THREE-WAY METHODS FOR THE CALIBRATION OF CHROMATOGRAPHIC SYSTEMS:COMPARING PARAFAC AND THREE-WAY PLS

For the calibration of chromatographic systems,different methods can be used.One class of methodsutilizes three-way approaches.The calibration problem is stated in such a way that the decompositionof a three-way array can serve for the prediction of retention on new stationary phases.Two three-way approaches are presented:the Unfold-PCA and PARAFAC models.The theory ofboth methods is presented and the differences are highlighted,the main difference being that PARAFACis a trilinear decomposition whereas Unfold-PCA is not.Both three-way methods are evaluated on asmall data set consisting of retention measurements of eight solutes at six mobile phase compositions onsix stationary phases.The differences in performance of the two models are minor,For calibration purposes,two variants of the methods are discussed:three-way PLS and an extensionof PARAFAC.Again the theory and differences between the two methods are explained.The predictiveperformance of the two methods is compared using the same data set as earlier.The differences inpredictive performance,however,are minor.Both methods are capable of predicting 98% of thevariation in the test sets.Yet,there are other considerations when comparing methods than predictiveperformance,e.g.the quality of the predictions.     

Dawn; the Vesta–HED connection; and the geologic context for eucrites,diogenites, and howardites

The Dawn mission has provided new evidence strengthening the identification of asteroid Vesta as the parent body of the howardite, eucrite, and diogenite (HED) meteorites. The evidence includes Vesta's petrologic complexity, detailed spectroscopic characteristics, unique space weathering, diagnostic geochemical abundances and neutron absorption characteristics, chronology of surface units and impact history, occurrence of exogenous carbonaceous chondritic materials in the regolith, and dimensions of the core, all of which are consistent with HED observations and constraints. Global mapping of the distributions of HED lithologies by Dawn cameras and spectrometers provides the missing geologic context for these meteorites, thereby allowing tests of petrogenetic models and increasing their scientific value.     

The reflection seismic survey of project TIPTEQ—the inventory of the Chilean subduction zone at 38.2° S

We describe results of an active-source seismology experiment across the Chilean subduction zone at 38.2°S. The seismic sections clearly show the subducted Nazca plate with varying reflectivity. Below the coast the plate interface occurs at 25 km depth as the sharp lower boundary of a 2–5 km thick, highly reflective region, which we interpret as the subduction channel, that is, a zone of subducted material with a velocity gradient with respect to the upper and lower plate. Further downdip along the seismogenic coupling zone the reflectivity decreases in the area of the presumed 1960 Valdivia hypocentre. The plate interface itself can be traced further down to depths of 50–60 km below the Central Valley. We observe strong reflectivity at the plate interface as well as in the continental mantle wedge. The sections also show a segmented forearc crust in the overriding South American plate. Major features in the accretionary wedge, such as the Lanalhue fault zone, can be identified. At the eastern end of the profile a bright west-dipping reflector lies perpendicular to the plate interface and may be linked to the volcanic arc.     

Chemical Composition of Ancient Celadon Material （1127-1279 A.D.） from Zhejiang, China and Its Implication

The microprobe EDXRF equipment was used for analysis of the major and trace elements in glaze layer-transitive layer-body layer of the celadon from the Altar Yao （Kiln） and Laohudong Yao in the Southern Song Dynasty （1127-1279 A.D.）, Zhejiang, China. The K values of the discriminant factor for the celadon wares are larger than 8, which means the celadon of the Altar Yao and Laohudong Yao are different from that of the Longquan Yao. The former two belong to the Guan Yao system （the Chinese imperial kilns）, but the latter to the Min Yao system （the Chinese popular kilns）. The principle component analysis shows their relationship between the Altar and Laohudong wares with provenance postulation. The thickness of the transitive layer in the Altar and Laohudong wares is obviously different, which reveals the microstructure characteristics of the celadon even though both kinds of wares belong to the imperial kiln system.     

