Discovery of the most distal Ries tektites found in Lower Silesia,southwestern Poland

We report the first occurrence of moldavites in Poland. This discovery confirms the hypothesis that moldavites could have been distributed up to 500 km from the Ries crater in Germany. The tektites were reworked from Middle Miocene sediments and redeposited in Late Miocene (Pannonian) fluvial deposits of the Gozdnicka Formation in Lower Silesia. The Polish moldavites are represented by nine (<8 mm) fragments with a total of 0.471 g. The lack of the autochthonous tektites indicates that tektites investigated here had to be redeposited in a fluvial environment, probably from the Lusatian area. The chemical composition of the Polish moldavites plots in the same area with those from other localities.     

Monitoring In Situ Biodegradation of MTBE Using Multiple Rounds of Compound‐Specific Stable Carbon Isotope Analysis

At a large industrial facility, methyl tert‐butyl ether (MTBE) was released to the subsurface and dispersed into the light, non‐aqueous phase liquids (LNAPL), in the first aquifer, with the LNAPL serving as a continuous source of MTBE in groundwater. Compound‐specific isotope analysis was conducted on both MTBE and tert‐butyl alcohol (TBA) in groundwater samples collected in 2008, 2011, and 2013 from wells located along and off the center line of the MTBE plume. The study demonstrated the onset and progress of biodegradation of MTBE between 2008 and 2013. The TBA observed in 2008 appears to be derived only in part from MTBE transformation while a significant portion of TBA might be contributed directly from LNAPL sources. In 2011 to 2013, the dominant source of TBA in the mid‐gradient plume was MTBE transformation. A contribution of an offsite LNAPL source, in particular to the down‐gradient area of the plume, is possible but could not be unequivocally confirmed. The time series provided direct evidence for MTBE biodegradation, but also a valuable insight on the sources of TBA.     

Pareto Joint Inversion of 2D Magnetotelluric and Gravity Data — Towards Practical Applications

In this paper, a Pareto inversion based global optimization approach, to obtain results of joint inversion of two types of geophysical data sets, is formulated. 2D magnetotelluric and gravity data were used for tests, but presented solution is flexible enough to be used for combination of any kind of two or more target functions, as long as misfits can be calculated and forward problems solved. To minimize dimensionality of the solution, space and introduce straightforward regularization Sharp Boundary Interface (SBI) method was applied. As a main optimization engine, Particle Swarm Optimization (PSO) was used. Synthetic examples based on a real geological model were used to test proposed approach and show its usefulness in practical applications.     

A reconstruction of the palaeohydrological conditions of a flood‐plain: a multi‐proxy study from the Grabia River valley mire,central Poland

This study investigated the Grabia River valley mire in central Poland to reconstruct its palaeoenvironmental conditions from the Younger Dryas to the present. We analysed sedimentological, biological and geochemical data from the palaeo‐oxbow lake and valley mire to identify the principal hydrological trends, especially episodes of high water level. During the Lateglacial and Holocene, the Grabia River had a meandering channel, and its hydraulic parameters and the channel dimensions changed in response to climatic oscillations and vegetation development. We identified phases of high flood intensity and high groundwater level that correlate with regional and supraregional climatic events. The frequency and timing of palaeohydroclimatic oscillations show strong similarities to records from other sites in Poland and the rest of Europe. We show that various analytical methods, namely, pollen, plant macrofossils, Cladocera, Chironomidae, sedimentological, geochemical and radiocarbon data, can be effective tools for reconstructing past hydroclimatic changes in palaeo‐oxbow lakes and investigating the effects of past climate changes on river environments. The high sensitivity of the biota, especially Cladocera, to changes in water level permits the reconstruction of palaeoecological changes, especially flood episodes that occurred in the river valley. In particular, the increase in the proportion of sediment‐associated Cladocera and pelagic taxa was closely correlated with floods. Through comparisons with the palaeobiological data, geochemical data allowed the identification of humid phases within the fen associated with a rising groundwater table, direct fluvial activity (floods) and alluvial deposition. We also discuss the limitations of palaeohydrological reconstructions based on these proxies, especially on fossil aquatic invertebrates.     

Web Service for extracting stream networks from DEM data

This paper describes the implementation of a morphology based algorithm for extracting stream networks from data as a Web Service within the framework of GeoBrain, an open, interoperable, distributed, standard-compliant, multi-tier web-based geospatial information services and knowledge building system. Unlike standard out-of-the-box GIS software, which uses the flow direction based algorithm and often produces streams that are spatially uniform, streams extracted with this Web Service correctly reflect spatial variability in dissection patterns. In addition, this Web Service is free and can be accessed from anywhere provided that there is an Internet connection and a standard Web browser.     

