Intergranular diffusion rates from the analysis of garnet surfaces: Implications for metamorphic equilibration

Novel approaches to garnet analysis have been used to assess rates of intergranular diffusion between different matrix phases and garnet porphyroblasts in a regionally metamorphosed staurolite‐mica‐schist from the Barrovian‐type area in Scotland. X‐ray maps and chemical traverses of planar porphyroblast surfaces reveal chemical heterogeneity of the garnet grain boundary linked to the nature of the adjacent matrix phase. The garnet preserves evidence of low temperature retrograde exchange with matrix minerals and diffusion profiles documenting cation movement along the garnet boundaries. Garnet–quartz and garnet–plagioclase boundaries preserve evidence of sluggish Mg, Mn and Fe diffusion at comparable rates to volume diffusion in garnet, whereas diffusion along garnet–biotite interfaces is much more effective. Evidence of particularly slow Al transport, probably coupled to Fe³⁺ exchange, is locally preserved on garnet surfaces adjacent to Fe‐oxide phases. The Ca distribution on the garnet surface shows the most complex behaviour, with long‐wavelength heterogeneities apparently unrelated to the matrix grain boundaries. This implies that the Ca content of garnet is controlled by local availability and is thought likely to reflect disequilibrium established during garnet growth. Geochemical anomalies on the garnet surfaces are also linked to the location of triple junctions between the porphyroblasts and the matrix phases, and imply enhanced transport along these channels. The slow rates of intergranular diffusion and the characteristics of different boundary types may explain many features associated with the prograde growth of garnet porphyroblasts. Thus, minerals such as quartz, Fe‐oxides and plagioclase whose boundaries with garnet are characterized by slow intergranular diffusion rates appear to be preferentially trapped as inclusions within porphyroblasts. As such grain boundary diffusion rates may be a significant kinetic impediment to metamorphic equilibrium and garnet may struggle to maintain chemical and textural equilibrium during growth in pelites.     

Chemical and textural equilibration of garnet during amphibolite facies metamorphism: The influence of coupled dissolution–reprecipitation

Metamorphic equilibration requires chemical communication between minerals and may be inhibited through sluggish volume diffusion and or slow rates of dissolution in a fluid phase. Relatively slow diffusion and the perceived robust nature of chemical growth zoning may preclude garnet porphyroblasts from readily participating in low‐temperature amphibolite facies metamorphic reactions. Garnet is widely assumed to be a reactant in staurolite‐isograd reactions, and the evidence for this has been assessed in the Late Proterozoic Dalradian pelitic schists of the Scottish Highlands. The 3D imaging of garnet porphyroblasts in staurolite‐bearing schists reveals a good crystal shape and little evidence of marginal dissolution; however, there is also lack of evidence for the involvement of either chlorite or chloritoid in the reaction. Staurolite forms directly adjacent to the garnet, and its nucleation is strongly associated with deformation of the muscovite‐rich fabrics around the porphyroblasts. “Cloudy” fluid inclusion‐rich garnet forms in both marginal and internal parts of the garnet porphyroblast and is linked both to the production of staurolite and to the introduction of abundant quartz inclusions within the garnet. Such cloudy garnet typically has a Mg‐rich, Mn‐poor composition and is interpreted to have formed during a coupled dissolution–reprecipitation process, triggered by a local influx of fluid. All garnet in the muscovite‐bearing schists present in this area is potentially reactive, irrespective of the garnet composition, but very few of the schists contain staurolite. The staurolite‐producing reaction appears to be substantially overstepped during the relatively high‐pressure Barrovian regional metamorphism reflecting the limited permeability of the schists in peak metamorphic conditions. Fluid influx and hence reaction progress appear to be strongly controlled by subtle differences in deformation history. The remaining garnet fails to achieve chemical equilibrium during the reaction creating distinctive patchy compositional zoning. Such zoning in metamorphic garnet created during coupled dissolution–reprecipitation reactions may be difficult to recognize in higher grade pelites due to subsequent diffusive re‐equilibration. Fundamental assumptions about metamorphic processes are questioned by the lack of chemical equilibrium during this reaction and the restricted permeability of the regional metamorphic pelitic schists. In addition, the partial loss of prograde chemical and textural information from the garnet porphyroblasts cautions against their routine use as a reliable monitor of metamorphic history. However, the partial re‐equilibration of the porphyroblasts during coupled dissolution–reprecipitation opens possibilities of mapping reaction progress in garnet as a means of assessing fluid access during peak metamorphic conditions.     

