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81.
The Kabanga Ni sulfide deposit, Tanzania: I. Geology, petrography, silicate rock geochemistry, and sulfur and oxygen isotopes 总被引:1,自引:0,他引:1
Wolfgang D. Maier Sarah-Jane Barnes Arindam Sarkar Ed Ripley Chusi Li Tim Livesey 《Mineralium Deposita》2010,45(5):419-441
The Kabanga Ni sulfide deposit represents one of the most significant Ni sulfide discoveries of the last two decades, with
current indicated mineral resources of 23.23 Mt at 2.64% Ni and inferred mineral resources of 28.5 Mt at 2.7% Ni (Nov. 2008).
The sulfides are hosted by a suite of ∼1.4 Ga ultramafic–mafic, sill-like, and chonolithic intrusions that form part of the
approximately 500 km long Kabanga–Musongati–Kapalagulu igneous belt in Tanzania and Burundi. The igneous bodies are up to
about 1 km thick and 4 km long. They crystallized from several compositionally distinct magma pulses emplaced into sulfide-bearing
pelitic schists. The first magma was a siliceous high-magnesium basalt (approximately 13.3% MgO) that formed a network of
fine-grained acicular-textured gabbronoritic and orthopyroxenitic sills (Mg# opx 78–88, An plag 45–88). The magma was highly
enriched in incompatible trace elements (LILE, LREE) and had pronounced negative Nb and Ta anomalies and heavy O isotopic
signatures (δ18O +6 to +8). These compositional features are consistent with about 20% contamination of primitive picrite with the sulfidic
pelitic schists. Subsequent magma pulses were more magnesian (approximately 14–15% MgO) and less contaminated (e.g., δ18O +5.1 to +6.6). They injected into the earlier sills, resulting in the formation of medium-grained harzburgites, olivine
orthopyroxenites and orthopyroxenites (Fo 83–89, Mg# opx 86–89), and magmatic breccias consisting of gabbronorite–orthopyroxenite fragments within an olivine-rich matrix. All intrusions
in the Kabanga area contain abundant sulfides (pyrrhotite, pentlandite, and minor chalcopyrite and pyrite). In the lower portions
and the immediate footwall of two of the intrusions, namely Kabanga North and Kabanga Main, there occur numerous layers, lenses,
and veins of massive Ni sulfides reaching a thickness of several meters. The largest amount of high grade, massive sulfide
occurs in the smallest intrusion (Kabanga North). The sulfides have heavy S isotopic signatures (δ34S wr = +10 to +24) that broadly overlap with those of the country rock sulfides, consistent with significant assimilation
of external sulfur from the Karagwe–Ankolean sedimentary sequence. However, based partly on the relatively homogenous distribution
of disseminated sulfides in many of the intrusive rocks, we propose that the Kabanga magmas reached sulfide saturation prior
to final emplacement, in staging chambers or feeder conduits, followed by entrainment of the sulfides during continued magma
ascent. Oxygen isotope data indicate that the mode of sulfide assimilation changed with time. The heavy δ18O ratios of the early magmas are consistent with ingestion of the sedimentary country rocks in bulk. The relatively light
δ18O ratios of the later magmas indicate less bulk assimilation of the country rocks, but in addition the magmas selectively
assimilated additional S, possibly through devolatization of the country rocks or through cannibalization of magmatic sulfides
deposited in the conduits by preceding magma surges. The intrusions were tilted at ca. 1.37 Ga, during the Kibaran orogeny
and associated synkinematic granite plutonism. This caused solid-state mobilization of ductile sulfides into shear zones,
notably along the base of the intrusions where sulfide-hornfels breccias and lenses and layers of massive sulfides may reach
a thickness of >10 m and can extend for several 10 s to >100 m away from the intrusions. These horizons represent an important
exploration target for additional nickel sulfide deposits. 相似文献
82.
The oxygen isotopic composition of land-snail shells may provide insight into the source region and trajectory of precipitation. Last glacial maximum (LGM) gastropod shells were sampled from loess from Belgium to Serbia and modern land-snail shells both record δ18O values between 0‰ and − 5‰. There are significant differences in mean fossil shell δ18O between sites but not among genera at a single location. Therefore, we group δ18O values from different genera together to map the spatial distribution of δ18O in shell carbonate. Shell δ18O values reflect the spatial variation in the isotopic composition of precipitation and incorporate the snails' preferential sampling of precipitation during the warm season. Modern shell δ18O decreases in Europe along a N-S gradient from the North Sea inland toward the Alps. Modern observed data of isotopes in precipitation (GNIP) demonstrate a similar trend for low-altitude sites. LGM shell δ18O data show a different gradient with δ18O declining toward the ENE, implying a mid-Atlantic source due to increased sea ice and a possible southern displacement of the westerly jet stream. Balkan LGM samples show the influence of a Mediterranean source, with δ18O values decreasing northward. 相似文献
83.
