispersion and impact assessment model. This paper summarizes monitoring data from surveys conducted in two major oil and gas production areas, and compares the results to concentrations of polycyclic aromatic hydrocarbons (PAH) in surface waters predicted by the dose-related risk and effect assessment model (DREAM). Blue mussels and semi-permeable membrane devices (SPMDs) were deployed in the Ekofisk and Tampen Regions and analyzed for more than 50 PAH. PAH concentrations in ambient seawater were estimated based on the mussels and SPMD concentrations, and compared to model predictions. Surface water total PAH concentrations ranged from 25 to 350 ng/L within 1 km of the platform discharges and reached background levels of 4-8 ng/L within 5-10 km of the discharge; a 100,000-fold dilution of the PAH in the discharge water. The PAH concentrations in surface water, predicted by three methods, compared well for the Ekofisk Region. The model predicted higher concentrations than the field-based methods for parts of the Tampen Region; particularly the most tidally influenced areas. Tidally-mediated fluctuations in PAH concentrations in surface water must be considered because they affect the estimation of PAH concentrations from mussel and SPMD residue data, and the predictions by the DREAM model. Predictions using mussels, SPMDs, and modeling support and complement each other; all are valuable tools for estimating the fate and impact of chemical contaminants in produced water that are discharged to the ocean.     

Oil well produced water discharges to the North Sea. Part II: comparison of deployed mussels (Mytilus edulis) and the DREAM model to predict ecological risk

Large volumes of water often are produced with oil and gas from offshore platforms. The produced water is separated from the oil and gas and either reinjected into a deep formation or discharged to the ocean. The Norwegian oil and gas industry advocates ecological risk assessment as the basis for managing produced water discharges to the North Sea. In this paper, we compare estimates of ecological risks to water-column communities based on data on hydrocarbon residues in soft tissues of blue mussels deployed for a month near offshore platforms and based on predictions of the Dose related Risk and Effect Assessment Model (DREAM). The study was performed near produced water discharges to the Tampen and Ekofisk Regions of the Norwegian Sector of the North Sea. Because polycyclic aromatic hydrocarbons (PAH) are considered the most important contributors to the ecological hazard posed by produced water discharges, comparisons made here focus on this group of compounds. The mussel approach is based on predicted environmental concentrations (PECs) of individual PAH, estimated from PAH residues in mussels following deployment for a month near several produced water discharges, and predicted no effects concentrations (PNECs) based on a K(ow) regression model. In the DREAM method, PECs for three PAH fractions are estimated in the three-dimensional area around produced water discharge with the DREAM model. PNECs for each fraction are based on the chronic toxicity of a representative PAH from each fraction divided by an assessment factor to account for uncertainty in the chronic value. The mussel method gives much lower estimates of ecological risk than the DREAM method. The differences are caused by the much lower PNECs used in DREAM than derived from the regression model, and by the lower concentrations of aqueous PAH predicted by DREAM than estimated from PAH residues in mussel tissues. However, the two methods rank stations at different distances from produced water discharges in the same order and both identify 2- and 3-ring PAHs as the main contributors to the ecological risk of produced water discharges. Neither method identifies a significant ecological risk of PAH in the upper water column of the oil fields. The DREAM model may produce an overly conservative estimate of ecological risk of produced water discharges to the North Sea.     

Brecciation driven by changes in fluid column heights

A mechanism is presented for the pulses of high fluid pressure (P_F) necessary for fluid‐assisted brecciation. Establishment of hydraulic‐ or pneumatic‐connectivity between rock masses with different P_F can cause overpressure in the higher rocks because the P_F gradient is parallel to the hydrostatic gradient (the centroid effect). P_F can become high enough to create a fracture network, with an influx of fluids and mineralisation occurring as fluids migrate to areas of lower P_F. Changes in P_F caused by the centroid effect can cause other structures and seismicity.