Surface complexation modeling for predicting solid phase arsenic concentrations in the sediments of the Mississippi River Valley alluvial aquifer, Arkansas, USA

The potential health impact of As in drinking water supply systems in the Mississippi River Valley alluvial aquifer in the state of Arkansas, USA is significant. In this context it is important to understand the occurrence, distribution and mobilization of As in the Mississippi River Valley alluvial aquifer. Application of surface complexation models (SCMs) to predict the sorption behavior of As and hydrous Fe oxides (HFO) in the laboratory has increased in the last decade. However, the application of SCMs to predict the sorption of As in natural sediments has not often been reported, and such applications are greatly constrained by the lack of site-specific model parameters. Attempts have been made to use SCMs considering a component additivity (CA) approach which accounts for relative abundances of pure phases in natural sediments, followed by the addition of SCM parameters individually for each phase. Although few reliable and internally consistent sorption databases related to HFO exist, the use of SCMs using laboratory-derived sorption databases to predict the mobility of As in natural sediments has increased. This study is an attempt to evaluate the ability of the SCMs using the geochemical code PHREEQC to predict solid phase As in the sediments of the Mississippi River Valley alluvial aquifer in Arkansas. The SCM option of the double-layer model (DLM) was simulated using ferrihydrite and goethite as sorbents quantified from chemical extractions, calculated surface-site densities, published surface properties, and published laboratory-derived sorption constants for the sorbents. The model results are satisfactory for shallow wells (10.6 m below ground surface), where the redox condition is relatively oxic or mildly suboxic. However, for the deep alluvial aquifer (21-36.6 m below ground surface) where the redox condition is suboxic to anoxic, the model results are unsatisfactory.     

AWAPer: An R package for area weighted catchment daily meteorological data anywhere within Australia

Meteorological time-series data are a fundamental input to hydrological investigations. But sourcing data is often laborious and plagued with difficulties. In an effort to improve efficiency and rigor we present an R-package, named AWAPer ( https://github.com/peterson-tim-j/AWAPer ), for the efficient estimation of daily area weighted catchment average and spatial variance of meteorological variables, including evapotranspiration. The package allows creation and updating of a data-cube of gridded daily data from 1900 onwards. Once created, point and area weighted estimates can be extracted at user-defined locations and time periods for anywhere within Australia. Examples of point and catchment average extraction are presented.     

Retraction: Evaluation of Co‐Digestion at a Commercial Dairy Anaerobic Digester

The above article published online on 16 June 2011 in Wiley Online Library ( http://www.onlinelibrary.wiley.com ), and in Volume 39, pp. 697‐704, has been retracted by agreement between the Editor‐in‐Chief, Prisca Henheik, and Wiley‐VCH Verlag GmbH & Co. KgaA. The retraction has been agreed following an investigation carried out by Washington State University (WSU) which determined that research misconduct had occurred with respect to fabricating experimental data and falsifying data that formed the basis of a section of this article on the part of the corresponding author. Furthermore, WSU determined that the corresponding author did not declare an existing commercial conflict of interest when submitting the paper to the peer‐‐reviewed journal CLEAN ‐ Soil, Air, Water.     

The Effects of Climate Change on Water Resources in the West: Introduction and Overview

The results of an experimental `end to end' assessment of the effects of climate change on water resources in the western United States are described. The assessment focuses on the potential effects of climate change over the first half of the 21st century on the Columbia, Sacramento/San Joaquin, and Colorado river basins. The paper describes the methodology used for the assessment, and it summarizes the principal findings of the study. The strengths and weaknesses of this study are discussed, and suggestions are made for improving future climate change assessments.     

