Urban and rural limestone weathering; the contribution of dust to black crust formation

A novel approach of studying dust, black crust and host limestones by using various techniques is presented in this paper. Samples were collected from limestone monuments located in rural, urban and industrial areas in Germany and Hungary. The paper focuses on differences in the mineralogical composition, major and trace element distribution of materials and their total polyaromatic hydrocarbons (PAH) concentration having different exposure to air pollutants. High concentration of gypsum was found in laminar and dendritic black crusts and even in the dust of both urban and rural areas, despite the low concentration of SO₂ in rural atmospheric environments. The black crusts show a typical microfabric with distinct layers of various gypsum–calcite mineral associations, silt-sized mineral fragments and black particle content. In dust, newly formed gypsum crystals were found along with mineral fragments, and siliceous and, less frequently, carbonaceous fly ash particles. High concentration of lead was found both in the samples of urban and rural areas of Germany and Hungary. Lead mostly accumulates in dust and also in the black crust. Highest lead concentrations were found not on the surface of the black crust, but close to the crust/limestone boundary according to LA-ICPMS analyses. It indicates that despite the ban of leaded petrol, lead is still present in the dust and the in the soiled zones of the built environment. Similarly to lead, no significant difference in the total PAH content of dust and crust samples were found in the two countries. Dusts are equally enriched in PAH in both countries, whereas black crusts contain fewer amounts. Most of the aqueous extracts of the samples were saturated with respect to sulphate, which also indicate the presence of gypsum, whilst in some German samples unsaturated conditions were detected. In summary, by using a combination of these analytical techniques, it was possible to distinguish rural and urban samples and to outline the role of dust in bringing pollutants to the stone surface. It is suggested that the analysed dust and stone samples indicate not only present, but also the past, pollution fluxes and as a consequence stones similar to sediments or surface waters can be used as environment indicators.     

Correlation between distribution and shape of VMS deposits and regional deformation patterns,Skellefte district,northern Sweden

The Skellefte district in northern Sweden is host to abundant volcanogenic massive sulphide (VMS) deposits comprising pyritic, massive, semi-massive and disseminated Zn–Cu–Au ± Pb ores surrounded by disseminated pyrite and with or without stockwork mineralisation. The VMS deposits are associated with Palaeoproterozoic upper crustal extension (D₁) that resulted in the development of normal faults and related transfer faults. The VMS ores formed as sub-seafloor replacement in both felsic volcaniclastic and sedimentary rocks and partly as exhalative deposits within the uppermost part of the volcanic stratigraphy. Subsequently, the district was subjected to deformation (D₂) during crustal shortening. Comparing the distribution of VMS deposits with the regional fault pattern reveals a close spatial relationship of VMS deposits to the faults that formed during crustal extension (D₁) utilising the syn-extensional faults as fluid conduits. Analysing the shape and orientation of VMS ore bodies shows how their deformation pattern mimics those of the hosting structures and results from the overprinting D₂ deformation. Furthermore, regional structural transitions are imitated in the deformation patterns of the ore bodies. Plotting the aspect ratios of VMS ore bodies and the comparison with undeformed equivalents in the Hokuroko district, Japan allow an estimation of apparent strain and show correlation with the D₂ deformation intensity of the certain structural domains. A comparison of the size of VMS deposits with their location shows that the smallest deposits are not related to known high-strain zones and the largest deposits are associated with regional-scale high-strain zones. The comparison of distribution and size with the pattern of high-strain zones provides an important tool for regional-scale mineral exploration in the Skellefte district, whereas the analysis of ore body shape and orientation can aid near-mine exploration activities.     

Electron Acceleration and Transport During the November 5, 1998 Solar Flare At ∼13:34 UT

This paper deals with a detailed analysis of spectral and imaging observations of the November 5, 1998 (Hα 1B, GOES M1.5) flare obtained over a large spectral range, i.e., from hard X-rays to radiometric wavelengths. These observations allowed us to probe electron acceleration and transport over a large range of altitudes that is to say within small-scale (a few 10³ km) and large-scale (a few 10⁵ km) magnetic structures. The observations combined with potential and linear force-free magnetic field extrapolations allow us to show that: (i) Flare energy release and electron acceleration are basically driven by loop–loop interactions at two independent, low lying, null points of the active region magnetic field; (ii) <300 keV hard X-ray-producing electrons are accelerated by a different process (probably DC field acceleration) than relativistic electrons that radiate the microwave emission; and (iii) although there is evidence that hard X-ray and decimetric/metric radio-emitting electrons are produced by the same accelerator, the present observations and analysis did not allow us to find a clear and direct magnetic connection between the hard X-ray emitting region and the radio-emitting sources in the middle corona.     

