南秦岭横丹浊积岩系——晚古生代发育于扬子板块被动陆缘上的弧前盆地充填物

南秦岭横丹浊积岩系是一套巨厚的浊流沉积,以向南或南东倾的单斜构造产出。由下而上,该沉积层序包括深水盆地、深水浊积扇和斜坡水道3个相序。相应地,沉积物粒度变粗,厚度变大,火山质组分含量增加,凝灰层大量发育,表明横丹浊积岩系为活动型浊积岩;其古水流方向为NNW—NNE向,物源区为南侧的碧口火山岩系。另外,横丹浊积岩系内还见石英岩、重结晶大理岩成分的砾石,说明其物源还包括被动陆缘环境的沉积物。相序、组构、沉积特征和物源区综合分析表明,横丹浊积岩系为弧前盆地充填物。构筑这一弧前盆地的动力学机制是洋壳板块向南俯冲于扬子板块被动陆缘之下,时代可能晚于中晚泥盆世。     

南海西部围区中特提斯东延通道问题

通过对南海西部围区中生代岩相古地理资料的收集整理和分析,编制了该区T_2,T_3~1,T_3~2,T_3~3,J_1-J_2,J_3-K_1共6个时段的岩相古地理简图,根据其中生代海相地层的时空分布和岩相特征,讨论了尚存争议的中特提斯进入南海的通道问题。实际资料表明,黑水河盆地在三叠纪受印支运动影响完成了从海到陆的过程,之后不再出现海相沉积,中特提斯不可能从红河裂谷带进入南海。在新加坡所见的晚三叠世至早侏罗世浅海至陆相沉积代表古特提斯的残余海,到中侏罗世完全消失。早侏罗世时期在印支半岛南部出现的近南北走向的海湾可能经过泰国湾与当时的滇缅海相通;但是这个海湾浅而短暂,滇缅海能否从这里进入南海值得怀疑,更不可能是中特提斯的通道。在南海西部围区,迄今已证实的中生代洋壳碎片(蛇绿岩套)和深海沉积仅见于南部Woyla—Maratus—Lupar一线及其附近。这套延伸2000余km,从洋壳、深海到浅海岩相齐全的岩石所代表的晚侏罗世至早白垩纪世大洋应是中特提斯洋的一部分。中特提斯东延而最可能是走南路,即从班公一怒江带南下之后,经Woyla线穿过苏门答腊岛,绕加里曼丹岛南缘到Maratus线,向北再经沙巴到Lupar线,在沙捞越北部或纳土纳岛附近进入南海。     

Geochemical distribution and removal of As,Fe, Mn and Al in a surface water system affected by acid mine drainage at a coalfield in Southwestern China

The chemical characteristics, formation and natural attenuation of pollutants in the coal acid mine drainage (AMD) at Xingren coalfield, Southwest China, are discussed in this paper based on the results of a geochemical investigation as well as geological and hydrogeological background information. The chemical composition of the AMD is controlled by the dissolution of sulfide minerals in the coal seam, the initial composition of the groundwater and the water–rock interaction. The AMD is characterized by high sulfate concentrations, high levels of dissolved metals (Fe, Al, Mn, etc.) and low pH values. Ca²⁺ and SO₄ ²⁻ are the dominant cation and anion in the AMD, respectively, while Ca²⁺ and HCO₃ ⁻ are present at significant levels in background water and surface water after the drainage leaves the mine site. The pH and alkalinity increase asymptotically with the distance along the flow path, while concentrations of sulfate, ferrous iron, aluminum and manganese are typically controlled by the deposition of secondary minerals. Low concentrations of As and other pollutants in the surface waters of the Xingren coalfield could be due to relatively low quantities being released from coal seams, to adsorption and coprecipitation on secondary minerals in stream sediments, and to dilution by unpolluted surface recharge. Although As is not the most serious water quality problem in the Xingren region at present, it is still a potential environmental problem. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