84.
Ogallala gravels are an important lithic material source for stone tool manufacture across the Great Plains. The lithology of eight gravel sample locations along the eastern escarpment of the Southern High Plains has been examined to quantify the composition and variability in Ogallala deposits. In addition, three Ogallala gravel quarry sites have been analyzed to determine how the lithology of Ogallala gravels influenced procurement and tool production strategies. Results indicate deposits of Ogallala gravels differ in their composition related to their position on the landscape, and the types of rocks vary by size and shape. Investigation of the quarry sites has revealed that the lithology of Ogallala gravels had an impact on testing and the initial stages of lithic reduction. Different rock types, however, may have more of an influence on later stages of tool manufacture at nearby campsites and other locations where Ogallala gravels are not as dense. © 2009 Wiley Periodicals, Inc. 相似文献
85.
Numerical Modelling of the Anisotropic Mechanical Behaviour of Opalinus Clay at the Laboratory-Scale Using FEM/DEM 总被引:1,自引:1,他引:0
Andrea Lisjak Bryan S. A. Tatone Giovanni Grasselli Tim Vietor 《Rock Mechanics and Rock Engineering》2014,47(1):187-206
The Opalinus Clay (OPA) is an argillaceous rock formation selected to host a deep geologic repository for high-level nuclear waste in Switzerland. It has been shown that the excavation damaged zone (EDZ) in this formation is heavily affected by the anisotropic mechanical response of the material related to the presence of bedding planes. In this context, the purpose of this study is twofold: (i) to illustrate the new developments that have been introduced into the combined finite-discrete element method (FEM/DEM) to model layered materials and (ii) to demonstrate the effectiveness of this new modelling approach in simulating the short-term mechanical response of OPA at the laboratory-scale. A transversely isotropic elastic constitutive law is implemented to account for the anisotropic elastic modulus, while a procedure to incorporate a distribution of preferentially oriented defects is devised to capture the anisotropic strength. Laboratory results of indirect tensile tests and uniaxial compression tests are used to calibrate the numerical model. Emergent strength and deformation properties, together with the simulated damage mechanisms, are shown to be in strong agreement with experimental observations. Subsequently, the calibrated model is validated by investigating the effect of confinement and the influence of the loading angle with respect to the specimen anisotropy. Simulated fracture patterns are discussed in the context of the theory of brittle rock failure and analyzed with reference to the EDZ formation mechanisms observed at the Mont Terri Underground Research Laboratory. 相似文献
86.
Ureilite smelting 总被引:2,自引:0,他引:2
Abstract— Ureilites containing homogeneous Fo76 olivine cores in intimate co-existence with graphite must have recrystallized at pressures of at least ~100 bars to suppress smelting of the fayalite component of the olivine to Fe metal. Smelting of olivine and pyroxene-saturated magmatic liquids produces orthopyroxene-without-olivine crystalline derivatives unlike those in ureilites. Thus the Mg# compositional variation within the ureilite suite, which is commonly attributed to partial smelting, cannot plausibly be produced by assemblages rich in liquid. In situ smelting of graphitic olivine + pigeonite crystal mushes can produce the correct crystal assemblage, but fails to provide a plausible account for the removal of metal from ureilites or for the correlation of Mg# with Δ17O. Even if Mg# and Δ17O variations are established in the nebula, ureilite recrystallization with graphite must have occurred at pressures greater than the minima we have experimentally established, corresponding to parent objects not less than ~100 km in radius. 相似文献
87.
Peer Helmke Susanne Neuer Michael W. Lomas Maureen Conte Tim Freudenthal 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(2):213-227
We compared in-situ and satellite-derived measures of the biological carbon pump efficiency at the two seemingly similar subtropical North Atlantic gyre time series sites, the Bermuda time series (BATS, Bermuda Atlantic time-series study and OFP, ocean flux program) in the western gyre and the ESTOC time series (European station for time-series in the ocean, Canary Islands) in the eastern gyre. Satellite-derived surface chlorophyll a was slightly lower at Bermuda compared to ESTOC (annual average of 0.10±0.04 vs. 0.14±0.05-mg-m?3), as was satellite-derived primary production (annual average of 380±77 vs. 440±80-mg C-m?2 d?1). However, export production normalized to primary production (export ratio) was higher at Bermuda by a factor of 2–3 when estimated using mesopelagic traps moored at 500-m depth and by a factor of 3–4 when estimated using surface-tethered drifting traps. When averaged seasonally, flux at BATS was highest in spring (March, April, May) at all depths followed by summer (June, July, August) and decreasing towards fall, but this seasonality was less visible at ESTOC. Seasonal comparison showed the fastest flux attenuation at Bermuda in winter and spring, coinciding with the highest POC flux. POC/PIC ratios derived from the moored traps were significantly higher at BATS than at ESTOC in fall and winter, but this difference was not significant in spring (p>0.05). This study shows that while the western and eastern Atlantic subtropical gyres have similar rates of primary production, the biological carbon pump differs between the two provinces. Higher new nutrient input observed at Bermuda compared to ESTOC might explain part of the difference in export ratio but alone is insufficient. Greater winter mixed-layer depths and higher mesoscale eddy activity at Bermuda resulting in pulsed production events of labile organic matter might explain both the higher export flux and export ratios found at Bermuda. 相似文献
88.
