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91.
D. Rickard B. Hatton D. M. Murphy I. B. Butler A. Oldroyd A. Hann 《Aquatic Geochemistry》2011,17(4-5):545-566
Plasmid DNA was incubated at 25°C with aqueous solutions of dissolved Fe(II), S(-II), and nanoparticulate FeS with a mackinawite structure, FeSm. At ??0.1 mM total dissolved Fe(II) and S(-II), an increase in the proportion of the relaxed plasmid DNA occurs, through scission of the DNA backbone. In solutions where FeSm was precipitated, nanoparticulate FeSm binds to the DNA molecules. In solutions with concentrations below the FeSm solubility product, nicking of supercoiled pDNA occurs. Plasmid DNA appears to be a sensitive proxy for radical reactions. The reactant is proposed to be a sulfur-based radical produced from the iron-catalyzed decomposition of bisulfide, in a manner analogous to the Fenton reaction. This is further supported by experiments that suggest that sulfide free radicals are produced during the photolysis of aqueous solutions of polysulfides. Supercoiling of DNA affects nearly all DNA?Cprotein transactions so the observation of relaxation of supercoiled forms through reaction with FeS solutions has direct implications to biochemistry. The results of this experimentation suggest that genotoxicity in FeS-rich systems is a further contributory factor to the limited survival of organisms in sulfidic environments. Mutations resulting from the interactions of organisms and mobile elements, such as plasmids, in sediments will also be affected in sulfide-rich environments. 相似文献
92.
Decentralization in access to and control of Bolivia's forest resources, coupled with a rising global demand for tropical hardwoods, raises important questions about whether increased trade and community forest management (CFM) initiatives can enable forms of market integration that have more favourable outcomes for rural communities. This paper assesses the prospects for such a transition through an examination of the relationships linking wood product market intermediaries (brokers and buyers) to rural suppliers and forest communities in Bolivia. The analysis centres on whether trust – conceptualized as a power‐laden sociospatial process driven by multiscalar factors – can evolve between buyers and suppliers such that more progressive (sustainable and mutually beneficial) partnerships devolop. Focusing on three types of buyer–supplier relationships in Bolivia – direct ties between wood brokers/buyers and suppliers, nongovernmental organization (NGO) mediated exchange relationships and Forest Stewardship Council (FSC) certification of suppliers – our findings show how trust building initiatives that focus on one scale may fail if factors at other scales create obstacles to collaboration, Given these relational constraints, CFM strategies in Bolivia currently face limitation on their viability as economic development strategies. 相似文献
93.
E. Shamir K. P. Georgakakos C. Spencer T. M. Modrick M. J. Murphy Jr. R. Jubach 《Natural Hazards》2013,67(2):459-482
The January 2010 earthquake that devastated Haiti left its population ever more vulnerable to rainfall-induced flash floods. A flash flood guidance system has been implemented to provide real-time information on the potential of small (~70 km2) basins for flash flooding throughout Haiti. This system has components for satellite rainfall ingest and adjustment on the basis of rain gauge information, dynamic soil water deficit estimation, ingest of operational mesoscale model quantitative precipitation forecasts, and estimation of the times of channel flow at bankfull. The result of the system integration is the estimation of the flash flood guidance (FFG) for a given basin and for a given duration. FFG is the amount of rain of a given duration over a small basin that causes minor flooding in the outlet of the basin. Amounts predicted or nowcasted that are higher than the FFG indicate basins with potential for flash flooding. In preparation for Hurricane Tomas’ landfall in early November 2010, the FFG system was used to generate 36-h forecasts of flash flood occurrence based on rainfall forecasts of the nested high-resolution North American Model of the National Centers for Environmental Prediction. Assessment of the forecast flood maps and forecast precipitation indicates the utility and value of the forecasts in understanding the spatial distribution of the expected flooding for mitigation and disaster management. It also highlights the need for explicit uncertainty characterization of forecast risk products due to large uncertainties in quantitative precipitation forecasts on hydrologic basin scales. 相似文献
94.
Daniel Pastor-Galán Gabriel Gutiérrez-Alonso J. Brendan Murphy Javier Fernández-Suárez Mandy Hofmann Ulf Linnemann 《Gondwana Research》2013,23(3):1089-1103
The Cantabrian Zone of NW Iberia preserves a voluminous, almost continuous, sedimentary sequence that ranges from Neoproterozoic to Early Permian in age. Its tectonic setting is controversial and recent hypotheses include (i) passive margin deposition along the northern margin of Gondwana or (ii) an active continental margin or (iii) a drifting ribbon continent. In this paper we present detrital zircon U–Pb laser ablation age data from 13 samples taken in detrital rocks from the Cantabrian Zone sequence ranging from Early Silurian to Early Permian in depositional age. The obtained results, together with previously published detrital zircon ages from Ediacaran–Ordovician strata, allow a comprehensive analysis of changing provenance through time. Collectively, these data indicate that this portion of Iberia was part of the passive margin of Gondwana at least from Ordovician to Late Devonian times. Zircon populations in all samples show strong similarities with the Sahara Craton and with zircons found in Libya, suggesting that NW Iberia occupied a paleoposition close to those regions of present-day northern Africa during this time interval. Changes in provenance in the Late Devonian are attributed to the onset of the collision between Gondwana and Laurussia.Additionally, the Middle Carboniferous to Permian samples record populations consistent with the recycling of older sedimentary sequences and exhumation of the igneous rocks formed before and during the Variscan orogeny. Late-Devonian to Permian samples yield zircon populations that reflect topographic changes produced during the Variscan orogeny and development of the lithospheric scale oroclinal buckling. 相似文献
95.
