In search of a hidden long-term isolated sub-chondritic Nd/Nd reservoir in the deep mantle: Implications for the Nd isotope systematics of the Earth

Here we search for evidence of the existence of a sub-chondritic ¹⁴²Nd/¹⁴⁴Nd reservoir that balances the Nd isotope chemistry of the Earth relative to chondrites. If present, it may reside in the source region of deeply sourced mantle plume material. We suggest that lavas from Hawai’i with coupled elevations in ¹⁸⁶Os/¹⁸⁸Os and ¹⁸⁷Os/¹⁸⁸Os, from Iceland that represent mixing of upper mantle and lower mantle components, and from Gough with sub-chondritic ¹⁴³Nd/¹⁴⁴Nd and high ²⁰⁷Pb/²⁰⁶Pb, are favorable samples that could reflect mantle sources that have interacted with an Early-Enriched Reservoir (EER) with sub-chondritic ¹⁴²Nd/¹⁴⁴Nd.High-precision Nd isotope analyses of basalts from Hawai’i, Iceland and Gough demonstrate no discernable ¹⁴²Nd/¹⁴⁴Nd deviation from terrestrial standards. These data are consistent with previous high-precision Nd isotope analysis of recent mantle-derived samples and demonstrate that no mantle-derived material to date provides evidence for the existence of an EER in the mantle.We then evaluate mass balance in the Earth with respect to both ¹⁴²Nd/¹⁴⁴Nd and ¹⁴³Nd/¹⁴⁴Nd. The Nd isotope systematics of EERs are modeled for different sizes and timing of formation relative to ε¹⁴³Nd estimates of the reservoirs in the μ¹⁴²Nd = 0 Earth, where μ¹⁴²Nd is ((measured ¹⁴²Nd/¹⁴⁴Nd/terrestrial standard ¹⁴²Nd/¹⁴⁴Nd)−1 * 10⁻⁶) and the μ¹⁴²Nd = 0 Earth is the proportion of the silicate Earth with ¹⁴²Nd/¹⁴⁴Nd indistinguishable from the terrestrial standard. The models indicate that it is not possible to balance the Earth with respect to both ¹⁴²Nd/¹⁴⁴Nd and ¹⁴³Nd/¹⁴⁴Nd unless the μ¹⁴²Nd = 0 Earth has a ε¹⁴³Nd within error of the present-day Depleted Mid-ocean ridge basalt Mantle source (DMM). The 4567 Myr age ¹⁴²Nd-¹⁴³Nd isochron for the Earth intersects μ¹⁴²Nd = 0 at ε¹⁴³Nd of +8 ± 2 providing a minimum ε¹⁴³Nd for the μ¹⁴²Nd = 0 Earth. The high ε¹⁴³Nd of the μ¹⁴²Nd = 0 Earth is confirmed by the Nd isotope systematics of Archean mantle-derived rocks that consistently have positive ε¹⁴³Nd.If the EER formed early after solar system formation (0-70 Ma) continental crust and DMM can be complementary reservoirs with respect to Nd isotopes, with no requirement for significant additional reservoirs. If the EER formed after 70 Ma then the μ¹⁴²Nd = 0 Earth must have a bulk ε¹⁴³Nd more radiogenic than DMM and additional high ε¹⁴³Nd material is required to balance the Nd isotope systematics of the Earth.     

Geochemistry and Sm–Nd isotopic systematics of Ediacaran–Ordovician,sedimentary and bimodal igneous rocks in the western Acatlán Complex,southern Mexico: Evidence for rifting on the southern margin of the Rheic Ocean

