Timescales of magma differentiation from basalt to andesite beneath Hekla Volcano, Iceland: Constraints from U-series disequilibria in lavas from the last quarter-millennium flows

Measurements of ²³⁸U-²³⁰Th-²²⁶Ra disequilibria, Sr-Nd-Pb-Hf isotopes and major-trace elements have been conducted for lavas erupted in the last quarter-millennium at Hekla volcano, Iceland. The volcanic rocks range from basalt to dacite. Most of the lavas (excluding dacitic samples) display limited compositional variations in radiogenic Sr-Nd-Pb-Hf isotopes (⁸⁷Sr/⁸⁶Sr = 0.70319-0.70322; ¹⁴³Nd/¹⁴⁴Nd = 0.51302-0.51305; ²⁰⁶Pb/²⁰⁴Pb = 19.04-19.06; ²⁰⁷Pb/²⁰⁴Pb = 15.53-15.54; ²⁰⁸Pb/²⁰⁴Pb = 38.61-38.65; ¹⁷⁶Hf/¹⁷⁷Hf = 0.28311-0.28312). All the samples possess (²³⁰Th/²³⁸U) disequilibrium with ²³⁰Th excesses, and they show systematic variations in (²³⁰Th/²³²Th) and (²³⁸U/²³²Th) ratios. The highest ²²⁶Ra excesses occur in the basalt and most differentiated andesite lavas, while some basaltic-andesite lavas have (²²⁶Ra/²³⁰Th) ratio that are close to equilibrium. The ²³⁸U-²³⁰Th-²²⁶Ra disequilibria variations cannot be produced by simple closed-system fractional crystallization with radioactive decay of ²³⁰Th and ²²⁶Ra in a magma chamber. A closed-system fractional crystallization model and assimilation and fractional crystallization (AFC) model indicate that the least differentiated basaltic andesites were derived from basalt by fractional crystallization with a differentiation age of ∼24 ± 11 kyr, whereas the andesites were formed by assimilation of crustal material and fractionation of the basaltic-andesites within 2 kyr. Apatite is inferred to play a key role in fractionating the parent-daughter nuclides in ²³⁰Th-²³⁸U and ²²⁶Ra-²³⁰Th to make the observed variations. Our proposed model is that several batches of basaltic-andesite magmas that formed by fractional crystallization of a basaltic melt from a deeper reservoir, were periodically injected into the shallow crust to form individual magma pockets, and subsequently modifying the original magma compositions via simultaneous assimilation and fractional crystallization. The assimilant is the dacitic melt, which formed by partial melting of the crust.     

Physical properties of the shallow sediments in late Pleistocene formations,Ursa Basin,Gulf of Mexico,and their implications for generation and preservation of shallow overpressures

Understanding the evolution of abnormally high fluid pressures within sedimentary formations is critical for analysing hydrogeological processes and assessing drilling risks. We have constructed a two-dimensional basin model and have performed numerical simulations to increase the understanding of the history of fluid flow and shallow overpressures in the Pleistocene and Holocene formations in the Ursa basin, deepwater Gulf of Mexico. We measured physical properties of sediments, such as porosity and permeability, in the laboratory and estimated in situ pore pressures from preconsolidation pressures. We obtained porosity–effective stress relationships from measurements of bulk density, grain density and preconsolidation pressures in the laboratory. Porosity–effective stress relationships were also obtained from downhole density logs and measured pore pressures. The porosity–effective stress and porosity–permeability relationships obtained were applied in two-dimensional basin simulations. Results showed that high pore pressures developed shortly after sediment deposition. Peaks in pore pressure ratios were related to high sedimentation rates of mass transport deposits and the incision of the Ursa channel. Lateral flows from the area where the overburden is thick towards the area where it is thin have occurred at least since 30 ka. Present pore pressure and temperature distributions suggest that lateral flows play a role in re-distributing heat in the basin.     