A combination of geophysical methods including continuous electrical resistivity and high-resolution Chirp sub-bottom profiling were utilized to characterize geologic controls on pore fluid salinity in the nearshore of Long Bay, SC. Resistivity values ranged from less than 1 Ω m to greater than 40 Ω m throughout the bay. Areas of elevated electrical resistivity suggest the influence of relatively fresher water on pore water composition. Geophysical evidence alone does not eliminate all ambiguity associated with lithological and porosity variations that may also contribute to electrical structure of shallow marine sediments. The anomalous field is of sufficient magnitude that lithological variation alone does not control the spatial distribution of elevated electrical resistivity zones. Geographical distribution of electrical anomalies and structures interpreted from nearby sub-bottom profiles indicates abrupt changes in shallow geologic units control preferential pathways for discharge of fresh water into the marine environment. Shore parallel resistivity profiles show dramatic decreases in magnitude with increasing distance from shore, suggesting a significant portion of the terrestrially driven fresh SGD in Long Bay is occurring via the surficial aquifer within a few hundred meters of shore. 相似文献
89.
Doug W. Johnson Simon Osborne Robert Wood Karsten Suhre Patricia K. Quinn Tim Bates M. O. Andreae Kevin J. Noone Paul Glantz Brian Bandy J. Rudolph Colin O'Dowd 《Tellus. Series B, Chemical and physical meteorology》2000,52(2):348-374
During the 1st Lagrangian experiment of the North Atlantic Regional Aerosol Characterisation Experiment (ACE‐2), a parcel of air was tagged by releasing a smart, constant level balloon into it from the Research Vessel Vodyanitskiy . The Meteorological Research Flight's C‐130 aircraft then followed this parcel over a period of 30 h characterising the marine boundary layer (MBL), the cloud and the physical and chemical aerosol evolution. The air mass had originated over the northern North Atlantic and thus was clean and had low aerosol concentrations. At the beginning of the experiment the MBL was over 1500 m deep and made up of a surface mixed layer (SML) underlying a layer containing cloud beneath a subsidence inversion. Subsidence in the free troposphere caused the depth of the MBL to almost halve during the experiment and, after 26 h, the MBL became well mixed throughout its whole depth. Salt particle mass in the MBL increased as the surface wind speed increased from 8 m s−1 to 16 m s−1 and the accumulation mode (0.1μm to 3.0 μm) aerosol concentrations quadrupled from 50 cm−3 to 200 cm−3 . However, at the same time the total condensation nuclei (>3 nm) decreased from over 1000 cm−3 to 750 cm−3 . The changes in the accumulation mode aerosol concentrations had a significant effect on the observed cloud microphysics. Observational evidence suggests that the important processes in controlling the Aitken mode concentration which, dominated the total CN concentration, included, scavenging of interstitial aerosol by cloud droplets, enhanced coagulation of Aitken mode aerosol and accumulation mode aerosol due to the increased sea salt aerosol surface area, and dilution of the MBL by free tropospheric air. 相似文献
90.
This study uses long‐term records of stream chemistry, discharge and air temperature from two neighbouring forested catchments in the southern Appalachians in order to calculate production of dissolved CO2 and dissolved inorganic carbon (DIC). One of the pair of catchments was clear‐felled during the period of the study. The study shows that: (1) areal production rates of both dissolved CO2 and DIC are similar between the two catchments even during and immediately after the period of clear‐felling; (2) flux of total inorganic carbon (dissolved CO2+ DIC) rises dramatically in response to a catchment‐wide acidification event; (3) DIC and dissolved CO2 are dominantly released on the old water portion of the discharge and concentrations peak in the early autumn when flows in the study catchments are at their lowest; (4) total fluvial carbon flux from the clear‐felled catchment is 11·6 t km−2 year−1 and for the control catchment is 11·4 t km−2 year−1. The total inorganic carbon flux represents 69% of the total fluvial carbon flux. The method presented in the study provides a useful way of estimating inorganic carbon flux from a catchment without detailed gas monitoring. The time series of dissolved CO2 at emergence to the stream can also be a proxy for the soil flux of CO2. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献