三峡库区消落区土壤磷释放的环境影响因子

以三峡库区消落区万州段为试验基地,选取释磷能力较强的紫色冲积土,根据三峡水库消落带的"干湿交替"空间和时间特征,进行万州断面土壤磷释放的影响因子的实验室模拟试验和万州江面淹没的对照试验。研究发现,随着淹水时间的变化,各种形态的磷在前5~10d各形态磷变化有相当的差异,随后变化趋势趋于稳定。TP有降低的趋势,土壤磷有一定的释放。野外研究表明Olsen-P在淹水10周左右到达最大值,以后缓慢降低。淹水时土壤Olsen-P增加,干燥后降低。多次淹水时每次淹水后土壤的有效磷水平都略有增加,落干后相较上次落干后有效磷水平降低,最后一次淹水后相较与初始时Olsen-P水平低16.7%。随着淹水深度增加,土壤的Olsen-P水平在淹水时由淹水前20.53mg/kg提高到43.23mg/kg,增加110.6%。当上覆水磷浓度较低时(<2mg/L),磷吸附到达平衡的时间较短,约需要6周。当上覆水磷浓度较高(>2mg/L)时,磷吸附到达平衡的时间较长。微生物活动对淹水土壤的磷释放有一定影响,有微生物时磷的释放高于无微生物者0.048mg/L。种植植物的土壤在淹水后Olsen-P含量大于土壤直接淹没时的释放量,种植狗牙根(Cynodondactylon)和野地瓜藤(Ficustikoua)的土壤中Olsen-P分别较未种植物土壤释放量高出21.5%和12.7%。     

全球温度变化的热力学平衡和最新发现

本文提出了一种新的研究全球气候温度变化的思路。为发现全球气候变化的宏观规律,把生物圈系统作为一个整体的物质进行研究,从而把纷繁复杂的全球气候温度变化问题归纳成经典物理学的热量与温度变化问题。给出了广义生物圈的热平衡测量Q值和温度变化的热力学公式,并在实际数据的基础上通过计算发现人类使用矿物燃料和核能所排放的热量理论上可使全球海平面每年升高35 mm或者可使大气对流层温度每年升高011 ℃。该发现表明:能源热量因素已成为影响全球温度变化的重要因素。     

Levels, seasonal variations, and health risks assessment of ambient air pollutants in the residential areas

People living in the urban area and the surrounding suburban area have disparities in exposure and health risks due to different levels of ambient air pollutants. The main objective of this study is to investigate the concentrations, seasonal variations, and related health risks of ambient air pollutants (PM₁₀, NO₂, and SO₂) in urban and suburban areas of Ningbo, China. The results showed that the average PM₁₀, NO₂, and SO₂ concentrations in the urban area were 85.2, 49.3, and 37.4 μg/m³, which were 1.13, 1.25, and 1.41 times the values of the suburban area during the period of March 2009 to February 2010. For the potential health risk analysis, the residents have been divided into four age categories namely, infants, children (1 year), children (8–10 years), and adults. The analysis took into account age-specific breathing rates, body weights for different age categories. The results showed that the potential health risks to respiratory disease for all age categories living in urban area were higher than those in suburban area.     

论东秦岭秋树湾铜钼矿区扩大找矿的有利因素

作为东秦岭铜钼矿带上重要的铜钼矿区,秋树湾及其外围的找矿工作一直未取得重大突破,因此,明确秋树湾岩体形态及位置是扩大找矿的关键所在。本文通过分析成矿母岩、蚀变及矿化分带,结合遥感、地球物理探测技术,总结出研究区矿化蚀变分带模型,并利用钻孔验证,在秋树湾矿区先期取得了找矿突破。在理论和实践上指出:秋树湾斑岩体为本区的成矿母岩;埋深在1000m以下仍存在花岗斑岩体,深部斑岩体是重要的找矿方向;近南北向断裂为岩浆沿断裂从东向北西倾入提供了通道,岩体具有西浅东深的特点。     

The generation kinetics of natural gases in the Kela-2 gas field from the Kuqa Depression, Tarim Basin, northwestern China

