Site occupation and electric field gradient in acentric neptunite-measurements and evaluations concerning powder- and single crystal – Mössbauer spectroscopy and x-ray diffractometry

Mössbauer measurements on neptunite (KNa₂Li(Fe,Mn,Mg)₂Ti₂Si₈O₂₄) at 400?K reveal the distribution of Fe-ions on the crystallographic sites in agreement with neutron diffraction results published elsewhere. Even the previously postulated small amount of Fe-ions on the Ti(2) site has been detected, combined with a charge transfer which is in agreement with optical absorption investigations by other authors. A qualitative site occupation model is able to explain the different features of our observations. Single crystal Mössbauer measurements with the k-vector of incident γ-rays parallel to the crystallographic b-axis (space group Cc) of neptunite at different temperatures yield the angle β between the main component of the electric field gradient (EFG), V _zz and b. This angle is in close accordance with a calculated value of β for the Fe(1) position from electron density maps. The latter also reveal an absolute value of V _zz which is in satisfactory agreement with V _zz derived from Mössbauer spectroscopy.     

Jupiter: New retrieved thermal profiles and ammonia distributions

New thermal profiles of Jupiter are retrieved from recent far infrared spectral measurements and for H₂ mixing ratios varying from 0.8 to 0.94. The effective temperature corresponding to the inferred thermal profile is 123.15 ± 0.35°K. Far-infrared brightness temperature spectra computed from these profiles are compared to experimental data including measurements made at high spectral resolution in the NH₃ν₂ band at 10 μm and in NH₃ pure rotational bands between 40 and 110 μm. It is found that a strong depletion of NH₃ does occur in the Jovian stratosphere and that ammonia seems to be undersaturated in the upper troposphere.     

Galilean satellite eclipse studies: III. Jovian methane abundance

The methane abundance in the lower Jovian stratosphere is measured using Galilean satellite eclipse light curves. Spectrally selective observations in and between absorption bands are compared. An average mixing ratio at the locations measured is [CH₄]/[H₂] ～ 1.3 × 10^?3, larger than the value 0.9 × 10^?3 expected for a solar abundance of carbon. Some zenographic variation of the mixing ratio may occur. Observationally compatible values are 1.3–2.0 × 10^?3 in the STZ, 1.3– 2.6 × 10^?3 on the GRS/STrZ edge, and 0.7–1.3 × 10^?3 in the GRS.     

40Ar39Ar ages of Allende

KAr and/or ⁴⁰Ar³⁹Ar plateau ages of Allende samples—whole rock, matrix, chondrules, white inclusions–range from 3.8 AE for matrix of ?5 AE for some white inclusions, but cluster strongly near 4.53 AE. This age marks the dominant KAr resetting of Allende materials. Age spectra show disturbances due to ³⁹Ar recoil or some other argon redistribution processes. Possible explanations for the apparent presolar ages (>4.6 AE) include: ?20% loss of ³⁹Ar; ?40% loss of ⁴⁰K ～3.8 AE ago with no loss of ⁴⁰Arl trapped argon of unique ⁴⁰Ar/³⁶Ar isotopic composition; admixture of “very old” presolar grains.     

Systematic reductions of 19th century planetary observations

Systematic reductions of nineteenth century observations to the system of the FK4 are discussed. Reductions made on a nightly basis are described and compared with the results obtained through the use of conventional tables. The series of observations made at the Paris Observatory from 1837 to 1881 was used to compare the two methods, and a combined system of 24 000 FK4, FK4 Sup and AGK 3R positions and proper motions provided the reference stars. The results show that for Uranus the mean error of a single observation in right ascension is ±1..33 when tables are used for the reductions, and ±1.12 when nightly reductions are made, while in declination the corresponding mean errors are ±0.88 and ±0.80. The observations of Neptune show an even greater difference between the two methods; the mean errors for the tabular and nightly reductions are ±1.57 and ±1.09 in right ascension and ±0.88 and ±0.75 in declination. Secular rates in the (0–C)'s of Uranus of –0.029/year in right ascension and ±0.030/year in declination are present when the observations are reduced with tables. These rates are reduced to –0.007/year and +0.015/year, respectively, when nightly reductions are made.Presented at the Symposium Star Catalogues, Positional Astronomy and Celestial Mechanics, held in honor of Paul Herget at the U.S. Naval Observatory, Washington, November 30, 1978.     

