Rare Earth, Major and Trace Elements in the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.     

Seismic structure of the upper mantle beneath the western Philippine Sea

We investigate the seismic structure of the western Philippine Sea using two sets of seismological observations: ScS reverberations, which provide the layering framework for a regional upper mantle model, and observations of frequency-dependent phase delays for direct S waves, surface-reflected phases (sS, SS, sSS), and surface waves (R₁, G₁), which constrain the velocity and anisotropy structure within the layers. The combined data set, comprising 17 discontinuity amplitudes and layer travel times from the ScS-reverberation stack and more than 1000 frequency-dependent phase delays, was inverted for a path-averaged, radially anisotropic model. Mineralogical estimates of the bulk sound velocity and density are incorporated as complementary constraints. The final model, PHB3, is characterized by a 11.5-km thick crust, an anisotropic lid bounded by a sharp negative G discontinuity at 89 km, an anisotropic low-velocity layer extending to 166 km, a subjacent high-gradient region, and transition-zone discontinuities at depths of 408 km, 520 km and 664 km. The lid is slower than in a comparable model for the Tonga–Hawaii corridor (PA5), but also significantly thicker, requiring a compositional variation between the two regions. We explore the hypothesis that the thickness of the oceanic lid is controlled by the melting depth at the spreading centers during crust formation, and that the thicker crust and lid in the Philippine Sea results from deeper melting owing to a higher potential temperature and perhaps a higher water content in the upper mantle.     

Effect of Sliding Rate on the Activity of Acoustic Emission During Stable Sliding

--The mechanical and statistical characteristics of acoustic emission (AE) events during stable sliding are investigated through a laboratory experiment using a granite specimen with a pre-cut fault. Numerous AE events are found to be generated on the pre-cut fault, indicating that microscopically unstable fracture occurs during macroscopically stable sliding. The composite focal mechanism solution of AE events is determined from the first motion directions of P-waves. The determined mechanism is consistent with the double-couple one expected for the slip on the pre-cut fault. The source radii of large AE events are estimated to be about 10 mm from the widths of the first P-wave pulses. These indicate that the AE events are generated by shear fracture whose faulting area is a part of the pre-cut fault plane. The occurrence of AE events as a stochastic process approximately obeys the Poisson process, if the effect of mutually dependent events consti tuting clusters is corrected. The observed amplitude-frequency relation of AE events approximately follows a power law for a limited amplitude range. As the macroscopic sliding rate increases, the number of AE events per unit sliding distance decreases. This rate dependence of the AE activity is qualitatively consistent with the observation that the real area of contact between sliding surfaces decreases with an increase in the sliding rate as reported in the literature.     

Distribution of vertical crustal movement rates in the Tohoku district, Japan, predicted by least-squares collocation

Least-squares prediction using an empirically deduced local covariance function was performed to investigate the temporal change in the rates of vertical crustal movements in the Tohoku district, Japan. Levelling data covering an area of approximately 450 × 275 km² observed between 1966 and 1995 were used and the results shown in the form of contour maps. Firstly we derived a covariance function of the rates of vertical crustal movement with a Gaussian form function. We used this function to estimate the spatial distribution of the rates of vertical crustal movements. By the present method, a steady tilt of the Tohoku district to the east, toward the Japan Trench and an areal uplift in the southwestern part were well reproduced. Moreover, a significant temporal change in vertical movement rates is clearly seen. Received: 15 July 1996      

Subsurface thermal and hydrothermal characterization based on geothermal resources map, drill hole thermal gradients, Curie point depths and hypocenter distribution — Examples of Tohoku district, Japan

Subsurface thermal structure in Tohoku district are characterized by existing data such as geothermal resources maps, drill hole thermal gradients, Curie point depths and hypocenters distribution maps. The collected data are registered in a database system, then, compared in plan view, cross-section and bird's-eye pictures. The comparison indicates that subsurface temperatures extrapolated from drill hole thermal gradients are generally concordant to the Curie point depth, assumed to be 650 °C. Tohoku district is generally divided into 5 type areas; fore arc lowland, fore arc mountain country, Quaternary volcanic terrain, back arc lowland and back arc mountain country. The surface thermal manifestations in Quaternary volcanic terrain are mainly controlled by the magma chambers as heat sources, while, surface thermal features such as hot springs in non-volcanic areas are controlled by degrees of heat flows, and hydrothermal flows in permeable Cenozoic formations and along permeable fault zones.     

An emission pathway for stabilization at 6?Wm?2 radiative forcing

Representative Concentration Pathway 6.0 (RCP6) is a pathway that describes trends in long-term, global emissions of greenhouse gases (GHGs), short-lived species, and land-use/land-cover change leading to a stabilisation of radiative forcing at 6.0 Watts per square meter (Wm^?2) in the year 2100 without exceeding that value in prior years. Simulated with the Asia-Pacific Integrated Model (AIM), GHG emissions of RCP6 peak around 2060 and then decline through the rest of the century. The energy intensity improvement rates changes from 0.9% per year to 1.5% per year around 2060. Emissions are assumed to be reduced cost-effectively in any period through a global market for emissions permits. The exchange of CO₂ between the atmosphere and terrestrial ecosystem through photosynthesis and respiration are estimated with the ecosystem model. The regional emissions, except CO₂ and N₂O, are downscaled to facilitate transfer to climate models.     

Precipitation of authigenic uranium in suboxic continental margin sediments from the Okinawa Trough

Concentrations of U and Th isotopes in Okinawa Trough and East China Sea sediment cores were determined by isotope dilution inductively coupled plasma-mass spectrometry (ID-ICP-MS) to investigate the behavior of redox sensitive uranium in suboxic hemipelagic sediments and determine their significance in oceanic uranium balance. ²³⁸U concentrations and ²³⁸U/²³²Th activity ratios in the East China Sea sediments showed no remarkable variation with depth. However, ²³⁸U and ²³⁸U/²³²Th ratios in the Okinawa Trough sediments were low in the surface oxidizing layer but increased where the suboxic condition was encountered. The distribution profiles of ²³⁰Th and ²³²Th concentrations were relatively constant with depth in both the Okinawa Trough and East China Sea sediment cores. These results suggested that there has been post-depositional precipitation of authigenic uranium within the suboxic Okinawa Trough sediment column. The post-depositional precipitation rates of authigenic uranium were estimated to be 47 ± 5 to >62 ± 8 ng cm⁻² yr⁻¹; these rates were comparable to those previously reported for several anoxic sediments. A mechanism controlling precipitation of uranium may be the downward diffusion of uranium U(VI), reduction to U(IV) and finally precipitation onto the solid phase. The accumulation rate of uranium for the Okinawa Trough sediments was approximately eight times higher than the world average rate reported for suboxic sediments. This removal of uranium in the oceanic budget increases the importance of the suboxic sediment sink.     

Solar brightness distribution at 8.6 mm from interferometer observations

The radial brightness distribution of the quiet Sun at 8.6 mm is synthesized from observations using a sixteen element east-west interferometer in Nagoya. The observed brightness is flat from the disk center to 0.8R . A slight darkening appeared between 0.8R and the limb. No evidence of the bright ring near the limb is found. The radio radius at 8.6 mm is 1.015±0.005R . In addition there exists a coronal component just outside the radio limb.