Progressive changes in lithological association of the Sanbagawa metamorphic complex,Southwest Japan: Relict clinopyroxene and detrital zircon perspectives

The main tectono‐stratigraphic unit (Shirataki unit) of the Sanbagawa metamorphic complex in central Shikoku is characterized by abundant mafic schist layers that show the mid‐ocean ridge basalt (MORB) affinity. These MORB‐derived schist layers are absent in a southern (structurally lower) domain within the unit. Instead, sporadic occurrences of small metabasite lenses that contain relict igneous minerals (Ti‐rich augite and kaersutite) indicative of alkali basalt magmatism are newly recognized in the southern domain. Compositions of relict clinopyroxene in metabasalt are useful to identify the tectonic setting and origin of the protolith basalt, and those in each unit of the Sanbagawa metamorphic complex are presented. The metamorphic grade of the Shirataki unit generally increases structurally upwards in the southern side of the highest‐grade zone, and metamorphic zonation is subparallel to lithostratigraphic succession. The protolith assemblage of the Shirataki unit shows a distinct change from the southern low‐grade domain (lower Shirataki subunit) composed of terrigenous sedimentary rocks (mudstone and sandstone) with minor alkali basalt to the northern higher‐grade domain (upper Shirataki subunit) consisting of terrigenous and pelagic sedimentary rocks with abundant MORB. The youngest detrital zircon U–Pb ages (ca 95–90 Ma) suggest that both domains have Late Cretaceous depositional ages at the trench. Progressive peeling of oceanic plate stratigraphy during subduction can account for the observed change of lithological association in the Shirataki unit.     

Dating of altered mafic intrusions by applying a zircon fission track thermochronometer to baked country rock,and implications for the timing of volcanic activity during the opening of the Japan Sea

Once a mafic intrusive rock has become altered, it is generally difficult to obtain a reliable intrusion age using conventional isotopic dating methods. To overcome this problem, this study used zircon fission track (ZFT) thermochronometry to determine the timing of crystallization of altered mafic intrusions. ZFT dating was carried out on samples of baked granite country rock adjacent to dolerite dikes (5–10 m thick) in the Takato area of central Japan. Three granite samples collected within 8 mm of a dike contact yielded consistent ZFT ages of 17–16 Ma, with confined track lengths indicative of the complete annealing of pre‐existing tracks by reheating due to dike intrusion. An older ZFT age was obtained for one granite sample collected within 20 mm of the contact, but confined track length measurements indicate that this is an incompletely reset age that lies between the ZFT age of the unbaked granitic country rocks (ca. 55 Ma) and the emplacement age of the dike. Petrographic examinations suggest that post‐intrusion hydrothermal activity did not influence the ZFT ages. We conclude that the 17–16 Ma ZFT age represents the emplacement age of the dikes. Our results show that ZFT dating of baked country rock is an effective tool for dating altered mafic intrusions, for which other dating techniques are not applicable. In the eastern part of Southwest Japan, dispersed volcanic activity occurred in the late Early to early Middle Miocene (18–15 Ma), and the volcanic belt extended into the forearc. This pulse of activity was possibly related to the injection of asthenospheric material into the trench‐side mantle wedge beneath the Japan arc. We also present young apatite fission track ages (ca. 4 Ma) that may reflect a Middle Miocene or later thermal event associated with local magmatic activity near the Takato area.     

Duluth Complex apatites: Age reference material for LA–ICP–MS‐based fission‐track dating

Anorthositic series apatites of the Duluth Complex, Minnesota, USA, have high spontaneous fission‐track densities of up to ~10⁷ cm^–2 and a homogeneous age of ~900 Ma, allowing high‐precision fission‐track dating based on LA–ICP–MS U analysis. Absolute fission‐track dating, track‐length measurement and chemical composition analysis were performed to evaluate a cooling history, which is essential for age reference materials. Preliminary inverse modelling for a sample with a shortened track‐length distribution yielded a monotonic cooling history from ~100°C at 925 Ma. The apatites incur an over‐etching problem when employing the commonly used etching protocol involving 5.5 M HNO₃.     