X-ray imaging of three flares during the impulsive phase

The impulsive phases of three flares that occurred on April 10, May 21, and November 5, 1980 are discussed. Observations were obtained with the Hard X-ray Imaging Spectrometer (HXIS) and other instruments aboard SMM, and have been supplemented with Hα data and magnetograms. The flares show hard X-ray brightenings (16–30 keV) at widely separated locations that spatially coincide with bright Hα patches. The bulk of the soft X-ray emission (3.5–5.5 keV) originates from in between the hard X-ray brightenings. The latter are located at different sides of the neutral line and start to brighten simultaneously to within the time resolution of HXIS. Concluded is that:

1. The bright hard X-ray patches coincide with the footpoints of loops.
2. The hard X-ray emission from the footpoints is most likely thick target emission from fast electrons moving downward into the dense chromosphere.
3. The density of the loops along which the beam electrons propagate to the footpoints is restricted to a narrow range (10⁹ < n < 2 × 10¹⁰ cm^-3), determined by the instability threshold of the return current and the condition that the mean free path of the fast electrons should be larger than the length of the loop.
4. For the November 5 flare it seems likely that the acceleration source is located at the merging point of two loops near one of the footpoints.

It is found that the total flare energy is always larger than the total energy residing in the beam electrons. However, it is also estimated that at the time of the peak of the impulsive hard X-ray emission a large fraction (at least 20%) of the dissipated flare power has to go into electron acceleration. The explanation of such a high acceleration efficiency remains a major theoretical problem.     

Spatial and temporal evolution of soft and hard X-ray emission in a solar flare

We study the spatial and temporal characteristics of the 3.5 to 30.0 keV emission in a solar flare on April 10, 1980. The data were obtained by the Hard X-ray Imaging Spectrometer aboard the Solar Maximum Mission Satellite. It is complemented in our analysis with data from other instruments on the same spacecraft, in particular that of the Hard X-ray Burst Spectrometer.Key results of our investigation are: (a) Continuous energy release is needed to substain the increase of the emission through the rising phase of the flare, before and after the impulsive phase in hard X-rays. The energy release is characterized by the production of hot (5 × 10⁷ T 1.5 × 10⁸ K) thermal regions within the flare loop structures. (b) The observational parameters characterizing the impulsive burst show that it is most likely associated with non-thermal processes (particle acceleration). (c) The continuous energy release is associated with strong chromospheric evaporation, as evidenced in the spectral line behavior determined from the Bent Crystal Spectrometer data. Both processes seem to stop just before flare maximum, and the subsequent evolution is most likely governed by the radiative cooling of the flare plasma.     

The equatorial photospheric rotation rate

The equatorial photospheric rotation rate has been observed on 14 days in 1978–1980. The resulting rotation rate, = 14.14±0.04°/day, is 2% slower than the rate as observed for long-lived sunspots.Stationed at Kitt Peak National Observatory.Operated by the Association of Universities for Research in Astronomy, Inc. under contract with the National Science Foundation.     

Crustal structure of the Rhenish Massif: results of deep seismic reflection lines Dekorp 2-North and 2-North-Q

The reflection seismic line DEKORP 2-N reveals an almost complete cross section through the Rhenohercynian Zone, the most external part of the Variscan orogen in Europe.The northern part of DEKORP 2-N and a NE-directed branch (2-N-Q) reveal the Cretaceous of the Münsterland basin and the underlying folded Palaeozoic rocks. The northward decreasing intensity of folding is depicted in great detail by the highly reflective Late Carboniferous coal-measures and deeper reflections down to the level of the Givetian/Frasnian shallow-water carbonates.In the Devonian and older rocks of the Rhenish Massif, bedding is only represented by relatively weak, short and irregular reflections. These are truncated by stronger, southward dipping reflections, which exhibit the listric curvature and flat/ramp geometry characteristic of faults. In the northern part of the section, the thrusts appear to be blind. From the Ebbe Anticline southwards, prominent reflections can be correlated with important thrust faults known from the surface, such as the Ebbe-, Siegen-, Müsen- and Sackpfeife- Thrusts, as well as further important thrust faults in the Lahn- and Dill Synclines. The basal thrust of the extremely thin-skinned Giessen Nappe is only recognizable for a very short distance.At depth, the thrusts flatten out in a relatively transparent zone between 3–5 s TWT, with strongly reflective bands at its bottom and top. The transparent zone might correlate with a high-conductivity layer detected in a magnetotelluric survey; it represents either graphitic metapelites or a zone with an interconnected, brine-filled pore space. The seismic record relates either to lithological differences, or to rheological boundaries.The lower crust in the north is characterized by a relatively transparent zone, which wedges out towards south under the northern margin of the Siegen Anticline. Comparisons with a similar feature in the ECORS profile »Nord de la France« suggest that the transparent zones in both sections correspond to a pre-Palaeozoic basement, such as it underlies the Brabant Massif. Further south, the lower crust is increasingly reflective.The curvilinear, thrust-related reflections are cut by a conjugate set of much weaker, N- and S-dipping reflectors indicating a later deformation with pure shear. Displacement of some marker reflections suggests late- or post-Variscan compression.In an alternative interpretation, these straight and weak reflections represent the only thrust faults, while the curvilinear elements might relate to bedding.A southward rise of the Moho from approx. 11 to 8.5 s TWT is probably due to Tertiary rifting.