The Kela-2 gas field, found in the Kuqa Depression of the Tarim Basin, northwestern China, is a large-sized dry gas field (C1 /C1-5 =0.992 0.999) and characterized by ultra-high pressure (pressure factor up to 2.0 2.2). The pyrolysis experiment was carried out under isothermal gold-tube closed system, with samples collected from the Jurassic coal, Jurassic mudstone and Triassic mudstone in the Kuqa Depression. The result of gas yield showed that the Middle and Lower Jurassic source rocks have higher gas generation potential than the Triassic source rocks. The kinetic modeling of gas generation and methane carbon isotope fractionation suggested that the Kela-2 gases belong to the products of high-over mature stages and were mainly derived from the Middle and Lower Jurassic coal-bearing strata. The Triassic source rocks made a minor contribution to the Kela-2 gases. The Kela-2 gases chiefly generated from coal-bearing source rocks with R o values from 1.3% to 2.5%, and thus primarily accumulated after 5 Ma.     

基于节理网络有限元的柱状节理岩体等效变形模量结构效应研究

因其特殊的地质成因,柱状节理成为一种具有强烈非连续性及各向异性的特殊岩体结构。以白鹤滩水电工程设计、建设中所遇到的柱状节理玄武岩体为背景,针对柱状节理岩体的等效变形模量问题,在探讨了其结构效应表征参数的基础上,利用节理网络有限元为工具,研究各结构效应表征参数对柱状节理岩体等效变形模量的影响。研究结果表明：在柱轴线横向平面上,对于柱体不规则程度,当柱体完全不规则相对于完全规则情况,等效模量提高大约10%左右;在其他条件不变情况下,当柱体平均边长从0.1 m增加至0.5 m时,等效模量从5.36 GPa增加至23.4 GPa;对不同加载方向的研究结果表明,柱状节理在柱轴横向平面上可以视作各向同性;当节理刚度线性递增时,相应的岩体等效模量也基本符合线性递增的规律。在平行柱体轴线平面,节理组2间距越大,柱状节理岩体的等效变形模量越大;随着错距比的增加,柱状节理岩体的等效变形模量呈现先增加后减少的趋势,当错距比为50%时,节理岩体的等效变形模量取最大值;对于节理刚度的影响,与柱轴横向平面类似的,随柱体轴线平面上节理刚度的线性增加,相应的岩体模量也基本符合线性递增的规律。该研究成果与已有的现场研究成果及三维数值模型成果相比,吻合良好。说明了文中提供的研究结论具有较好的可信度及参考价值。     

Nucleation and crystallization of otavite, witherite, calcite, strontianite, hydrozincite, and hydrocerussite by CO2 membrane diffusion technique

Otavite, witherite, calcite, strontianite, hydrozincite and hydrocerussite nucleation was induced by CO₂ diffusion through a polyethylene membrane into a metal bearing solution. Nucleation and ongoing precipitation was followed at 25 ± 1 °C by the chemical evolution of the solution and the consumption of sodium hydroxide (pH-stat conditions). X-ray diffraction patterns as well as FT-infrared and Raman spectra confirmed the formation of well crystallized solids, except for less crystalline hydrozincite. In several experiments simonkolleite and laurionite precipitated concurrently with hydrozincite and hydrocerussite. The carbonate end-member minerals, smithsonite and cerussite, however were not formed. Carbonate minerals crystallized as spherical aggregates of thin layered otavite, spherical orientated witherite needles, rhombohedral calcite, pseudo-hexagonal strontianite laths, fibrous lumps of hydrozincite and planar hexagonal hydrocerussite crystals. Crystal and aggregate sizes range between 1 and 100 μm. Nucleation occurred at well defined reaction times and distinct critical supersaturation indices (SI_crit). The time for nucleation at constant pH decreased as the initial metal concentration increased for a given solid. The SI_crit values decreased in the order of hydrocerussite (3.2), otavite (2.5), strontianite (1.6), witherite (0.9) and calcite (0.7).