Sources of variability in springwater chemistry in Fool Creek,a high-elevation catchment of the Rocky Mountains,Colorado, USA

Springs are the point of origin for most headwater streams and are important regulators of their chemical composition. We analysed solute concentrations of water emerging from 57 springs within the 3 km² Fool Creek catchment at the Fraser Experimental Forest and considered sources of spatial variation among them and their influence on the chemical composition of downstream water. On average, calcium and acid neutralizing capacity (bicarbonate-ANC) comprised 50 and 90% of the cation and anion charge respectively, in both spring and stream water. Variation in inorganic chemical composition among springs reflected distinct groundwater sources and catchment geology. Springs emerging through glacial deposits in the upper portion of the catchment were the most dilute and similar to snowmelt, whereas lower elevation springs were more concentrated in cations and ANC. Water emerging from a handful of springs in a geologically faulted portion of the catchment were more concentrated than all others and had a predominant effect on downstream ion concentrations. Chemical similarity indicated that these springs were linked along surface and subsurface flowpaths. This survey shows that springwater chemistry is influenced at nested spatial scales including broad geologic conditions, elevational and spatial attributes and isolated local features. Our results highlight the role of overlapping factors on solute export from headwater catchments.     

Using LM‐OSL of quartz to distinguish sediments derived from surface‐soil and channel erosion

This study describes the use of linearly modulated optically stimulated luminescence (LM‐OSL) to distinguish surface‐soil derived sediments from those derived from channel bank erosion. LM‐OSL signals from quartz extracted from 15 surface‐soil and five channel bank samples were analysed and compared to signals from samples collected from two downstream river sites. Discriminant analysis showed that the detrapping probabilities of fast, first slow and second slow components of the LM‐OSL signal can be used to differentiate between the samples collected from the channel bank and surface‐soil sources. We show that for each of these source end members these components are all normally distributed. These distributions are then used to estimate the relative contribution of surface‐soil derived and channel bank derived sediment to the river bed sediments. The results indicate that channel bank derived sediments dominate the sediment sources at both sites, with 90.1 ± 3% and 91.9 ± 1.9% contributions. These results are in agreement with a previous study which used measurements of ¹³⁷Cs and ²¹⁰Pb_ex fallout radionuclides to estimate the relative contribution from these two sources. This result shows that LM‐OSL may be a useful method, at least in the studied catchment, to estimate the relative contribution of surface soil and channel erosion to river sediments. However, further research in different settings is required to test the difference of OSL signals in distinguishing these sediment sources. And if generally acceptable, this technique may provide an alternative to the use of fallout radionuclides for source tracing. Copyright © 2015 John Wiley & Sons, Ltd.     

Total evaporation estimation for accurate water accounting purposes: an appraisal of various available estimation methods

The estimation of total evaporation is fundamental for water accounting, considering its influence on water availability. Moreover, the current increase in water consumption (e.g. in sub-Saharan Africa and the world over), land cover/use changes, deteriorating water quality and the climate change projections in most regions of the world underscore the need to understand water loss. So far, different approaches have been developed and implemented in estimating the variations of total evaporation, with varying accuracies. The aim of this work was therefore, to provide a review of these different approaches for estimating total evaporation, as well as a detailed discussion of their strengths and weaknesses. Findings from this review have shown that total evaporation estimates derived, using ground-based meteorological and micro-meteorological methods are inadequate for representing its large-scale spatial variations. On the other hand, remote sensing technology, which acquires data at different resolutions (i.e. radiometric, spectral, spatial and temporal), provides timely, up-to-date and relatively accurate spatial estimates of total evaporation over large geographic coverage, for sustainable and effective water accounting, which is key for well-informed and improved management of water resources at both catchment and regional scales. In this regard, more details on the remote sensing-based methods of estimating total evaporation are provided, especially considering the robust technological advancements and its potential in characterizing earth features over time and space. This work has also managed to identify research gaps and challenges in the accurate estimation of total evaporation, using remote sensing, especially with the emergence of more advanced sensors and the characteristics of the landscape.     