Ordovician igneous rocks in the western Acatlán Complex (Olinalá area) of southern Mexico include a bimodal igneous suite that intrudes quartzites and gneisses of the Zacango Unit, and all these rocks were polydeformed and metamorphosed in the amphibolite facies during the Devono-Carboniferous. The Ordovician igneous rocks consist of the penecontemporaneous amphibolites, megacrystic granitoids and leucogranite, the latter dated at ca. 464 Ma. Geochemical and Sm–Nd data indicate that the amphibolites have a differentiated tholeiitic signature, and that its mafic protoliths formed in an extensional setting transitional between within-plate and ocean floor. The amphibolites are variably contaminated by a Mesoproterozoic crustal source, inferred to be the Oaxacan basement exposed in the adjacent terrane. The most primitive samples have εNdt (t = 465 Ma) values significantly below that of the contemporary depleted mantle and were probably derived from the sub-continental lithospheric mantle. The megacrystic granites were most probably derived by partial melting of an arc crustal source (similar to the Oaxacan Complex) and triggered by the ascent of mafic magma from the lithospheric mantle. Sm–Nd isotopic signatures suggest that metasedimentary rocks from Zacango Unit were derived from adjacent Oaxacan Complex. Trace elements relationships (e.g. La/Th vs. Hf) and REE patterns suggest provenance in felsic-intermediate igneous rocks with a calc-alkaline signature. The Ordovician bimodal magmatism is inferred to have resulted from rifting on the southern flank of the Rheic Ocean and is an expression of a major rifting event that occurred along much of the northern Gondwanan margin in the Ordovician.     

Analytical and numerical investigation of multicomponent multiphase WAG displacements

In this paper the ability of analytical solutions for four-component three-phase flow to predict displacement efficiency in water alternating gas (WAG) injection processes is studied. First analytical solutions for Riemann problems with injection compositions that are the average water and gas mixture for various WAG injection schemes are presented. These solutions are compared to numerical calculations with variable slug sizes and used to explore the effect of slug size, injecting water vs gas first, and the average injection composition on displacement efficiency in compositional WAG schemes. The example model is partially miscible WAG injection of water and CO₂ into an oil reservoir containing C₁₀ and CH₄ with and without a mobile aqueous phase present initially. The trailing end of the water and gas profiles are sensitive to whether water or gas is injected first, but the magnitude of the oil bank and the breakthrough time of the injected fluids are accurately predicted by the analytical solutions, even for displacements where large water and gas slugs are injected. Fluctuations in the saturation and composition profiles resulting from the alternating injection sequence in the WAG simulations appear as super-imposed on top of the sequence of rarefaction and shock waves predicted by analytical solutions. As the number of slugs increases, the effect of alternating boundary conditions diminishes and the displacements predicted by numerical calculations converge to the analytical solutions.     

Refashioning place and new-build gentrification: The material and symbolic redevelopment of Three Kings,Auckland

Auckland's post-suburban landscape is associated with new mixed-use apartment developments. When located in former industrial sites, these emergent residential and retail spaces constitute new-build gentrification and carry the potential to rupture existing people/place dynamics. This article examines material and socio-cultural processes associated with the redevelopment of an industrial quarry in Three Kings, Auckland. It is argued that the redevelopment constitutes a physical refashioning of a former industrial space located within a traditional working-class community. The development involves a remaking of the material and socio-cultural fabric of the neighbourhood and aligns with new-build gentrification practices.     

Transient climate changes in a perturbed parameter ensemble of emissions-driven earth system model simulations