The survival and disruption of cold dark matter microhaloes: implications for direct and indirect detection experiments

If the dark matter particle is a neutralino, then the first structures to form are cuspy cold dark matter (CDM) haloes collapsing after redshifts   z ≈ 100  in the mass range  10⁻⁶–10⁻³ M_⊙  . We carry out a detailed study of the survival of these microhaloes in the Galaxy as they experience tidal encounters with stars, molecular clouds, and other dark matter substructures. We test the validity of analytic impulsive heating calculations using high-resolution N -body simulations. A major limitation of analytic estimates is that mean energy inputs are compared to mean binding energies, instead of the actual mass lost from the system. This energy criterion leads to an overestimate of the stripped mass and an underestimate of the disruption time-scale, since CDM haloes are strongly bound in their inner parts. We show that a significant fraction of material from CDM microhaloes can be unbound by encounters with Galactic substructure and stars; however, the cuspy central regions remain relatively intact. Furthermore, the microhaloes near the solar radius are those which collapse significantly earlier than average and will suffer very little mass-loss. Thus, we expect a fraction of surviving bound microhaloes, a smooth component with narrow features in phase space, which may be uncovered by direct detection experiments, as well as numerous surviving cuspy cores with proper motions of arcminutes per year, which can be detected indirectly via their annihilation into gamma-rays.     

The Jovian stratosphere in the ultraviolet

The center-of-disk reflectivity of Jupiter in the wavelength range from 1450 to 3150A?has been computed from 30 low-dispersion IUE spectra taken during solar maximum in 1978–1980. A vertically inhomogeneous radiative transfer program is used to compute model reflectivities of various stratospheric compositions for comparison. Ammonia and acetylene are well determined because they show narrow absorption bands in the ultraviolet. Above 1800A?, these two gases provide a good fit to the data, but not below. At shorter wavelengths the fit would be much improved by a small amount (5–15 ppb) of propadiene/allene (C₃H₄). Voyager IRIS spectra show that the IR bands of allene are not strong enough to be detected in such a small amount. Additional absorption around 1600A?can be reproduced best with the presence of cyclopropane (C₃H₆, <15ppb), although other absorbers (e.g., hydrocarbon molecules with more than three carbon atoms, oxygen- or nitrogen-containing molecules, or a high-attitude haze) could also explain the spectrum in this region. The data are too noisy to detect possible CO Cameron band absorption near 2000A?.     

Eemian landscape response to climatic shifts and evidence for northerly Neanderthal occupation at a palaeolake margin in northern Germany

The prevailing view suggests that the Eemian interglacial on the European Plain was characterized by largely negligible geomorphic activity beyond the coastal areas. However, systematic geomorphological studies are sparse. Here we present a detailed reconstruction of Eemian to Early Weichselian landscape evolution in the vicinity of a small fingerlake on the northern margin of the Salzwedel Palaeolake in Lower Saxony (Germany). We apply a combination of seismics, sediment coring, pollen analysis and luminescence dating on a complex sequence of colluvial, paludal and lacustrine sediments. Results suggest two pronounced phases of geomorphic activity, directly before the onset and at the end of the Eemian period, with an intermediate period of pronounced landscape stability. The dynamic phases were largely driven by incomplete vegetation cover, but likely accentuated by fluvial incision in the neighbouring Elbe Valley. Furthermore, we discovered Neanderthal occupation at the lakeshore during Eemian pollen zone (PZ) E IV, which is chronologically in line with other known Eemian sites of central Europe. Our highly-resolved spatio-temporal data substantially contribute to the understanding of climate-induced geomorphic processes throughout and directly after the last interglacial period. It helps unraveling the landscape dynamics between the coastal areas to the north and the loess belt to the south.