Zero-valent iron on Mars: An alternative energy source for methanogens

Zero-valent iron, montmorillonite-like smectites, and CO₂ gas are known to exist on Mars, and work was performed to investigate the ability of methanogens to subsist on these materials. After 71 days of incubation at 55 °C, mean methane concentration as percent of headspace volume was 19.80 ± 1.76% (mean ± SE) for replicates containing elemental iron and 0.50 ± 0.15% for those lacking elemental iron.     

Analysis of ordinary chondrites using powder X‐ray diffraction: 2. Applications to ordinary chondrite parent‐body processes

Abstract– We evaluate the chemical and physical conditions of metamorphism in ordinary chondrite parent bodies using X‐ray diffraction (XRD)‐measured modal mineral abundances and geochemical analyses of 48 type 4–6 ordinary chondrites. Several observations indicate that oxidation may have occurred during progressive metamorphism of equilibrated chondrites, including systematic changes with petrologic type in XRD‐derived olivine and low‐Ca pyroxene abundances, increasing ratios of MgO/(MgO+FeO) in olivine and pyroxene, mean Ni/Fe and Co/Fe ratios in bulk metal with increasing metamorphic grade, and linear Fe addition trends in molar Fe/Mn and Fe/Mg plots. An aqueous fluid, likely incorporated as hydrous silicates and distributed homogeneously throughout the parent body, was responsible for oxidation. Based on mass balance calculations, a minimum of 0.3–0.4 wt% H₂O reacted with metal to produce oxidized Fe. Prior to oxidation the parent body underwent a period of reduction, as evidenced by the unequilibrated chondrites. Unlike olivine and pyroxene, average plagioclase abundances do not show any systematic changes with increasing petrologic type. Based on this observation and a comparison of modal and normative plagioclase abundances, we suggest that plagioclase completely crystallized from glass by type 4 temperature conditions in the H and L chondrites and by type 5 in the LL chondrites. Because the validity of using the plagioclase thermometer to determine peak temperatures rests on the assumption that plagioclase continued to crystallize through type 6 conditions, we suggest that temperatures calculated using pyroxene goethermometry provide more accurate estimates of the peak temperatures reached in ordinary chondrite parent bodies.     

Facilitating adaptation to global climate change: perspectives from experts and decision makers serving the Florida Keys

Slivers of land amidst the world’s third largest barrier reef, the Florida Keys provide unique insights on the emerging challenges associated with adaptation to global climate change. While political will and public awareness are gradually shifting on the imposing risks, analysis of survey responses from experts and decision makers serving the Florida Keys (federal, state and local personnel) reveals insufficient resources, limited direction and leadership, and lack of institutional frameworks to facilitate the adaptation process. Against this backdrop, we investigate experts and decision makers’ interest in an array of adaptation measures including their willingness to support a proposed ‘Community Adaptation Fund’ (CAF) to mobilize resources and lay the foundation for adaptation initiatives in the Florida Keys. We also explore potential funding sources for establishing the proposed CAF, and test the feasibility of a diverse set of financing mechanisms. We discuss implications of our findings in the context of enhancing adaptive capacity in the Florida Keys and beyond.     

Peak Minerals: Theoretical Foundations and Practical Application

This article reviews the theoretical foundations for the concept of peak minerals; drawing on similarities and differences with peak oil as modelled using Hubbert style curves. Whilst several studies have applied peak modelling to selected minerals, discussion of the appropriateness of using Hubbert style curves in the minerals context remains largely unexplored. Our discussion focuses on a comparison between oil and minerals, on the key variables: rates of discovery, estimates of ultimately recoverable resources and demand and production trends. With respect to minerals, there are several obstacles which complicate the application of Hubbert style curves to the prediction of future mineral production, including the lack of accurate discovery data, the effect of uncertain reserve estimates, and varying ore quality and quantity. Another notable difference is that while oil is often combusted during use, minerals are used to make metals which are inherently recyclable. Notwithstanding, by using a range of estimates of resources and/or reserves, a period of time can be identified which indicates when a peak in minerals production may occur. This information may then be used to plan for a transition from using a potentially constrained resource, to using substitutes if available, or to reducing demand for that mineral in society.     

Observational constraints on thawing quintessence models

We use a dynamical systems approach to study thawing quintessence models, using a multiparameter extension of the exponential potential which can approximate the form of typical thawing potentials. We impose observational constraints using a compilation of current data, and forecast the tightening of constraints expected from future dark energy surveys, as well as discussing the relation of our results to analytical constraints already in the literature.     