Tropical Cyclone Size Change under Ocean Warming and Associated Responses of Tropical Cyclone Destructiveness: Idealized Experiments

The power dissipation index (PDI), which is defined as the sum of the cube of tropical cyclone (TC) maximum wind speed during TC lifetime, is widely used to estimate the TC destructive potential. However, due to the lack of high-resolution observations, little attention has been paid to the contribution of TC size change to TC destructive potential in response to ocean warming. In this study, sensitivity experiments are performed by using the high-resolution Weather Research and Forecasting (WRF) model to investigate the responses of TC size and TC destructive potential to prescribed sea surface temperature (SST) increase under the present climate condition. The results show that TC size increases with the ocean warming. Possible reasons for TC size change are investigated with a focus on the outer air-sea moisture difference (ASMD). As SST increases, ASMD in the outer zone of the TC is larger than that in the inner zone, which increases the surface entropy flux (SEF) of the outer zone. This change in the radial distribution of SEF causes the increase of tangential wind in the outer zone, which further increases SEF, resulting in a positive feedback between outer-zone SEF and outer-zone tangential wind. This feedback leads to the increase of the radius of gale-force wind, leading to the expansion of TC size. Moreover, to estimate the contribution of TC size change to TC destructiveness, we calculate TC size-dependent destructive potential (PDS) as the storm size information is available in the model outputs, as well as PDI that does not consider the effect of TC size change. We find that PDS increases exponentially as SST increases from 1 to 4°C, while PDI increases linearly; hence the former is soon much greater than the latter. This suggests that the growth effect of TC size cannot be ignored in estimating destructiveness under ocean warming.     

Seasonal and Sub-Seasonal Circulation Anomalies Associated with Persistent Rainy Days in 2018/2019 Winter in Shanghai,China

Shanghai experienced the longest rainy days in 2018/2019 winter since 1988. The physical cause of such an unusual climate condition was investigated through the diagnosis of observational data. From a seasonal perspective, a long persistent rainy winter was often associated with an El Niño condition in the equatorial Pacific. This abnormal oceanic condition induces a remote teleconnection pattern with pronounced low-level southerly anomalies over East China. The wind anomalies transported moisture from tropical oceans and caused persistent rainfall in East Asia. Meanwhile, the local rainfall time series exhibited a strong quasi-biweekly oscillation (QBWO). Three persistent rainy events were identified in the 2018/2019 winter and they all occurred during the active phase of the QBWO. The first two events were associated with a low pressure anomaly west of Shanghai. Southerly anomalies associated with the low pressure system advected high mean moisture into central eastern China, leading to the persistent rainfall there. The third event was associated with a high pressure anomaly in lower troposphere to the east of Shanghai, which induced anomalous southerlies to its west, favoring the occurrence of rainfall in Shanghai. The result suggests the importance of high-frequency variability in affecting seasonal rainfall anomalies.     

MJO对2018年华北夏季降水的影响

本文基于华北夏季降水资料和热带大气季节内振荡（Madden–Julian Oscillation，简称MJO）指数、NCEP/NCAR（美国国家环境预报中心/美国国家大气研究中心）再分析环流资料，采用多种统计方法分析MJO与2018年华北夏季降水的关系及影响机制。结果表明:（1）MJO与华北夏季降水有密切的联系。虽然MJO不能移到较高纬度直接影响华北夏季降水，但MJO对流区的气旋会在其北侧激发出反气旋环流，这对“气旋—反气旋对”在缓慢东移过程中，处于较高纬度的反气旋会直接影响华北夏季降水。即MJO会间接影响华北夏季降水，表现为当夏季MJO进入5、6位相时，华北地区夏季会出现明显降水过程，但降水强弱与MJO振幅大小有关。（2）影响机制方面。在850 hPa，伴随MJO的“气旋—反气旋对”的东移，它会造成华北夏季偏南风水汽输送加强（对应RMM1）或东南风水汽输送加强（对应RMM2），从而有利于降水过程发生。在500 hPa层，MJO通过中层扰动向中高纬的传播，诱导副热带高压移到朝鲜半岛附近并加强，对西来高空槽形成阻挡作用，有利于华北地区产生上升运动，从而有利于华北夏季降水过程发生。（3）可以用MJO制作华北夏季延伸期降水过程预报。