Activity–composition relations for phases in petrological calculations: an asymmetric multicomponent formulation

For petrological calculations, including geothermobarometry and the calculation of phase diagrams (for example, P–T petrogenetic grids and pseudosections), it is necessary to be able to express the activity–composition (a–x) relations of minerals, melt and fluid in multicomponent systems. Although the symmetric formalism—a macroscopic regular model approach to a–x relations—is an easy-to-formulate, general way of doing this, the energetic relationships are a symmetric function of composition. We allow asymmetric energetics to be accommodated via a simple extension to the symmetric formalism which turns it into a macroscopic van Laar formulation. We term this the asymmetric formalism (ASF). In the symmetric formalism, the a–x relations are specified by an interaction energy for each of the constituent binaries amongst the independent set of end members used to represent the phase. In the asymmetric formalism, there is additionally a "size parameter" for each of the end members in the independent set, with size parameter differences between end members accounting for asymmetry. In the case of fluid mixtures, for example, H₂O–CO₂, the volumes of the end members as a function of pressure and temperature serve as the size parameters, providing an excellent fit to the a–x relations. In the case of minerals and silicate liquid, the size parameters are empirical parameters to be determined along with the interaction energies as part of the calibration of the a–x relations. In this way, we determine the a–x relations for feldspars in the systems KAlSi₃O₈–NaAlSi₃O₈ and KAlSi₃O₈–NaAlSi₃O₈–CaAl₂Si₂O₈, for carbonates in the system CaCO₃–MgCO₃, for melt in the melting relationships involving forsterite, protoenstatite and cristobalite in the system Mg₂SiO₄–SiO₂, as well as for fluids in the system H₂O–CO₂. In each case the a–x relations allow the corresponding, experimentally determined phase diagrams to be reproduced faithfully. The asymmetric formalism provides a powerful and flexible way of handling a–x relations of complex phases in multicomponent systems for petrological calculations.     

井间断层的计算机分析方法

井间断层分析的研究,是油气储层地质研究的一项重要基础性工作,对油气的运移和聚集其中重要的控制作用。它是利用测井资料,以地层分层为基础,采用计算机技术实现井间断层分析的一种井间断层自动分析方法。动态波形匹配算法是本次研究采用的主要算法,它能够很好地建立井间地层之间的对比关系,通过曲线拟合、特征提取、匹配代价计算等步骤,自动绘制井间地层对比的路径图解。本文在对各种构造的路径图分析的基础上,总结出正断层、逆断层、不整合、同沉积断层、犁式断层和地层尖灭等30种情况下的路径图模式,提出路径图模式及相关概念。在大港油田的实例分析中取得了很好的效果。     

青藏高原东部全新世冬夏季风变化的高分辨率泥炭记录

在建立了全新世泥炭沉积物高分辨率冬夏季风代用指标时间序列的基础上, 发现青藏高原若尔盖地区全新世冬夏季风的变化具有此消彼长和同时消长两种基本的模式, 冬季风与夏季风在不同时间尺度上两种模式又相互嵌套. 由冬夏季风指标叠加效应合成的气候状况却有与全球同步的规律性, 表现出千年-百年尺度的不稳定性, 6.2 ka的季风突然减弱事件要比8.0 ka的事件更显著, 反映了亚洲季风的区域特点或它本身就是全球气候的一个窗口.     

The effect of organic materials on the mobility and toxicity of metals in contaminated soils

Organic materials such as compost are often proposed as suitable materials for the remediation of contaminated brownfield sites intended for soft end-use. In addition to vitalising the soil, they are also believed to immobilise metals thereby breaking contaminant-receptor pathways and reducing the ecotoxicity of the contaminants. However, some research has demonstrated contradictory effects between composts on metal immobilisation. In the present study, four different composts and a liming product containing organic matter (LimeX70) were tested to examine both their metal retention and toxicity reduction capabilities on three different metal contaminated soils. Leaching tests, a plant growth test with Greek cress (Lepidium sativum), an earthworm (Eisenia fetida) survival and condition test and a bacterial toxicity test using Vibrio fischeri were carried out. The leaching test results showed that spent mushroom compost caused an increase in metal concentration in the leachates, while LimeX70 caused a decrease. The variation in behaviour between different amendments for each soil was high, so a generic conclusion could not be drawn. Toxicity tests showed significant reduction of metal bioavailability and toxicity for Greek cress, earthworms and bacteria. The results also suggest that more research should be undertaken to understand the mechanisms involved in metal complexation using different types of organic matter, in order to optimise the use of organic materials like compost for soil remediation.     