We describe results from a 57-member ensemble of transient climate change simulations, featuring simultaneous perturbations to 54 parameters in the atmosphere, ocean, sulphur cycle and terrestrial ecosystem components of an earth system model (ESM). These emissions-driven simulations are compared against the CMIP3 multi-model ensemble of physical climate system models, used extensively to inform previous assessments of regional climate change, and also against emissions-driven simulations from ESMs contributed to the CMIP5 archive. Members of our earth system perturbed parameter ensemble (ESPPE) are competitive with CMIP3 and CMIP5 models in their simulations of historical climate. In particular, they perform reasonably well in comparison with HadGEM2-ES, a more sophisticated and expensive earth system model contributed to CMIP5. The ESPPE therefore provides a computationally cost-effective tool to explore interactions between earth system processes. In response to a non-intervention emissions scenario, the ESPPE simulates distributions of future regional temperature change characterised by wide ranges, and warm shifts, compared to those of CMIP3 models. These differences partly reflect the uncertain influence of global carbon cycle feedbacks in the ESPPE. In addition, the regional effects of interactions between different earth system feedbacks, particularly involving physical and ecosystem processes, shift and widen the ESPPE spread in normalised patterns of surface temperature and precipitation change in many regions. Significant differences from CMIP3 also arise from the use of parametric perturbations (rather than a multimodel ensemble) to represent model uncertainties, and this is also the case when ESPPE results are compared against parallel emissions-driven simulations from CMIP5 ESMs. When driven by an aggressive mitigation scenario, the ESPPE and HadGEM2-ES reveal significant but uncertain impacts in limiting temperature increases during the second half of the twenty-first century. Emissions-driven simulations create scope for development of errors in properties that were previously prescribed in coupled ocean–atmosphere models, such as historical CO₂ concentrations and vegetation distributions. In this context, historical intra-ensemble variations in the airborne fraction of CO₂ emissions, and in summer soil moisture in northern hemisphere continental regions, are shown to be potentially useful constraints, subject to uncertainties in the relevant observations. Our results suggest that future climate-related risks can be assessed more comprehensively by updating projection methodologies to support formal combination of emissions-driven perturbed parameter and multi-model earth system model simulations with suitable observational constraints. This would provide scenarios underpinned by a more complete representation of the chain of uncertainties from anthropogenic emissions to future climate outcomes.     

Larval Brachyuran Crab Timing and Distribution in Relation to Water Properties and Flow in a High-Latitude Estuary

Crab larval dispersal and, thus, adult population size can be influenced by oceanographic conditions, especially in highly dynamic and variable environments such as high-latitude estuaries. This study's primary goal was to understand larval timing, abundance, and distribution in relation to oceanographic effects between the more estuarine inner and more oceanic outer part of the subarctic estuary of Kachemak Bay (south-central Alaska, USA). Temperature and salinity measurements and plankton tows were taken along the boundary between the two bay parts from 31 March to 28 October 2008 on spring and neap tides. Summer water flow and stratification in Kachemak Bay were chiefly buoyancy driven, and predominant flow patterns were not affected by the large tidal range in the region. Larvae of seven brachyuran species were found over the sampling period, with seasonally different peak abundances. Larval spatial distribution patterns, presence of most larval stages for each species, and their seasonal timing and persistence within the water column suggest that most species are locally transported within or close to Kachemak Bay. The larval assemblage was correlated with seasonal changes in water temperature, and peak abundances of some species coincided with spring tides and/or frontal systems between the in- and outflow regions of the bay. The strong influence of freshwater on the local circulation pattern in the summer indicates that larval transport will likely be strongly affected by future changes in glacial melt and precipitation.     

Coherence of river and ocean conditions along the US West Coast during storms

The majority of water and sediment discharge from the small, mountainous watersheds of the US West Coast occurs during and immediately following winter storms. The physical conditions (waves, currents, and winds) within and acting upon the proximal coastal ocean during these winter storms strongly influence dispersal patterns. We examined this river–ocean temporal coherence for four coastal river–shelf systems of the US West Coast (Umpqua, Eel, Salinas, and Santa Clara) to evaluate whether specific ocean conditions occur during floods that may influence coastal dispersal of sediment. Eleven years of corresponding river discharge, wind, and wave data were obtained for each river–shelf system from USGS and NOAA historical records, and each record was evaluated for seasonal and event-based patterns. Because near-bed shear stresses due to waves influence sediment resuspension and transport, we used spectral wave data to compute and evaluate wave-generated bottom-orbital velocities. The highest values of wave energy and discharge for all four systems were consistently observed between October 15 and March 15, and there were strong latitudinal patterns observed in these data with lower discharge and wave energies in the southernmost systems. During floods we observed patterns of river–ocean coherence that differed from the overall seasonal patterns. For example, downwelling winds generally prevailed during floods in the northern two systems (Umpqua and Eel), whereas winds in the southern systems (Salinas and Santa Clara) were generally downwelling before peak discharge and upwelling after peak discharge. Winds not associated with floods were generally upwelling on all four river–shelf systems. Although there are seasonal variations in river–ocean coherence, waves generally led floods in the three northern systems, while they lagged floods in the Santa Clara. Combined, these observations suggest that there are consistent river–ocean coherence patterns along the US West Coast during winter storms and that these patterns vary substantially with latitude. These results should assist with future evaluations of flood plume formation and sediment fate along this coast.     

