A theoretical study of Comet Halley's spectrum in the infrared range

Synthetic spectra of Comet Halley between 2.5 and 15 μm are calculated on the basis of current cometary models. This study shows that molecules which are most likely detectable in the infrared range include H₂O, CO, CO₂, CH₄, NH₃, N₂H₄, and H₂CO. The flux emitted by these molecules, mostly due to resonant scattering, should be sufficient for detection by a flyby mission.     

Refining the timing of eclogite metamorphism: a geochemical,petrological, Sm-Nd and U-Pb case study from the Pohorje Mountains,Slovenia (Eastern Alps)

High-pressure metamorphism in the Pohorje Mountains of Slovenia (Austroalpine unit, Eastern Alps) affected N-MORB type metabasic and metapelitic lithologies. Thermodynamic calculations and equilibrium phase diagrams of kyanite–phengite-bearing eclogites reveal PT conditions of >2.1 GPa at T<750°C, but within the stability field of quartz. Metapelitic eclogite country rocks contain the assemblage garnet + phengite + kyanite + quartz, for which calculated peak pressure conditions are in good agreement with results obtained from eclogite samples. The eclogites contain a single population of spherical zircon with a low Th/U ratio. Combined constraints on the age of metamorphism come from U/Pb zircon as well as garnet–whole rock and mineral–mineral Sm-Nd analyses from eclogites. A coherent cluster of single zircon analyses yields a ²⁰⁶Pb/²³⁸U age of 90.7±1.0 Ma that is in good agreement with results from Sm-Nd garnet–whole rock regression of 90.7±3.9 and 90.1±2.0 Ma (εNd: +8) for two eclogite samples. The agreement between U-Pb and Sm-Nd age data strongly suggests an age of approximately 90 Ma for the pressure peak of the eclogites in the Pohorje Mountains. The presence of garnet, omphacite and quartz inclusions in unfractured zircon indicates high-pressure rather than ultrahigh pressure conditions. The analysed metapelite sample yields a Sm-Nd garnet–whole rock scatterchron age of 97±15 Ma. These data probably support a single P-T loop for mafic and pelitic lithologies of the Pohorje area and a late Cretaceous high-pressure event that affected the entire easternmost Austroalpine basement including the Koralpe and Saualpe eclogite type locality in the course of the complex collision of the Apulian microplate and Europe.     

Effects of 12 years' operation of a sewage treatment plant on trace metal occurrence within a Mediterranean commercial sponge (Spongia officinalis, Demospongiae)

The present field study uses Spongia officinalis for assessing trace metals occurrence in time and space within Mediterranean rocky communities. Nine sites were selected in the Marseille area for studying spatial trends in 12 metal concentrations. Long term changes in 8 metal concentrations were assessed at sites that had been sampled before and 12 years after the opening of a treatment plant. Spongia officinalis highly concentrated all the trace metal surveyed excepted Hg and Cd. The overall contamination level registered provided a classification of the study sites which is congruent with that given by other studies on pollutant accumulation in neighbouring sandy-bottoms or benthic assemblages. Among the metals studied, Fe, Pb, Cr are those that best highlighted a pollution gradient. In the present study, only Cd concentration did not vary in space. Except for Ni, all pollutant concentrations clearly decreased between 1984 and 1999. This very impressive decrease in heavy metal concentrations within the Marseille area represents an indisputable evidence of the improvement of the seawater quality resulting from 12 years' operation of the Marseille sewage plant. Moreover, the significant decrease also recorded in the reference population at Port-Cros might reflect an overall improvement in the seawater quality of the NW Mediterranean.     

Die Ablenkung des Lichtes an der Sonne und die Änderung Seiner Geschwindigkeit und Wellenlänge

Zusammenfassung Die Ergebnisse der Radar-Echo-Messungen von I. I. Shapiro, welche auf eine Verringerung der Lichtgeschwindigkeit beim Vorübergang des Lichtes an der Sonne hinweisen, werden zusammen mit der Ablenkung des Lichtes und der Verschiebung seiner Spektrallinien wellentheoretisch erklärt. Es genügt hierzu die Annahme eines materiellen lichtwellentragenden Mediums mit einer Dichte unterhalb des empirischen Vakuums; das Medium muss dann radial zur Sonne eine geringe Inhomogenität besitzen, die in entsprechenden kleinen Zusatzgliedern in den Maxwellschen Gleichungen ihren Ausdruck findet.Auf protophysikalischer Grundlage aufbauend wird die Phasengleichung (22) der an der Sonne vorbeigehenden Lichtwellen unter einfachsten Annahmen abgeleitet und integriert; als Resultat ergeben sich die drei genannten Effekte in Übereinstimmung mit der Erfahrung (Gleichung (39), (44), (47)).

