Studying air pollution with kitt peak solar flux atlas — analysis method and results of observation

For the measurement of atmospheric NO2 vertical column density (VCD), Kitt Peak Solar Flux Atlas can be substituted as an extraterrestrial solar radiation. Compared with differential analysis method, the Taylor expansion of integrated transfer equation underestimates the VCD. This underestimation is as large as 35% when the amount of NO2 is 1 × 1017 cm－2 and observation is conducted with an air mass factor of 10. Even when the VCD is 2 × 1016 cm－2 and the air mass factor is 4, the relative error of the retrieved VCD is still no less than 3%. If the observation is restricted under the small air mass factor condition (≤4), with Kitt Peak Solar spectrum as an extraterrestrial solar radiation, only an atmospheric layer of 2 km thick from ground can be studied, which will make the absorption too weak to be detected by normal instruments.The VCD in winter Tokyo area was observed and analyzed by differential method, which shows a good precision even when the absorption is as low as 3%. The largest average VCD was about 1.3 × 1017 cm－2, and the lowest was about 1.3 × 1016 cm－2. The trend of its variation was almost the same as the ground level observation by Saltzman reagent method.     

Surface mass balance on Glacier No. 31 in the Suntar–Khayata Range,eastern Siberia,from 1951 to 2014

This study presents a 64-year(1951–2014) reconstruction of the surface mass balance of Glacier No. 31, located in the Suntar-Khayata Range of the eastern Siberia, where the ablation zone is characterized by the extensive dark ice surface. We use a temperature index-based glacier mass-balance model, which computes all major components of glacier mass budget and is forced by daily air temperature and precipitation from a nearby meteorological station. The glacier shows a mean annual mass balance of –0.35 m w.e.a~(–1) during the past 64 years, with an acceleration of –0.50 m w.e. a~(–1) during the recent years. A cumulative mass loss of the glacier is ~22.3 m w.e. over the study period, about 56% of which is observed during 1991–2014. In addition to the contribution of temperature rise and precipitation decrease to recent mass loss of the glacier, an experimental analysis, in which the cleanand dark ice surfaces are respectively assumed to cover the entire ablation zone, indicates that dark ice surface, caused by insoluble impurities consisting of mineral dusts, cryoconite granules, and ice algae, plays a crucial role in the changing mass balance through enhancing melt rates in the ablation zone of the glacier.     

Three‐dimensional microstructure of samples recovered from asteroid 25143 Itokawa: Comparison with LL5 and LL6 chondrite particles

In this study, the three‐dimensional (3‐D) microstructure of 48 Itokawa regolith particles was examined by synchrotron microtomography at SPring‐8 during the preliminary examination of Hayabusa samples. Moreover, the 3‐D microstructure of particles collected from two LL6 chondrites (Ensisheim and Kilabo meteorites) and an LL5 chondrite (Tuxtuac meteorite) was investigated by the same method for comparison. The modal abundances of minerals, especially olivine, bulk density, porosity, and grain size are similar in all samples, including voids and cracks. These results show that the Itokawa particles, which are surface materials from the S‐type asteroid Itokawa, are consistent with the LL chondrite materials in terms of not only elemental and isotopic composition of the minerals but also 3‐D microstructure. However, we could not determine whether the Itokawa particles are purely LL5, LL6, or a mixture of the two. No difference between the particles collected from Rooms A and B of the sample chamber, corresponding to the sampling sequence of the spacecraft's second and first touchdowns, respectively, was detected because of the statistically small amount of particles from Room B.     

Status of butyltin pollution along the coasts of western Japan in 2001, 11 years after partial restrictions on the usage of tributyltin

Restrictions on the use of tributyltin (TBT) in aquaculture and on boats in coastal regions, except for ocean-going vessels, have been in place in Japan since 1990 due to the strong toxic effects of TBT on marine organisms. However, TBT pollution along the Japanese coasts has been reported after this legislation was enacted. In order to elucidate the present status of contamination by butyltin (BT) compounds, we measured the levels of BTs [monobutyltin (MBT), dibutyltin (DBT) and TBT] in seawater and Caprella spp. samples obtained from the western part of Seto Inland Sea, Uwa Sea and Uranouchi Bay in western Japan during March to September, 2001. Butyltins were detected in more than 90% of the seawater samples (n = 59), with average concentrations of 8.2 ± 9.2 (SD) ng MBT L⁻¹, 3.3 ± 3.0 ng DBT L⁻¹ and 9.0 ± 7.0 ng TBT L⁻¹. Among 41 stations situated on coastal lines, a sufficient number of Caprella organisms for chemical analysis could be collected from only 16 stations. The butyltin concentrations in seawater and Caprella samples from Uwa Sea and Uranouchi Bay, in which the dominant industry in both waters is aquaculture, showed significantly higher than or no significant differences from those samples from the western part of Seto Inland Sea, a major heavy-industry area in Japan. As the TBT concentration in seawater increased, the number of Caprella organisms collected decreased. The mean TBT concentration among the seawater samples was above the estimated lowest observable effect concentration (LOEC) that reduces the survival rate of Caprella danilevskii. Thus, the present study indicates that TBT is still a potential ecological hazard to the survival of marine invertebrates inhabiting coasts along western Japan, even 11 years after the partial ban on TBT usage was implemented.     