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Zusammenfassung Das reflexionsseismische Profil DEKORP 2-N stellt einen fast vollständigen Querschnitt durch das Rhenohercynikum dar.Der nördliche Teil des Profiles 2-N sowie ein SW/NE-verlaufender Abzweig (2-N-Q) zeigen die Transgression der Münsterländer Kreide und das unterlagernde gefaltete Paläozoikum. Schichtgebundene Reflektoren (flözführendes Karbon, devonischer Massenkalk) bilden das Ausklingen der variscischen Faltung nach NW detailliert ab.In den devonischen und vordevonischen Sedimenten des rechtsrheinischen Schiefergebirges erzeugt die Schichtung nur relativ schwache, kurze und unregelmäßige Reflexionen. Diese werden von stärkeren, südfallenden Reflektoren abgeschnitten, die aufgrund ihrer listrischen Krümmung und flat/ramp-Geometrie wahrscheinlich als Überschiebungen zu interpretieren sind. Im Nordteil des Schiefergebirges sind diese Überschiebungen offenbar blind, werden also nahe der Oberfläche durch Faltung kompensiert. Im Ebbe-Sattel und weiter südlich lassen sich die meisten der starken, südfallenden Reflektoren zweifelsfrei mit bekannten Großüberschiebungen korrelieren (Ebbe-, Siegen-, Müsen-, Sackpfeife-Ü, sowie weitere Überschiebungen in der Lahn- u. Dill-Mulde). Die Basisüberschiebung der Giessen-Decke wird nur teilweise abgebildet.Zur Tiefe hin zeigen die Überschiebungen ein zunehmend flacheres Einfallen, und verschwinden in einer relativ transparenten Zone zwischen 3 und 5 s TWT, die im Hangenden und Liegenden durch dünne, stark reflektive Zonen begrenzt ist. Diese transparente Zone entspricht möglicherweise einer Zone hoher integrierter Leitfähigkeit, die in einem begleitenden magnetotellurischen Experiment nachgewiesen worden ist; es handelt sich entweder um einen Graphit-führenden Phyllit-Horizont oder eine mächtigere permeable Zone mit Elektrolyt-gefülltem Porenraum. Die hochreflektiven Bänder über und unter der transparenten Zone entsprechen entweder lithologischen Kontrasten oder rheologischen Grenzen, die vermutlich von einer scherenden Verformung überprägt worden sind.Die Unterkruste im N-Teil des Profiles enthält einen relativ transparenten Bereich, der nach Süden hin unter dem Nordteil des Siegener Sattels keilförmig ausläuft. Ein ähnliches Bild zeigt der Nordteil des ECORS-Profiles »Nord de la France«. Die transparenten Bereiche beider Profile entsprechen wahrscheinlich einem prä-paläozoischen kristallinen Basement, das das Brabanter Massif unterlagert und sich rechtsrheinisch fortsetzt. Südlich des transparenten Keiles wird die Unterkruste zunehmend reflexionsreicher. Die listrisch gekrümmten, an Überschiebungen gebundenen Reflektoren werden von einem konjugierten System schwächerer, N- u. S-fallender Reflektoren abgeschnitten, die auf eine jüngere, bruchhafte Verformung durch reine Scherung hindeuten. Der Versatz einiger älterer Reflektoren deutet auf spät- oder postvariscische Kompression hin.In einer alternativen Interpretation werden nur diese jüngeren Reflektoren als Überschiebungen gedeutet; die älteren, gekrümmten Elemente müßten dann primären lithologischen Grenzen entsprechen.Die Moho steigt von ca. 11 s TWT im N auf 8.5 s TWT unter dem Taunus an. Die Krustenverdünnung im Süden geht wahrscheinlich auf Dehnung im Tertiär zurück.