Statistical empirical index of chemical weathering in igneous rocks: A new tool for evaluating the degree of weathering

Chemical weathering indices are useful tools in characterizing weathering profiles and determining the extent of weathering. However, the predictive performance of the conventional indices is critically dependent on the composition of the unweathered parent rock. To overcome this limitation, the present paper introduces an alternative statistical empirical index of chemical weathering that is extracted by the principal component analysis (PCA) of a large dataset derived from unweathered igneous rocks and their weathering profiles. The PCA analysis yields two principal components (PC1 and PC2), which capture 39.23% and 35.17% of total variability, respectively. The extent of weathering is reflected by variation along PC1, primarily due to the loss of Na₂O and CaO during weathering. In contrast, PC2 is the direction along which the projections of unweathered felsic, intermediate and mafic igneous rocks appear to be best discriminated; therefore, PC1 and PC2 represent independent latent variables that correspond to the extent of weathering and the chemistry of the unweathered parent rock. Subsequently, PC1 and PC2 were then mapped onto a ternary diagram (MFW diagram). The M and F vertices characterize mafic and felsic rock source, respectively, while the W vertex identifies the degree of weathering of these sources, independent of the chemistry of the unweathered parent rock.

The W index has a number of significant properties that are not found in conventional weathering indices. First, the W index is sensitive to chemical changes that occur during weathering because it is based on eight major oxides, whereas most conventional indices are defined by between two and four oxides. Second, the W index provides robust results even for highly weathered sesquioxide-rich samples. Third, the W index is applicable to a wide range of felsic, intermediate and mafic igneous rock types. Finally, the MFW diagram is expected to facilitate provenance analysis of sedimentary rocks by identifying their weathering trends and thereby enabling a backward estimate of the composition of the unweathered source rock.     

Nouvelles données sur le téphra de Sarliève et le téphra CF7, marqueurs chrono-stratigraphiques de Grande Limagne (Massif central,France)

A trachytic tephra, discovered in the ancient lake of Sarliève, ‘Grande Limagne’, has been dated using the thermoluminescence technique. The obtained age, 16±4 ka ($\text{2}\text{σ}$), is older than that of the trachytic volcanoes of the Cha??ne des Puys, the ashes of which have already been locally recognised in the region. Its analysis confirms its originality. In the course of the comparisons made to search for its spring, it appears that the wide-dispersion tephra CF7, beforehand correlated by hypothesis to the Puy de Clierzou, probably originates from the Kilian crater or the Puy de Vasset. To cite this article: D. Miallier et al., C. R. Geoscience 336 (2004).     

Radiometric Zircon Ages of a Tuff Sample from the Baishantou Member of Wuyun Formation,Jiayin: A Contribution to the Search for the K‐T Boundary in Heilongjian River Area,China

The existence of the Cretaceous-Tertiary (K/T) boundary in the non-marine succession is expected at Jiayin in the Heilongjiang River area, China. Zircons from a tuff sample from the Baishantou Member of Wuyun Formation in Jiayin were analyzed by the laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U-Pb dating and fission-track dating methods. Ages of 64.1±0.7 Ma (U-Pb) and 61.7±1.8 Ma (fission-track dating) were obtained, which allow re-evaluation of a previously reported late Maastrichian age for the tuff layer that was in conflict with the paleontological evidence. These results confirm the Danian age of the section in agreement with the paleontological evidence.     