青藏高原东北部黄河源区大暖期气候特征

本文通过孢粉、有机碳和粘土矿物的分析,探讨了黄河源区全新世的气候变迁,重点论述了大暖期的气候特点。在全新世,黄河源区的气候总体凉干,属于高原的高寒气候。在大暖期,该区的气候较现今高2～3℃,显得湿润些,但波动较频繁,尤其是大暖期的后期波动剧烈,并在5．0kaBP前后发生一次剧烈的降温。记录表明,黄河源区的大暖期始于9．0kaBP,止于2．30kaBP,较我国其他地区开始得早,而结束得晚,其鼎盛时期为6．0kaBP前后。     

塔巴庙地区上古生界砂岩成岩作用特征及其储集性分析

鄂尔多斯盆地北部塔巴庙地区上古生界发育一套低孔低渗致密砂岩储层,储集空间以溶蚀微孔、蜂窝状溶孔和高岭石晶间隙为主,孔喉以细——微细为主。成岩作用决定了砂岩内部储集空间特征和储集性能,主要表现在较强的压实作用和胶结作用使砂岩的原生孔隙很少得到保存;较弱的溶蚀作用和强的蚀变作用使砂岩储集空间以微孔、超微孔为主,具有孔径小喉道细的特征,这是砂岩储集物性特别是渗透率偏低的直接原因。     

陕西凤县八方山-二里河（铜）铅锌矿床地质特征及成矿模式

在综合分析凤-太矿集区成矿构造特征的基础上，依据以往总结的凤．太矿田铅锌、金矿聚矿构造模式，通过对八方山-二里河铅锌矿床地质特征的分析，总结了找矿标志，初步认为八方山-二里河（铜）铅锌矿床的成矿模式为：“前泥盆纪海底热水喷流沉积一印支-燕山期构造改造型”铅锌矿床。认为成矿物质来源于基底，后期的构造-岩浆改造使基底成矿元素活化，沿同生断裂迁移、改造，最后在泥盆系中形成的扩容性构造部位富集成矿。提出了下一步扩大找矿的方向和建议。     

Distribution of Arsenic in Sewage Irrigation Area of Pearl River Delta,China

The aim of the present work is to investigate the distribution of arsenic(As) in sewage ir-rigation area,to deduce the migration and transformation mechanism of As in soil and groundwater,and to infer the source of As in soil and groundwater.This study is carried out in a sewage irrigation area of the Pearl River Delta,China.Surface water samples,soil samples,and groundwater samples from sewage irrigation area were analyzed for As and other elements.As contents in water samples were analyzed by hydride gene...     

西太平洋海山磷酸盐的常量、微量和稀土元素地球化学研究

本文对主要取自于西太平洋我国调查区内不同海山、不同水深、不同产状的13个磷酸盐样品进行了常量、微量和稀土元素测定,以探讨与大洋富钴结壳密切伴生的磷酸盐的常、微量和稀土元素地球化学的特征。分析结果表明,调查区磷酸盐中主要氧化物的平均值与赤道太平洋的相近,暗示两者可能有相似的形成环境和形成机制。磷酸盐中微量元素Sr、Ba、Co、Cu、Ni及U丰度分别变化于862×10~(-6)～2181×10~(-6)、29×10~(-6)～3429×10~(-6)、6.3×10~(-6)～115×10~(-6)、23×10~(-6)～263×10~(-6)、12×10~(-6)～825×10~(-6)及4×10~(-6)～11×10~(-6),丰度多数低于泥质岩平均值,其CaO/P_2O_5、F/CO_2、Sr/P_2O_5值及常量、微量元素间的相关关系,清晰地显示了磷酸盐的种类、成分与结构、形成的地质背景和元素的主要组合特征。磷酸盐的稀土丰度为136.50×10~(-6)～853.70×10~(-6);Ce~*变化于0.01～0.18之间;(Ce/Yb)_N值变化于0.01～0.21之间。研究证实,不同产状磷酸盐的稀土元素配分模式基本一致,曲线相互平行,基本不呈现交叉现象,均呈Ce强烈亏损,轻、重稀土分馏程度大及重稀土富集的型式。调查区、赤道太平洋、中太平洋磷酸盐的稀土元素丰度、Ce~*、Ce/Yb值以及它们与海水稀土元素配分模式相似的特征,也进一步显     

滇西兰坪盆地五茂林剖面下白垩统景星组沉积相

实测了云南西部兰坪盆地东部下白垩统下部景星组的五茂林剖面,建立了曲流河、三角洲和湖泊3种沉积序列,其中三角洲序列在云南下白垩统中属首次建立。分析了粗碎屑岩的组成,将该剖面上出露的砾岩分成4类。早白垩世时兰坪盆地属丹那沙林-高黎贡弧的弧后盆地,景星组自下而上为曲流河沉积、三角洲沉积和湖泊沉积,且随湖侵发生,湖泊向西扩大。