Intercomparison of Stratospheric Chemistry Models under Polar Vortex Conditions

Several stratospheric chemistry modules from box, 2-D or 3-D models, have been intercompared. The intercomparison was focused on the ozone loss and associated reactive species under the conditions found in the cold, wintertime Arctic and Antarctic vortices. Comparisons of both gas phase and heterogeneous chemistry modules show excellent agreement between the models under constrained conditions for photolysis and the microphysics of polar stratospheric clouds. While the mean integral ozone loss ranges from 4–80% for different 30–50 days long air parcel trajectories, the mean scatter of model results around these values is only about ±1.5%. In a case study, where the models employed their standard photolysis and microphysical schemes, the variation around the mean percentage ozone loss increases to about ±7%. This increased scatter of model results is mainly due to the different treatment of the PSC microphysics and heterogeneous chemistry in the models, whereby the most unrealistic assumptions about PSC processes consequently lead to the least representative ozone chemistry. Furthermore, for this case study the model results for the ozone mixing ratios at different altitudes were compared with a measured ozone profile to investigate the extent to which models reproduce the stratospheric ozone losses. It was found that mainly in the height range of strong ozone depletion all models underestimate the ozone loss by about a factor of two. This finding corroborates earlier studies and implies a general deficiency in our understanding of the stratospheric ozone loss chemistry rather than a specific problem related to a particular model simulation.     

Evaluating the Ability of CRCM5 to Simulate Mixed Precipitation

Precipitation episodes in the form of freezing rain and ice pellets represent natural hazards affecting eastern Canada during the cold season. These types of precipitation mainly occur in the St. Lawrence River valley and the Atlantic provinces of Canada. This study aims to evaluate the ability of the fifth-generation Canadian Regional Climate Model (CRCM5), using a 0.11° horizontal grid mesh, to hindcast mixed precipitation when driven by reanalyses produced by the European Centre for Medium-range Weather Forecasts (ERA-Interim) for a 35-year period. In general, the CRCM5 simulation slightly overestimates the occurrence of freezing rain, but the geographical distribution is well reproduced. The duration of freezing rain events and accompanying surface winds in the Montréal region are reproduced by CRCM5. A case study is performed for an especially catastrophic freezing-rain event in January 1998; the model succeeds in simulating the intensity and duration of the episode, as well as the propitious meteorological environment. Overall, the model is also able to reproduce the climatology and a specific event of freezing rain and ice pellets.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Long-term groundwater resource observatory for Southwestern Madagascar

Madagascar has one of the highest poverty rates in the world and consequently the long-term monitoring of groundwater resources is not a priority for the authorities. However, groundwater is often the only sustainable resource that has a satisfactory quality to supply the population. This is especially true in the south-west of the country, which is a semi-arid region and a global change hot spot (intense land use and climate changes). In response to the lack of data, the Groundwater Resource Observatory for Southwestern Madagascar (GROSoM) was established to monitor piezometry and meteorology over the longer term as part of a humanitarian response. The first site was setup in 2014 in a catchment located over a carbonate plateau; in 2018, a second site was installed in an alluvial setting within a crystalline basement catchment and a third site will be installed in 2020 to monitor groundwater dynamics in a coastal setting. The three sites, located between Toliara and Taolagnaro cities, are complementary and representative of various hydrogeological systems in Southwestern Madagascar. Each site includes a weather station and between 3 and 6 piezometric probes. The monitoring data indicate a strong inter-annual variability in precipitation, which induces a strong variability in aquifers recharge. One of the driest years in 2016 seems to be consistent with strong El Niño – Southern Oscillation (ENSO) effects observed at the global scale, while years with higher recharge appear to be related to cyclones such as Fundi in 2015 and Eketsang in 2019. Preliminary results of cross-disciplinary studies demonstrated a link between groundwater and health issues (i.e., admissions to basic health centres). This observatory aims to produce long-term data and has two objectives: (i) strengthening the early warning system for humanitarian crises in Madagascar; (ii) contributing to a better understanding of the effects of climate change on groundwater resources in this semi-arid region.     

A note on the feldspars in the granite xenoliths of the nyiragongo magma

The lavas of the Nyiragongo volcano in Eastern Zaire contain partially fused granite xenoliths. The relictic feldspars found in these xenoliths were studied by microprobe analysis and by X-ray diffraction methods. Some xenoliths represent originally two-feldspar granites, in others only alkali feldspars or those of an anorthoclase composition were detected. All feldspars are homogeneous without perthitic textures detectable under the microscope. In thebc-diagram of Stewart and Wright all feldspars plot on the analbite-high sanidine join. These feldspars have been perfectly disordered through heating in the melilite-nephelinite magma of the volcano.     

Field verification of a theoretical model to predict the dynamic response of a soft clay deposit

A 40-m thick clay deposit was subjected to sinusoidal excitations using a foundation block and an eccentric mass type vibrator. The response of the foundation block and the surrounding soil was measured using geophones inside the soil and on the surface. The phase shift between the excitation signal and the response signal, the accelerations of the foundation block and the particle velocities in the soil are compared with those obtained from a frequency-dependent numerical model based on the exact analytical solution for the boundary value problem of a rectangular foundation resting on a linear elastic halfspace.     

The influence of soil properties on the erodibility of Belgian loamy soils: A study based on rainfall simulation experiments

Twenty soils from the Leuven region were tested in the laboratory with a rainfall simulator. Their texture varied from loam to loamy sand. On the basis of the results obtained, they were classified as a function of the runoff and splash erodibility. For every soil, several properties were determined and tentatively used to explain the classifications based on the runoff and splash erodibility. Significant negative correlations were found between silt content, aggregate stability, C_5–10 index, water content at saturation, and cohesion on the one side and erodibility on the other; a positive correlation was found between sand content and erodibility.     

Strain accumulation in sand due to cyclic loading: drained triaxial tests

Our aim is the prediction of the accumulation of strain and/or stress under cyclic loading with many (thousands to millions) cycles and relatively small amplitudes. A high-cycle constitutive model is used for this purpose. Its formulas are based on numerous cyclic tests. This paper describes drained tests with triaxial compression and uniaxial stress cycles. The influence of the strain amplitude, the average stress, the density, the cyclic preloading history and the grain size distribution on the direction and the intensity of strain accumulation is discussed.     

Effects of 12 years' operation of a sewage treatment plant on trace metal occurrence within a Mediterranean commercial sponge (Spongia officinalis, Demospongiae)

The present field study uses Spongia officinalis for assessing trace metals occurrence in time and space within Mediterranean rocky communities. Nine sites were selected in the Marseille area for studying spatial trends in 12 metal concentrations. Long term changes in 8 metal concentrations were assessed at sites that had been sampled before and 12 years after the opening of a treatment plant. Spongia officinalis highly concentrated all the trace metal surveyed excepted Hg and Cd. The overall contamination level registered provided a classification of the study sites which is congruent with that given by other studies on pollutant accumulation in neighbouring sandy-bottoms or benthic assemblages. Among the metals studied, Fe, Pb, Cr are those that best highlighted a pollution gradient. In the present study, only Cd concentration did not vary in space. Except for Ni, all pollutant concentrations clearly decreased between 1984 and 1999. This very impressive decrease in heavy metal concentrations within the Marseille area represents an indisputable evidence of the improvement of the seawater quality resulting from 12 years' operation of the Marseille sewage plant. Moreover, the significant decrease also recorded in the reference population at Port-Cros might reflect an overall improvement in the seawater quality of the NW Mediterranean.