Trace-element characteristics of east–west mantle geochemical hemispheres

Recent statistical analyses on the isotopic compositions of oceanic, arc, and continental basalts have revealed that the Earth's mantle is broadly divided into eastern and western hemispheres. The present study aimed to characterize the isotopically defined east–west geochemical hemispheres using trace-element concentrations. Basalt data with Rb, Sr, Nd, Sm, Pb, Th, and U in addition to the isotopic ratios ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb were selected mostly from the GEOROC and PetDB databases. A total of 4787 samples were used to investigate the global geochemical variations. The results show that the wide trace-element variations are broadly explained by the melting of melt-metasomatized and fluid-metasomatized mantle sources. The larger amount of the fluid component derived from subducted plates in the eastern hemisphere than that in the western hemisphere is inferred from the basalts. These characteristics support the hypothesis that focused subduction towards the supercontinent created the mantle geochemical hemispheres.     

Vesicle layering in solidified intrusive magma bodies: a newly recognized type of igneous structure

 We report a novel type of layering structure in igneous rocks. The layering structure in the Ogi picrite sill in Sado Island, Japan, is spatially periodic, and appears to be caused by the variation in vesicle volume fraction. The gas phase forming the vesicles apparently exsolved from the interstitial melt at the final stage of solidification of the magma body. We call this type of layering caused by periodic vesiculation in the solidifying magma body "vesicle layering." The presence of vesicle layering in other basic igneous bodies (pillow lava at Ogi and dolerite sill at Atsumi, Japan) implies that it may be a fairly common igneous feature. The width of individual layers slightly, but regularly, increases with distance from the upper contact. The layering plane is perpendicular to the long axes of columnar joints, regardless of gravitational direction, suggesting that the formation of vesicles is mainly controlled by the temperature distribution in the cooling magma body. We propose a model of formation of vesicle layering which is basically the same as that for Liesegang rings. The interplay between the diffusion of heat and magmatic volatiles in melt, and the sudden vesiculation upon supersaturation, both play important roles. Received: 15 February 1996 / Accepted: 24 June 1996     

Compositional relations of pyroxenes in a ferrogabbro from Beaver Bay intrusion,Minnesota

Four different types of pyroxene found in a Beaver Bay ferrogabbro were analysed by microprobe. The crystallization sequence of pyroxene is augite-ferroaugite with exsolution lamellae of Ca-poor clinopyroxene → ferropigeonite with exsolution lamellae of augite → ferrohypersthene without exsolution lamellae+augite and ferroaugite without exsolution lamellae. The core of augite-ferroaugite with exsolution lamellae is cumulus pyroxene, whereas others, including the margin of augite-ferroaugite with lamellae, are interpreted to have crystallized from the intercumulus liquid. The sequence of crystallization of minerals from intercumulus liquid is different from that of minerals which have accumulated successively to the bottom and which were related to the fractionation of the whole layered series. The difference may be attributed to the different oxidation state of crystallization.     

Surface morphological features of boulders on Asteroid 25143 Itokawa

On the sub-kilometer S-type asteroid, 25143 Itokawa, some boulders on rough terrains seem to be exposed without any powdery material covering. Based on surface morphological features, there are two major types of boulders: one has rounded edges and corners (rounded boulders), while the other has angular edges and corners (angular boulders). The surface features of the rounded boulders suggest that they have hardness heterogeneity and that some may be breccias. The angular boulders appear to be more resistant to impact disruption than the rounded ones, which may be due to a difference in lithology. The major constituents of Itokawa may be LL chondrite-like brecciated lithology (rounded boulders) along with a remarkable number of boulders suggesting that lithology is atypical among LL chondrites (angular boulders). Some of both types of boulders contain intersecting and stepped planar foliations. Comparison with meteorite ALH76009 suggests that the planar foliations may be marks where rocks were torn apart. As lithified breccias cannot be formed on present-day sub-kilometer-sized Itokawa, it is reasonable that boulders with various lithologies on Itokawa were formed on its large ancestor(s). The rubble-pile structure of Itokawa suggested by its low density (∼1.9 g/cm³) indicates that boulders on Itokawa are reassembled fragments formed by catastrophic disruption of large ancestor(s).     