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Résumé Le profil sismique par réflexion DEKORP-2-N représente une transversale quasiment complète à travers la zone rhénohercynienne. La partie septentrionale du DEKORP-2-N ainsi qu'une branche de direction SW-NE (2-N-Q) mettent en évidence la transgression du Crétacé du Münsterland sur le Paléozoïque sous-jacent plissé. Des réflecteurs liés à la stratification (à savoir: le Houiller et les calcaires de plate-forme dévoniens) illustrent de façon détaillée la diminution vers le nord de l'intensité du plissement varisque.Dans les sédiments dévoniens et pré-dévoniens du Massif Rhénan à l'est du Rhin, la stratification ne fournit que que des réflexions relativement faibles, courtes et irrégulières. Elles sont tronquées par des réflecteurs plus intenses, à pendage sud qui, en raison de leur courbure listrique et de leur géométrie en «flat/ramp», doivent être interprétés comme des chevauchements. Dans la partie septentrionale du Massif, ces chevauchements sont apparemment aveugles, c'est-à-dire qu'ils sont compensés, près de la surface, par le plissement. Dans l'anticlinal d'Ebbe, ainsi que plus au sud, la plupart des réflecteurs intenses à plongement sud peuvent être corrélés avec des chevauchements majeurs connus, tels ceux de Ebbe, Siegen, Müsen, Sackpfeife et d'autres encore dans les synclinaux de la Lahn et de la Dill. Le chevauchement basai de la nappe de Giessen n'est que partiellement représenté.Les chevauchements deviennent de plus en plus plats en profondeur pour disparaître dans une zone relativement transparente qui se situe entre 3–5 sec TWT. Celle-ci est prise en sandwich par des zones minces à forte réflectivité. La zone transparente correspond probablement à une zone de conductivité intégrée élevée dont l'existence a par ailleurs été démontrée dans un essai magnétotellurique mené parallèlement. Il s'agit soit d'un horizon phyllitique graphiteux, soit d'une zone perméable plus épaisse dont les pores sont remplis d'électrolyte. Les bandes à haute réflectivité au-dessus et en-dessous de la zone transparente correspondent soit à des contrastes lithologiques, soit à des limites rhéologiques probablement accentuées par la déformation cisaillante.La croûte inférieure dans la partie septentrionale du profil comporte un domaine relativement transparent qui s'amincit vers le S et se termine, en dessous de la partie nord de l'anticlinal de Siegen, en forme de coin. La partie nord du profil ECORS «Nord de la France» montre une image semblable.Les domaines transparents des deux profils correspondent vraisemblablement à un soubassement cristallin pré-paléozoïque qui est sousjacent au Paléozoïque du Massif du Brabant et se prolonge vers l'est au-delà du Rhin. Au sud du coin transparent, la réflectivité de la croûte inférieure va en augmentant. Les réflecteurs listriques liés à des chevauchements sont recoupés par un système conjugué de réflecteurs plus faibles à plongement nord et sud qui indiquent des failles plus récentes. Le déplacement de quelques réflecteurs plus anciens suggère l'effet d'une compression tardiou post-varisque.Dans une interprétation alternative, seuls ces réflecteurs plus récents sont considérés comme correspondant à des chevauchements. Dans ce cas, les éléments courbes plus anciens devraient représenter des limites lithologiques primaires.Le Moho s'élève à partir de 11 sec TWT environ au nord jusqu'à 8.5 sec TWT en-dessous du Taunus. L'amincissement crustal au sud résulterait du régime de distension survenu au Tertiaire.

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DEKORP 2 Nord. x-t- ray-tracing'a. 6,0 6,6 /, — 7,0 8,2 /. 6,25 /. 28 30 . , .

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Abbreviations MORB Mid-Ocean Ridge Basalt - TWT two-way travel time, seconds (s) - CMP common mid-point - VP vibration point - SNR signal to noise ratio     

Study of the influence of katabatic flows on the Antarctic circulation using GCM simulations

Summary A one dimensional analytical model of katabatic wind over the Antarctica has been developed. This parametric model is derived from the bulk two-layer model of Ball including the surface friction and taking into account the Earth's rotation and the geostrophic wind in the upper layer.This model is validated using the data set (70 soundings) collected during IAGO experiment at D47 (67°24S, 138°43E, altitude 1 564m), 110 km inland from the coast of Adélie Land.The parameteric model is then introduced into a GCM which is a spectral global version of the operational numerical weather prediction model used by the French weather service. The most significant effect of the parameterization is a 50 m increase of the geopotential height over the South Pole. The surface temperature at the South Pole increases (2°C) reducing the pole-midlatitude thermal gradient. The westerly circulation at 50° S is slowed down (4m/s at 850 hPa), and the surface pressure at the South Pole increases (4hPa). These results, consistent with an increase of katabatic winds, would however be improved by a better coupling between the parameterization and the GCM boundary layer.With 8 Figures