Cancer risks from exposure to vehicular air pollution: a household level analysis of intra-ethnic heterogeneity in Miami,Florida

Quantitative environmental justice (EJ) research has relied on aggregated data from census units to determine disproportionate hazard exposure. Additionally, variables typically used to analyze ethnic inequities in exposure (e.g., percent Hispanic) are too broad and assume a degree of homogeneity that may not exist, given the diversity of ethnic minority populations. We address these limitations through a study that utilizes primary household level survey data and cancer risk estimates from the National-Scale Air Toxics Assessment (NATA) to analyze intra-ethnic inequities in exposure to vehicular air pollutants in the Miami metropolitan area, Florida. Our analysis disaggregates the Hispanic category based on five characteristics (language proficiency, U.S. citizenship, nativity, unemployment status, and national origin) and finds that risk burdens are significantly higher for Hispanic respondents who are foreign-born, unemployed, and of Cuban origin. Findings highlight the advantages of downscaling EJ analyses to the household level and considering intra-ethnic heterogeneity in EJ research and policy.     

The impacts avoided with a 1.5 °C climate target: a global and regional assessment

The 2015 Paris Agreement commits countries to pursue efforts to limit the increase in global mean temperature to 1.5 °C above pre-industrial levels. We assess the consequences of achieving this target in 2100 for the impacts that are avoided, using several indicators of impact (exposure to drought, river flooding, heat waves and demands for heating and cooling energy). The proportion of impacts that are avoided is not simply equal to the proportional reduction in temperature. At the global scale, the median proportion of projected impacts avoided by the 1.5 °C target relative to a rise of 4 °C ranges between 62 and 95% across sectors: the greatest reduction is for heat wave impacts. The 1.5 °C target results in impacts that would be between 27 and 62% lower than with the 2 °C target. For each indicator, there are differences in the proportions of impacts avoided between regions depending on exposure and the regional changes in climate (particularly precipitation). Uncertainty in the proportion of impacts that are avoided for a specific sector depends on the range in the shape of the relationship between global temperature change and impact, and this varies between sectors.     

Evaluation of an automated EA-IRMS method for total carbon analysis of atmospheric aerosol at HEKAL

Comprehensive atmospheric studies have demonstrated that carbonaceous particles are one of the main components of atmospheric aerosols over Europe. The aim of our study was to establish an automated elemental analyser interfaced to a stable isotope mass spectrometer (EA-IRMS) method at the Hertelendi Laboratory of Environmental Studies (HEKAL), as a suitable method of quantification of total carbon mass in individual PM_2.5 aerosol samples. Total carbon (TC) mass and simultaneous stable isotopic ratios were determined for both test standard and genuine aerosol samples. Finally, the results were compared to the ones obtained independently by an alternative sealed tube combustion method developed previously at HEKAL. The TC recovery tests of standard material prepared by the sealed tube method confirmed at least a carbon recovery yield of 92% for a broad range of carbon mass (100–2000 μg). The stable isotopic results confirmed that sealed tube method is reproducible and suitable to be used as a reference to verify our new EA-IRMS method. The EA-IRMS TC measurements of genuine aerosols gave on average 3% higher carbon recovery yield, relative to the uncorrected results of the sealed tube method. The comparison of the stable isotopic results by the two methods for aerosols also showed minimal differences. Consequently, the possibility of simultaneous TC and stable isotopic analyses makes the EA-IRMS method a very attractive alternative for continuous measurement of aerosols, with an accuracy and reliability similar to other commercial devices.     

Value-added Impact of Geostationary Hyperspectral Infrared Sounders on Local Severe Storm Forecasts——via a Quick Regional OSSE