The supercontinent cycle,by which Earth history is seen as having been punctuated by the episodic assembly and breakup of supercontinents,has influenced the rock record more than any other geologic phenomena,and its recognition is arguably the most important advance in Earth Science since plate tectonics.It documents fundamental aspects of the planet’s interior dynamics and has charted the course of Earth’s tectonic,climatic and biogeochemical evolution for billions of years.But while the widespread realization of the importance of supercontinents in Earth history is a relatively recent development,the supercontinent cycle was first proposed thirty years ago and episodicity in tectonic processes was recognized long before plate tectonics provided a potential explanation for its occurrence.With interest in the supercontinent cycle gaining momentum and the literature expanding rapidly,it is instructive to recall the historical context from which the concept developed.Here we examine the supercontinent cycle from this perspective by tracing its development from the early recognition of long-term episodicity in tectonic processes,through the identification of tectonic cycles following the advent of plate tectonics,to the first realization that these phenomena were the manifestation of episodic supercontinent assembly and breakup. 相似文献
96.
97.
98.
Janet M. Fischer Tara Reed-Andersen Jennifer L. Klug Alice G. Chalmers 《Estuaries and Coasts》2000,23(4):565-571
Geomorphology may be an important predictor of vegetation pattern in systems where suceptibility to disturbance is unevenly
distributed across the landscape. Salt marsh communities exhibit spatial pattern in vegetation at a variety of spatial scales.
In coastal Georgia, the low marsh is a virtual monoculture ofSpartina alterniflora interspersed with patches of species that are more typical of the high marsh. These localized disturbances are most likely
created by wrack mats, mats of dead vegetation which can compact and smother underlying vegetation creating bare patches for
colonization by high marsh species. We investigated the spatial pattern of disturbed patches along a 2 km section of Dean
Creek, a tidal creek at the southwestern end of Sapelo Island, Georgia, U.S. We used a discriminant model to explore the relationship
between tidal creek morphology (e.g., the presence of drainage channels and creek bends) and the spatial distribution of disturbed
patches. The model predicted vegetation pattern along the creek with relatively high accuracy (>70%). Areas where water movement
is slowed or multidirectional (e.g., along creek bends and near drainage channels) were most susceptible to disturbance. Our
findings suggest an important functional linkage between geomorphology and vegetation pattern in salt marsh communities. 相似文献
99.
Summary. The seismic structure has been measured to a depth of about 3 km along a 30 km seismic profile in east central Ireland. This profile is unusual in that it is the S -wave velocity—depth structure that has been measured to a degree of precision more normally associated with P -wave results. One reason for this is that the sources used were quarry blasts which generated strong S -waves and short-period surface waves but rather weak P -waves.
The results show a layer of Carboniferous limestone with shear velocity 2.65 km−1 s overlying a layer with a velocity of 3.06 km s−1 . This second layer was interpreted as Lower Palaeozoic strata (Silurian/Ordovician) since this velocity was evident in an inlier seen at the surface at the northern end of the line. A third refraction horizon, shear velocity 3.45 km s−1 and displaying a basinal structure, was also recognized. This may be Cambrian or Precambrian basement. 相似文献
The results show a layer of Carboniferous limestone with shear velocity 2.65 km
100.
Jingyi Cong Gang Hu Tara N. Jonell Zhongpeng Yuan Xianghuai Kong Yong Zhang Yonghong Wang 《中国海洋大学学报(英文版)》2020,19(4):790-800
Large amounts of sediments originating from the Changjiang(Yangtze) River are deposited in the subaqueous delta and in the adjacent muddy area off the mouth and on the inner shelf of the East China Sea. The terrestrial sediments deposited in these areas not only contain information about the composition and environment of the source area, but they also record changes in anthropogenic activities. A sediment piston core(CJ0702) was extracted from the Changjiang subaqueous depocenter(31.00°N, 122.67°E) in a water depth of 22.0 m. The core was subsampled at 1 – 2 cm intervals and analyzed for grain size, clay mineralogy, and major element geochemistry. Results indicate a relatively high sediment accumulation rate of approximately 3.11 cm yr~(-1). These parameters exhibited only minor cyclical fluctuations in the core, which resulted from many factors. During the past 120 years, the Changjiang River-derived sediment is the primary source of sediment in the offshore mud area without evidence for the Yellow River-derived sediment increasing. After the trunk stream shifted from the North Branch to South Branch, the variations of proxies are controlled by the periodic fluctuation possibly linked to El Ni?o-Southern Oscillation(ENSO) and the Pacific Decadal Oscillation(PDO). In addition, anthropogenic heavy metal concentrations can be divided into three stages, which coincide well with economic development and environmental protection policies. 相似文献