The problem of underpowered rivers

This study has hypothesized that for many rivers the trade-off between flow accumulation and the decrease in slope along channel length means that stream power increases downstream and, moreover, that given the low slope angles in headwater and low-order streams, they would have insufficient stream power to erode let alone transport sediment. The study considered the stream power profile, the particle travel distances and the application of the Hjulström curve based on the velocity profile of nine, large UK catchments. The study showed that:

1. Some rivers never showed a maximum in their longitudinal stream power profile, implying that some rivers never develop a deposition zone before they discharge at the tidal limit.
2. Particle travel distances during a bankfull discharge event showed that for some rivers 91% of the upper main channel would not be cleared of sediment. Furthermore, while some rivers could transport a 2 mm particle their entire length in one bankfull event, for another river it would take 89 such events.
3. The Hjulström curve shows that for three of the study rivers the upper 20 km of the river was not capable of eroding a 2 μm particle.
4. The study has shown that for all rivers studied, erosion is focused downstream and deposition upstream. Many UK rivers have a dead zone where, on time scales of the order of centuries, no erosion or transport occurs and erosion only occurs in the lower courses of the channel where discharge rather than slope dominates – we propose these as underpowered rivers.

© 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

A Discussion of IGS Solutions and Their Impact on Geodetic and Geophysical Applications

The International Association of Geodesy officially established the International GPS Service (IGS) on Janaury 1, 1994. Its prime objective is to provide support and a rerefence system for a wide variety of scientific and practical applications involving GPS. To fulfill its role the IGS also generates, in addition to its fundamental products (orbital/staion positions and consistent Earth orientation parameters), additional reference-system products providing the necessary infrastructure, standards, and means of calibrations for timing and various atmospheric applications of GPS. The generation and efficient application of IGS products and their impact on a number of positioning and atmospheric applications, including low earth orbit satellites, is reviewed and discussed. @ 1998 John Wiley & Sons, Inc.     

Tropical Cyclone Size Change under Ocean Warming and Associated Responses of Tropical Cyclone Destructiveness: Idealized Experiments

The power dissipation index (PDI), which is defined as the sum of the cube of tropical cyclone (TC) maximum wind speed during TC lifetime, is widely used to estimate the TC destructive potential. However, due to the lack of high-resolution observations, little attention has been paid to the contribution of TC size change to TC destructive potential in response to ocean warming. In this study, sensitivity experiments are performed by using the high-resolution Weather Research and Forecasting (WRF) model to investigate the responses of TC size and TC destructive potential to prescribed sea surface temperature (SST) increase under the present climate condition. The results show that TC size increases with the ocean warming. Possible reasons for TC size change are investigated with a focus on the outer air-sea moisture difference (ASMD). As SST increases, ASMD in the outer zone of the TC is larger than that in the inner zone, which increases the surface entropy flux (SEF) of the outer zone. This change in the radial distribution of SEF causes the increase of tangential wind in the outer zone, which further increases SEF, resulting in a positive feedback between outer-zone SEF and outer-zone tangential wind. This feedback leads to the increase of the radius of gale-force wind, leading to the expansion of TC size. Moreover, to estimate the contribution of TC size change to TC destructiveness, we calculate TC size-dependent destructive potential (PDS) as the storm size information is available in the model outputs, as well as PDI that does not consider the effect of TC size change. We find that PDS increases exponentially as SST increases from 1 to 4°C, while PDI increases linearly; hence the former is soon much greater than the latter. This suggests that the growth effect of TC size cannot be ignored in estimating destructiveness under ocean warming.     

The Anglo-Brabant Massif: Persistent but enigmatic palaeo-relief at the heart of western Europe

The surface geology of central England and Belgium obscures a large ‘basement’ massif with a complex history and stronger crust and lithosphere than surrounding regions. The nucleus was forged by subduction-related magmatism at the Gondwana margin in Ediacaran time. Partitioning into a platform, in the English Midlands, and a basin stretching to Belgium, in the east, was already evident in Cambrian/earliest Ordovician time. The accretion of the Monian Composite Terrane during the Penobscotian deformation phase preceded late Tremadocian rifting, and Floian separation, of the Avalonia Terrane from the Gondwana margin. Late Ordovician magmatism in a belt from the Lake District to Belgium records subduction beneath Avalonia of part of the Tornquist Sea. This ‘Western Pacific-style’ oceanic basin closed in latest Ordovician time, uniting Avalonia and Baltica. Closure of the Iapetus Ocean in early Silurian time was soon followed by closure of the Rheic Ocean, recorded by subduction along the southern margin of the massif. The causes of late Caledonian deformation are poorly understood and controversial. Partitioned behaviour of the massif persisted into late Palaeozoic time. Late Devonian and Carboniferous sequences show strong onlap onto the massif, which was little affected by crustal extension. Compressional deformation during the Variscan Orogeny also appears slight, and was focussed in the west where a wedge-shaped mountain foreland uplift was driven by orogenic indentation, splitting the massif from the Welsh Massif along the reactivated Malvern Line. Permian to Mesozoic sequences exhibit persistent but variable degrees of onlap onto the massif.