Accurate atmospheric temperature and moisture information with high temporal/spatial resolutions are two of the key parameters needed in regional numerical weather prediction(NWP) models to reliably predict high-impact weather events such as local severe storms(LSSs). High spectral resolution or hyperspectral infrared(HIR) sounders from geostationary orbit(GEO) provide an unprecedented source of near time-continuous, three-dimensional information on the dynamic and thermodynamic atmospheric fields—an important benefit for nowcasting and NWP-based forecasting. In order to demonstrate the value of GEO HIR sounder radiances on LSS forecasts, a quick regional OSSE(Observing System Simulation Experiment)framework has been developed, including high-resolution nature run generation, synthetic observation simulation and validation, and impact study on LSS forecasts. Results show that, on top of the existing LEO(low earth orbit) sounders, a GEO HIR sounder may provide value-added impact [a reduction of 3.56% in normalized root-mean-square difference(RMSD)] on LSS forecasts due to large spatial coverage and high temporal resolution, even though the data are assimilated every 6 h with a thinning of 60 km. Additionally, more frequent assimilations and smaller thinning distances allow more observations to be assimilated, and may further increase the positive impact from a GEO HIR sounder. On the other hand, with denser and more frequent observations assimilated, it becomes more difficult to handle the spatial error correlation in observations and gravity waves due to the limitations of current assimilation and forecast systems(such as a static background error covariance). The peak reduction of 4.6% in normalized RMSD is found when observations are assimilated every 3 h with a thinning distance of 30 km.     

Kinematic analysis of mélange fabrics: examples and applications from the McHugh Complex, Kenai Peninsula, Alaska

Permian to Cretaceous mélange of the McHugh Complex on the Kenai Peninsula, south-central Alaska includes blocks and belts of graywacke, argillite, limestone, chert, basalt, gabbro, and ultramafic rocks, intruded by a variety of igneous rocks. An oceanic plate stratigraphy is repeated hundreds of times across the map area, but most structures at the outcrop scale extend lithological layering. Strong rheological units occur as blocks within a matrix that flowed around the competent blocks during deformation, forming broken formation and mélange. Deformation was noncoaxial, and disruption of primary layering was a consequence of general strain driven by plate convergence in a relatively narrow zone between the overriding accretionary wedge and the downgoing, generally thinly sedimented oceanic plate. Soft-sediment deformation processes do not appear to have played a major role in the formation of the mélange. A model for deformation at the toe of the wedge is proposed in which layers oriented at low angles to σ₁ are contracted in both the brittle and ductile regimes, layers at 30–45° to σ₁ are extended in the brittle regime and contracted in the ductile regime, and layers at angles greater than 45° to σ₁ are extended in both the brittle and ductile regimes. Imbrication in thrust duplexes occurs at deeper levels within the wedge. Many structures within mélange of the McHugh Complex are asymmetric and record kinematic information consistent with the inferred structural setting in an accretionary wedge. A displacement field for the McHugh Complex on the lower Kenai Peninsula includes three belts: an inboard belt of Late Triassic rocks records west-to-east-directed slip of hanging walls, a central belt of predominantly Early Jurassic rocks records north–south directed displacements, and Early Cretaceous rocks in an outboard belt preserve southwest–northeast directed slip vectors. Although precise ages of accretion are unknown, slip directions are compatible with inferred plate motions during the general time frame of accretion of the McHugh Complex. The slip vectors are interpreted to preserve the convergence directions between the overriding and underriding plates, which became more oblique with time. They are not considered indicative of strain partitioning into belts of orogen-parallel and orogen-perpendicular displacements, because the kinematic data are derived from the earliest preserved structures, whereas fabrics related to strain partitioning would be expected to be superimposed on earlier accretion-related fabrics.     

Beach-fill equilibration and dune growth at two large-scale nourishment sites

Natural dune growth after nourishment is often observed, and such growth plays an important role in beach management for coastal communities. Nourishment sand equilibration after construction is another important topic for project planning and design. Large-scale nourishment projects at Nags Head (NC, USA) (completed in 2011) and Bridgehampton–Sagaponack (NY, USA) (completed in 2014) are under comparatively high-wave energy conditions and offer new insight regarding these topics. After nourishment, a natural beach and inshore morphology were produced with high rates of dune growth by eolian transport. At Nags Head, volumetric dune growth averaged 8 m³/m/yr over the first 5 years following project completion, while Bridgehampton–Sagaponack averaged 9 m³/m/yr over the first 3 post-project years. Results are compared with the Bagnold (1941) analytical model predictions of dune growth and are shown to correlate and decay closely with dry-sand beach width as the nourished profile equilibrates. The extra volume and elevation in the dunes have provided a higher level of storm protection and have helped the sites avoid any major damage to oceanfront properties during hurricanes or numerous severe winter storms.