The effect of a hydrous phase on P‐wave velocity anisotropy within a detachment shear zone in the slow‐spreading oceanic crust: A case study from the Godzilla Megamullion,Philippine Sea

We studied the contributions of plagioclase, clinopyroxene, and amphibole to the P‐wave velocity properties of gabbroic mylonites of the Godzilla Megamullion (site KH07‐02‐D18) in the Parece Vela Rift of the central Parece Vela Basin, Philippine Sea, based on their crystal‐preferred orientations (CPOs), mineral modes, and elastic constants and densities of single crystals. The gabbroic mylonites have been classified into three types based on their microstructures and temperature conditions: HT1, HT2 and medium‐temperature (MT) mylonites. The P‐wave velocity properties of the HT1 mylonite are dominantly influenced by plagioclase CPOs. Secondary amphibole occurred after deformation in the HT1 mylonite, so that its effect on P‐wave velocity anisotropy is minimal due to weak CPOs. Although the HT2 mylonite developed deformation microstructures in the three minerals, the P‐wave velocity properties of the HT2 mylonite are essentially isotropic, resulting from the destructive interference of different P‐wave velocity anisotropy patterns produced by the distinct CPOs of the three constituent minerals (i.e., plagioclase, clinopyroxene, and amphibole). The P‐wave velocity properties of the MT mylonite are influenced mainly by amphibole CPOs, whereas the effect of plagioclase CPOs on P‐wave velocity anisotropy becomes very small with a decrease in the intensity of plagioclase CPOs. As a result, the gabbroic mylonites tend to have weak P‐wave velocity anisotropy in seismic velocity, although their constituent minerals show distinct CPOs. Such weakness in the whole‐rock P‐wave velocity anisotropy could result from the destructive contributions of the different mineral CPOs with respect to the structural framework (foliation and lineation). These results show that amphibole has a high potential for P‐wave velocity anisotropy by aligning both crystallographically and dimensionally during deformation in the hydrous oceanic crust. The results also suggest that the effect of a hydrous phase on P‐wave velocity anisotropy within the detachment shear zone in a slow‐spreading oceanic crust varies depending on the degree of deformation and on the timing of hydrothermal activity.     

An unconformity in the early Miocene syn-rifting succession, northern Noto Peninsula, Japan: Evidence for short-term uplifting precedent to the rapid opening of the Japan Sea

Abstract   The present paper describes the newly discovered early Miocene unconformity in the northern Noto Peninsula, on the Japan Sea side, central Japan. The unconformity marks the boundary between an early Miocene non-marine to marine succession and a more extensive, late early to early middle Miocene marine succession, and contains a time gap of an order of 1 million years or less from 18 Ma or earlier to 17 Ma. The early Miocene succession likely represents an early phase of marine transgression and initial slow rifting. The overlying early to early middle Miocene succession records the climax of the opening of the Japan Sea at ca  16 Ma with widespread, rapid subsidence of the Japan Arc. The unconformity between the two transgressive successions may represent a global sealevel fall or, more likely, crustal uplifting because no upward-shallowing or regressive facies remains between the two successions. Early Miocene unconformities that are thought to be correlative with this unconformity in the northern Noto Peninsula occur in places along the Japan Sea coast of Sakhalin and Japan. They are likely to have been produced during rifting in response to upwelling of asthenospheric mantle, although more accurate age constraints are necessary to evaluate this idea.     

Age and associated stress field of middle Miocene back-arc basalt magmatism in Northeast Japan

A large volume of middle Miocene basaltic rocks is widely distributed across the back-arc region of Northeast Japan, including around the Dewa Mountains. Petrological research has shown that basaltic rocks of the Aosawa Formation around the Dewa Mountains were generated as a result of the opening of the Sea of Japan. To determine the precise ages of the middle Miocene basaltic magmatism, we conducted U–Pb and fission-track (FT) dating of a rhyolite lava that constitutes the uppermost part of the Aosawa Formation. In addition, we estimated the paleostress field of the volcanism using data from a basaltic dike swarm in the same formation. The rhyolite lava yields a U–Pb age of 10.73 ±0.22 Ma (2σ) and a FT age of 10.6 ±1.6 Ma (2σ), and the paleostress analysis suggests a normal-faulting stress regime with a NW–SE-trending σ₃-axis, a relatively high stress ratio, and a relatively high magma pressure. Our results show that the late Aosawa magmatism occurred under NW–SE extensional stress and ended at ~ 11 Ma.