The use of selected research methods to describe the pore space of dolomite from copper ore mine,Poland

Basic knowledge of the characteristics of copper-bearing rock such as dolomite is essential to locate those areas of the deposit which have different structural and textural properties. Those regions can be important in terms of the assessment of the possibilities of gas accumulating in them as well as in terms of gasogeodynamic hazard. To better understand those threats, it is necessary to locate, monitor and analyse those areas in detail. This article characterises the structural and textural parameters of dolomite from the Polkowice–Sieroszowice copper mine in Poland. The study involved five samples from various areas of the mine. A number of research methods were selected. Reflected and transmitted light microscopy (MS), computer microtomography (Micro-CT), gas adsorption porosimetry (LPNA), mercury porosimetry (MIP), helium and quasi-fluid pycnometry (Pycno. He, DryFlo). Each of the methods examined a different scope of the pore size, which enabled to achieve a full view of the porous nature of those rocks. We determined their porosity (open, closed, total), surface area as well as mean size and volume of the pores. Also, we studied the character and the pore size distribution from a few nm to a few mm. Comprehensive dolomite properties analyses showed that these rocks are characterised by high structural variability. They have mesopores and macropores but few micropores. The analyses presented in this paper are determined by a large petrographic diversity of the deposits containing dolomite. This article is an example of a comprehensive approach to the rock analysis in copper ore mines.     

A three-scale cracking criterion for drying soils

Cracking is a most unwanted development in soil structures undergoing periodic drying and wetting. Desiccation cracks arise in an apparent absence of external forces. Hence, either an internal, self-equilibrated stress pattern resulting from kinematic incompatibilities, or a stress resulting from reaction forces at the constraints appear as a cracking cause, when reaching tensile strength. At a meso-scale, tubular drying pores are considered in the vicinity of a random imperfection, inducing a stress concentration in the presence of significant pore suction. This approach allows one to use the effective stress analysis, which otherwise, away from the stress concentration, usually yields compressive effective stress and hence a physically incompatible criterion for a tensile crack. Recent experiments on idealized configurations of clusters of grains provide geometrical data suggesting that an imperfection as a result of air entry deep into the granular medium penetrates over 4 to 8 internal radii of a typical pore could yield a tensile effective stress sufficient for crack propagation.     

A data-based regional scale autoregressive rainfall-runoff model: a study from the Odra River

This paper aims to compare the performances of multivariate autoregressive (MAR) techniques and univariate autoregressive (AR) methods applied to regional scale rainfall-runoff modelling. We focus on the case study from the upper and middle reaches of the Odra River with its main tributaries in SW Poland. The rivers drain both the mountains (the Sudetes) and the lowland (Nizina Śląska). The region is exposed to extreme hydrologic and meteorological events, especially rain-induced and snow-melt floods. For the analysis, four hydrologic and meteorological variables are chosen, i.e., discharge (17 locations), precipitation (7 locations), thickness of snow cover (7 locations) and groundwater level (1 location). The time period is November 1971–December 1981 and the temporal resolution of the time series is of 1 day. Both MAR and AR models of the same orders are fitted to various subsets of the data and subsequently forecasts of discharge are derived. In order to evaluate the predictions the stepwise procedure is applied to make the validation independent of the specific sample path of the stochastic process. It is shown that the model forecasts peak discharges even 2–4 days in advance in the case of both rain-induced and snow-melt peak flows. Furthermore, the accuracy of discharge predictions increases if one analyses the combined data on discharge, precipitation, snow cover, and groundwater level instead of the pure discharge multivariate time series. MAR-based discharge forecasts based on multivariate data on discharges are more accurate than AR-based univariate predictions for a year with a flood, however, this relation is reverse in the case of the free-of-flooding year. In contrast, independently of the occurrence of floods within a year, MAR-based discharge forecasts based on discharges, precipitation, snow cover, and groundwater level are more precise than AR-based predictions.     

A thermo-plastic constitutive law for brittle-plastic behavior of rocks at high temperatures

Mechanical properties of rocks change under the influence of, temperature. Stress at the onset of yielding, ultimate strength, dilatancy, strain hardening and softening, and the confining pressure at brittle-ductile transition are all reduced by the increasing temperature. This study presents a framework of constitutive modeling of thermo-brittle-plastic behavior of rocks which encompasses these changes. The constitutive law is based on a thermo-plasticity theory first proposed for metals byPrager (1958). Two phenomenological mechanisms have been identified as central for the modeling: temperature dependence of the yield locus (thermal softening), and temperature dependence of the strain-hardening function (thermally enhanced ductility). Material parameters for two rocks, Carrara marble and Westerly granite, were determined on the basis of additional hypotheses. These parameters are used in numerical simulations of triaxial tests at different temperatures. The obtained stress-strain curves compare well to the experimental results. The changes with temperature in the stress at the onset of yielding are more accurately reproduced that the evolution of hardening or softening. Suggestions for possible improvements and future research directions are indicated.     

Creep of saturated materials as a chemically enhanced rate‐dependent damage process

Material behaviour that exhibits characteristics of creep induced by a spontaneous mineral dissolution enhanced by material damage is studied. It is believed that the characteristic rates of the chemical processes involved determine the time‐rate dependence of the resulting strain. A basic model of a combined chemo‐plastic softening and chemically enhanced deviatoric strain hardening for saturated geomaterials is presented. Chemical softening is postulated to occur as a consequence of the net mass removal resulting from dissolution and precipitation of specific minerals occurring at the damage‐generated inter‐phase interfaces. Closed and open systems are discussed. In the former case, deformation at constant stress results entirely from a local compensation mechanism between the chemical softening and strain hardening. The classical three stages of creep are interpreted in terms of mechanisms of dissolution and precipitation, as well as the variation in the reaction surface areas involved in the mass exchange. In an open system, the above local mechanism is enhanced by the removal of mass via diffusion of species affecting the mass balance. Such a system is addressed via a boundary value problem as shown in an example. Copyright © 2007 John Wiley & Sons, Ltd.