Changes in microbial community composition in the leaf litter of successional communities after volcanic eruptions of Mount Usu,northern Japan

Changes in the fungal and bacterial biomass and community structure in litter after the volcanic eruptions of Mount Usu, northern Japan were investigated using a chronosequence approach, which is widely used for analyzing vegetation succession. The vegetation changed from bare ground(10 years after the eruptions) with little plant cover and poor soil to monotonic grassland dominated by Polygonum sachalinense with undeveloped soil(33 years) and then to deciduous broad-leaved forest dominated by Populus maximowiczii with diverse species composition and well-developed soil(100 years). At three chronosequential sites, we evaluated the compositions of phospholipid fatty acids(PLFAs), carbon(C) and nitrogen(N) contents and the isotope ratios of C(δ13C) and N(δ15N) in the litter of two dominant species, Polygonum sachalinense and Populus maximowiczii. The C/N ratio, δ13C and δ15N in the litter of these two species were higher in the forest than that in the bare ground and grassland. The PLFAs gradually increased from the bare ground to the forest, showing that microbial biomass increased with the development of the soil and/or vegetation. The fungi-to-bacteria ratio of PLFA was constant at 5.3 ± 1.4 in all three sites, suggesting that fungi were predominant. A canonical correspondence analysis suggested that the PLFA composition was related tothe successional ages and the developing soil properties(P 0.05, ANOSIM). The chronosequential analysis effectively detected the successional changes in both microbial and plant communities.     

A neutron activation analysis of iridium concentration in Yamato carbonaceous chondrite

Iridium concentration in extra-terrestrial bodies is an important quantity in relation to Ir-rich geological layers. Ir concentration of a Yamato carbonaceous chondrite (Y-793321) has been measured by a neutron activation method. The measurement yields a value (0.57 ± 0.06) g per gramme for the chondrite.     

A BTOP model to extend TOPMODEL for distributed hydrological simulation of large basins

Topography is a dominant factor in hillslope hydrology. TOPMODEL, which uses a topographical index derived from a simplified steady state assumption of mass balance and empirical equations of motion over a hillslope, has many advantages in this respect. Its use has been demonstrated in many small basins (catchment areas of the order of 2–500 km²) but not in large basins (catchment areas of the order of 10 000–100 000 km²). The objective of this paper is to introduce the Block‐wise TOPMODEL (BTOP) as an extension of the TOPMODEL concept in a grid based framework for distributed hydrological simulation of large river basins. This extension was made by redefining the topographical index by using an effective contributing area af(a) (0?f(a)?1) per unit grid cell area instead of the upstream catchment area per unit contour length and introducing a concept of mean groundwater travel distance. Further the transmissivity parameter T₀ was replaced by a groundwater dischargeability D which can provide a link between hill slope hydrology and macro hydrology. The BTOP model uses all the original TOPMODEL equations in their basic form. The BTOP model has been used as the core hydrological module of an integrated distributed hydrological model YHyM with advanced modules of precipitation, evapotranspiration, flow routing etc. Although the model has been successfully applied to many catchments around the world since 1999, there has not been a comprehensive theoretical basis presented in such applications. In this paper, an attempt is made to address this issue highlighted with an example application using the Mekong basin. Copyright © 2007 John Wiley & Sons, Ltd.     

Bifurcation current along the southwest coast of the Kii Peninsula

Along the southwest coast of the Kii Peninsula, a bifurcation current is regularly observed. By using ADCP data taken on board the R/V Wakayama of the Wakayama Prefectural Fisheries Experimental Station, characteristics of this bifurcation current are analyzed. The occurrence frequency of the bifurcation current reaches about 70% in the period from 1988 to 1996. The bifurcation point appears to be changeable and occurs almost evenly between Cape Ichie and Cape Shionomisaki. The current divergence in the alongshore direction was also investigated. Positive divergence values dominated in the whole analyzed area, and an onshore current appears to be dominant along the southwest coast of the Kii Peninsula, except in 1990 when the Kuroshio flowed in a large meandering path.