Feast and Famine: regulation of black hole growth in low-redshift galaxies

We analyse the observed distribution of Eddington ratios  ( L / L _Edd)  as a function of supermassive black hole mass for a large sample of nearby galaxies drawn from the Sloan Digital Sky Survey. We demonstrate that there are two distinct regimes of black hole growth in nearby galaxies. The first is associated with galaxies with significant star formation [   M _*/star formation rate (SFR) ∼  a Hubble time] in their central kiloparsec regions, and is characterized by a broad lognormal distribution of accretion rates peaked at a few per cent of the Eddington limit. In this regime, the Eddington ratio distribution is independent of the mass of the black hole and shows little dependence on the central stellar population of the galaxy. The second regime is associated with galaxies with old central stellar populations (   M _*/SFR ≫  a Hubble time), and is characterized by a power-law distribution function of Eddington ratios. In this regime, the time-averaged mass accretion rate on to black holes is proportional to the mass of stars in the galaxy bulge, with a constant of proportionality that depends on the mean stellar age of the stars. This result is once again independent of black hole mass. We show that both the slope of the power law and the decrease in the accretion rate on to black holes in old galaxies are consistent with population synthesis model predictions of the decline in stellar mass loss rates as a function of mean stellar age. Our results lead to a very simple picture of black hole growth in the local Universe. If the supply of cold gas in a galaxy bulge is plentiful, the black hole regulates its own growth at a rate that does not further depend on the properties of the interstellar medium. Once the gas runs out, black hole growth is regulated by the rate at which evolved stars lose their mass.     

Periodicities in the high-mass X-ray binary system RX J0146.9+6121/LS I+61°235

The high-mass X-ray binary RX J0146.9+6121, with optical counterpart LS I+61°235 (V831 Cas), is an intriguing system on the outskirts of the open cluster NGC 663. It contains the slowest Be type X-ray pulsar known with a pulse period of around 1400 s and, primarily from the study of variation in the emission line profile of Hα, it is known to have a Be decretion disc with a one-armed density wave period of approximately 1240 d. Here we present the results of an extensive photometric campaign, supplemented with optical spectroscopy, aimed at measuring short time-scale periodicities. We find three significant periodicities in the photometric data at, in order of statistical significance, 0.34, 0.67 and 0.10 d. We give arguments to support the interpretation that the 0.34 and 0.10 d periods could be due to stellar oscillations of the B-type primary star and that the 0.67 d period is the spin period of the Be star with a spin axis inclination of  23⁺¹⁰₋₈  degrees. We measured a systemic velocity of  −37.0 ± 4.3 km s⁻¹  confirming that LS I+61°235 has a high probability of membership in the young cluster NGC 663 from which the system's age can be estimated as 20–25 Myr. From archival RXTE All Sky Monitor (ASM) data we further find 'super' X-ray outbursts roughly every 450 d. If these super outbursts are caused by the alignment of the compact star with the one-armed decretion disc enhancement, then the orbital period is approximately 330 d.     

The production of unequal risk in hazardscapes: An explanatory frame applied to disaster at the US–Mexico border

This paper advances understanding of how unequal risks to environmental hazards are generated. Marginalization is the best known explanation for the production of risk. The concept of marginalization was elaborated through studies of hazards in the global South and connotes how social inequalities constrain livelihood options of less powerful social groups. Thus, marginal groups are pressured to degrade landscapes and occupy hazardous environments while they experience decreased capacities to cope with environmental change. This paper directs analytical attention beyond the material to include the discursive realm and demonstrates that the production of unequal risk is contingent upon how hazards are differentially perceived, represented, and contested in social spaces. Findings from a flood disaster case study in the El Paso (US)–Ciudad Juárez (Mexico) border metropolis highlight how hegemonic discourses reinforce material processes of marginalization in flood-prone social spaces. Findings also reveal how socially-powerful geographical groups of people have harnessed institutional resources in their efforts to externalize risks and capitalize on environmental opportunities in some flood-prone areas. The concept of facilitation is used to explain the material-discursive production of socially-elite, flood-prone spaces. Facilitation clarifies how powerful groups are provided privileged access to institutional resources in their pursuit of environmental rewards, contributing to unjust socioenvironmental outcomes. In conclusion, I outline key aspects of how unequal risks are materially and discursively (re)produced within hazardscapes through relational processes of marginalization/facilitation.