Modelling the effects of land‐use change on water and salt delivery from a catchment affected by dryland salinity in south‐east Australia

A comprehensive framework for the assessment of water and salt balance for large catchments affected by dryland salinity is applied to the Boorowa River catchment (1550 km²), located in south‐eastern Australia. The framework comprised two models, each focusing on a different aspect and operating on a different scale. A quasi‐physical semi‐distributed model CATSALT was used to estimate runoff and salt fluxes from different source areas within the catchment. The effects of land use, climate, topography, soils and geology are included. A groundwater model FLOWTUBE was used to estimate the long‐term effects of land‐use change on groundwater discharge. Unlike conventional salinity studies that focus on groundwater alone, this study makes use of a new approach to explore surface and groundwater interactions with salt stores and the stream. Land‐use change scenarios based on increased perennial pasture and tree‐cover content of the vegetation, aimed at high leakage and saline discharge areas, are investigated. Likely downstream impacts of the reduction in flow and salt export are estimated. The water balance model was able to simulate both the daily observed stream flow and salt load at the catchment outlet for high and low flow conditions satisfactorily. Mean leakage rate of about 23·2 mm year^?1 under current land use for the Boorowa catchment was estimated. The corresponding mean runoff and salt export from the catchment were 89 382 ML year^?1 and 38 938 t year^?1, respectively. Investigation of various land‐use change scenarios indicates that changing annual pastures and cropping areas to perennial pastures is not likely to result in substantial improvement of water quality in the Boorowa River. A land‐use change of about 20% tree‐cover, specifically targeting high recharge and the saline discharge areas, would be needed to decrease stream salinity by 150 µS cm^?1 from its current level. Stream salinity reductions of about 20 µS cm^?1 in the main Lachlan River downstream of the confluence of the Boorowa River is predicted. The FLOWTUBE modelling within the Boorowa River catchment indicated that discharge areas under increased recharge conditions could re‐equilibrate in around 20 years for the catchment, and around 15 years for individual hillslopes. Copyright © 2004 John Wiley & Sons, Ltd.     

RHESSI Observation of Atmospheric Gamma Rays from Impact of Solar Energetic Particles on 21 April 2002

The RHESSI high-resolution spectrometer detected γ-ray lines and continuum emitted by the Earth's atmosphere during impact of solar energetic particles in the south polar region from 16:00–17:00 UT on 21 April 2002. The particle intensity at the time of the observation was a factor of 10–100 weaker than previous events when gamma-rays were detected by other instruments. This is the first high-resolution observation of atmospheric gamma-ray lines produced by solar energetic particles. De-excitation lines were resolved that, in part, come from ¹⁴N at 728, 1635, 2313, 3890, and 5106 keV, and the ¹²C spallation product at ∼ 4439 keV. Other unresolved lines were also detected. We provide best-fit line energies and widths and compare these with moderate resolution measurements by SMM of lines from an SEP event and with high-resolution measurements made by HEAO 3 of lines excited by cosmic rays. We use line ratios to estimate the spectrum of solar energetic particles that impacted the atmosphere. The 21 April spectrum was significantly harder than that measured by SMM during the 20 October 1989 shock event; it is comparable to that measured by Yohkoh on 15 July 2000. This is consistent with measurements of 10–50 MeV protons made in space at the time of the γ-ray observations.     

Further constraints on variation of the fine-structure constant from alkali-doublet QSO absorption lines

Comparison of quasar (QSO) absorption-line spectra with laboratory spectra provides a precise probe for variability of the fine-structure constant, α , over cosmological time-scales. We constrain variation in α in 21 Keck/HIRES Si  iv absorption systems using the alkali-doublet (AD) method in which changes in α are related to changes in the doublet spacing. The precision obtained with the AD method has been increased by a factor of 3:     . We also analyse potential systematic errors in this result. Finally, we compare the AD method with the many-multiplet method, which has achieved an order of magnitude greater precision, and we discuss the future of the AD method.