A DETAILED CHEMICAL STUDY ON THE BARWISE CHONDRITE

Six fragments of the Barwise meteorite were analyzed for REE and eleven other elements (Al, Ca, Mg, Mn, Na, K, Cr, Fe, Co, Ni and Ba). In addition, two fragments were analyzed for Si and Mg. The chondrite-normalized REE patterns of six fragments studied show interesting systematic variations. Three fragments with relatively high La abundances show a negative Ce anomaly. Since the meteorite in question is a find, it could be suspected that the observed REE fractionations are due to terrestrial contamination. To examine this point, a soil sample from the find site was also analyzed for REE and major chemical elements. It is considered that several facts, especially, the relationships between La and SiO₂ and between SiO₂ and MgO, suggest the pre-terrestrial fractionation rather than the terrestrial contamination. Unexpectedly, it is shown that the REE fractionation observed in the investigated fragments correlates with the metal-silicate and the Fe-Co-Ni fractionations. In this connection, large metal grains were investigated for Fe, Co and Ni contents. A suggestion is presented that this chondrite was formed through the melting of the surface of a planetesimal and the subsequent collision, although the possibility of terrestrial contamination might not be ruled out.     

Geochemical evolution of a shallow magma plumbing system during the last 500 years, Miyakejima volcano, Japan: Constraints from U-Th-Ra systematics

In order to unravel magma processes and the geochemical evolution of shallow plumbing systems beneath active volcanoes, we investigated U-series disequilibria of rocks erupted over the past 500 years (1469-2000 AD) from Miyakejima volcano, Izu arc, Japan. Miyakejima volcanic rocks show ²³⁸U-²³⁰Th-²²⁶Ra disequilibria with excess ²³⁸U and ²²⁶Ra, due to the addition of slab-derived fluids to the mantle wedge. Basaltic bombs of the 2000 AD eruption have the lowest (²³⁰Th/²³²Th) ratio compared to older Miyakejima eruptives, yielding the youngest ²³⁸U-²³⁰Th model age of 2 kyr. This reinforces our previous model that fluid release from the slab and subsequent magma generation in the mantle wedge beneath Miyakejima occur episodically on a several-kyr timescale. In the last 500 years, Miyakejima eruptives show: (1) a vertical trend in a (²³⁰Th/²³²Th)-(²³⁸U/²³²Th) diagram and (2) a positive linear correlation in a (²²⁶Ra/²³⁰Th)₀ − 1/²³⁰Th diagram, which is also observed in lavas from some of the single eruptions (e.g., 1940, 1962, and 1983 AD). The variations cannot be produced by simple fractional crystallization in a magma chamber with radioactive decay of ²³⁰Th and ²²⁶Ra, but it is possibly produced by synchronous generation of melts in the mantle wedge with different upwelling rate or addition of multiple slab-derived fluids. A much more favorable scenario is that some basaltic magmas were intermittently supplied from deep in the mantle and injected into the crust, subsequently modifying the original magma composition and producing variations in (²³⁰Th/²³²Th) and (²²⁶Ra/²³⁰Th)₀ ratios via assimilation and fractional crystallization (AFC). The assimilant of the AFC process would be a volcanic edifice of previous Miyakejima magmatism. Due to the relatively short timescales involved, the interaction between the assimilant and recent Miyakejima magmatism has not been recorded by the Sr-Nd-Pb isotopic systems. In such cases, Th isotopes and (²²⁶Ra/²³⁰Th) ratio are excellent geochemical tracers of magmatic evolution.     

Artificial radionuclides in the western Northwest Pacific (I)90Sr and137Cs in the deep waters

⁹⁰Sr and¹³⁷Cs concentrations and their vertical distributions were determined in deep waters in the western Northwest Pacific, including the adjacent seas of Japan, from 1976 to 1979.The profiles of the radionuclides show distribution patterns with two parts with an exponential variation of radioisotope content with depth in both parts.Generally speaking, the inventories of⁹⁰Sr and¹³⁷Cs in the open waters of the northwestern Pacific correspond fairly well to the fallout inputs, but in some circumstances there seems to be considerable removal of radionuclides from the water column or they are diluted with water of lower radioactivity from other regions.The possibility of radioisotope remobilization from the bottom sediment or particulate matter is also discussed.