---

Shapiro (1968) published the first results of radar-echo-observations on Venus and Mercury in the neighbourhood of upper conjunctions with the Sun; the observations indicate a decrease of the velocity of light passing the Sun. The theory of Soldner is disproved; and the general relativity is in accord with the observed facts. But not this theory alone. In this publication the deflection of light, decrease of the velocity of light, and displacement of spectral-lines are explained with the aid of a wavetheory. Hereby the assumption of a material medium carrying light-waves is sufficient, the density of which is below that of the empirical vacuum; hence, the medium must have a small inhomogeneityh radial to the Sun, and the Maxwell equations contain small additional terms (Equation (3)). They lead to the field equations (4) and (5). The protophysical fundamentals of the wave-theory (6), (8), (9), (10a) lead to the Equations (12) of wave-phase. If we assume that the behaviour of the light passing the Sun is independent (in first approximation) from the wave-form (F), the Equation (22) of wave-phase, is deduced for simple-periodic waves of light. Figure 1 outlines the slope and deflection of the ray of light by the Sun. Section 5 contains the solution of (22); and Section 6 the results. The constant of inhomogeneity =1/210^–5 (of the radius of the Sun) produces a deflection (39) of light passing the Sun. The length of waves of the light approaching the Sun is decreased to a minimum and is increasing with increasing distance from the Sun until the former value ((43) and (44)). The velocity of light approaching the Sun is decreased to a minimum and increases with increasing distance from the Sun to its former value ((46) and (47)).

     

Pulsated hydromagnetic flow with free-convection currents and mass transfer along a vertical infinite porous plate

The influence of free-convection currents and mass transfer in the case of laminar, non-steady boundary layer is studied here. The fluid is the air, considered incompressible and electrically conductive. The free-stream velocity oscillates about a mean value. A pulsated suction is also taken into account. A second meterial lies in small concentration in the fluid and absorbs part of the radiation. The influence of various parameters (G. M. etc.) on the flow is examined.     

Arsenic Speciation in Lichens and in Coarse and Fine Airborne Particulate Matter by HPLC–UV–HG–AFS

A three-step sequential extraction procedure with Milli-Q, CaCl₂ and H₃PO₄ was applied for extraction of arsenic species in lichen transplants and airborne particulate matter (fine and coarse fractions). The samples used in this work were collected in 1994–1995 near coal-fired power plants. Both transplant lichens and airborne particulate matter were submitted to the same environment simultaneously. Arsenic species identification and quantification was performed by HPLC–UV–HG–AFS. Inorganic forms of arsenic (arsenite and arsenate) were present in significant amounts in most of the samples. Only in lichens also organic forms of arsenic (monomethyl arsonic acid and dimethyl arsinic acid) were identified which may indicate biotransformation of inorganic arsenic.     

Ground-Based Observations of the Martian Atmosphere in Support of Space Missions

Although Mars is a favored target for planetary exploration, there is still a need for complementary ground-based observing programs of the Martian atmosphere, and this need will remain in the future. Indeed, as the atmosphere is very tenuous (less than 0.01 bar at the surface), the lines are very narrow and a high spectral resolving power (above 10⁴) is required over large spectral intervals. In addition, ground-based observations of Mars allow the instantaneous mapping of the whole planet, and thus the study of diurnal effects, which cannot be achieved from an orbiter. Recent ground-based achievements about the Martian atmospheric science include the first detection of H₂O₂ in the submillimeter range, the measurement of winds from CO millimetric transitions, the first detection of CH₄ and the O₃, H₂O₂, H₂O, and CH₄ mapping in the infrared. With an ELT, it will be possible to study at high spatial resolution transient atmospheric phenomena and to search for traces of minor constituents with unprecedented sensitivity. With ALMA, it will be also possible to search for minor species and to map the mesospheric winds for better constraining the climate models.     

Using neural networks for the derivation of Runge-Kutta-Nyström pairs for integration of orbits

In this paper we present Runge-Kutta-Nyström (RKN) pairs of orders 4(3) and 6(4). We choose a test orbit from the Kepler problem to integrate for a specific tolerance. Then we train the free parameters of the above RKN4(3) and RKN6(4) families to perform optimally. For that we form a neural network approach and minimize its objective function using a differential evolution optimization technique. Finally we observe that the produced pairs outperform standard pairs from the literature for Pleiades orbits and Kepler problem over a wide range of eccentricities and tolerances.