Rare Earth Element Enrichment in Late Archean Manganese Deposits from the Iron Ore Group,East India

The major, trace and rare earth element (REE) composition of Late Archean manganese, ferromanganese and iron ores from the Iron Ore Group (IOG) in Orissa, east India, was examined. Manganese deposits, occurring above the iron formations of the IOG, display massive, rhythmically laminated or botryoidal textures. The ores are composed primarily of iron and manganese, and are low in other major and trace elements such as SiO₂, Al₂O₃, P₂O₅ and Zr. The total REE concentration is as high as 975 ppm in manganese ores, whereas concentrations as high as 345 ppm and 211 ppm are found in ferromanganese and iron ores, respectively. Heavy REE (HREE) enrichments, negative Ce anomalies and positive Eu anomalies were observed in post‐Archean average shale (PAAS)‐normalized REE patterns of the IOG manganese and ferromanganese ores. The stratiform or stratabound shapes of ore bodies within the shale horizon, and REE geochemistry, suggest that the manganese and ferromanganese ores of the IOG were formed by iron and/or manganese precipitation from a submarine, hydrothermal solution under oxic conditions that occurred as a result of mixing with oxic seawater. While HREE concentrations in the Late Archean manganese and ferromanganese ores in the IOG are slightly less than those of the Phanerozoic ferromanganese ores in Japan, HREE resources in the IOG manganese deposits appear to be two orders of magnitude higher because of the large size of the deposits. Although a reliable, economic concentration technique for HREE from manganese and ferromanganese ores has not yet been developed, those ores could be an important future source of HREE.     

Comparative geochemical,magnetic susceptibility,and fluid inclusion studies on the Paleoproterozoic Malanjkhand and Dongargarh granitoids,Central India and implications to metallogeny

The Malanjkhand granodiorite (MG) hosting economic copper mineralization and the hitherto barren Dongargarh granitoids (DG) have subtle differences in their petrographic and bulk geochemical features. The two plutons are contiguous and occur in the northern part of the Bhandara Craton in Central India with intervening volcanosedimentary sequence of the Dongargarh Supergroup amidst older gneisses. The Dongargarh granitoids studied in two smaller units have higher bulk magnetic susceptibility than the Cu-bearing MG; the majority of samples studied from the latter being ilmenite-series rocks. DG crystallized at higher pressures compared to MG. Plagioclase composition ranges from albite to high bytownite in MG, whereas its compositional range is restricted to high andesine in DG. However, both intrusions give identical temperature ranges estimated by binary feldspar thermometry. Biotite in MG shows higher Fe/Mg ratios, as well as a greater range of compositional variation, than that in DG. MG has a moderately fractionated rare earth element distribution pattern without any significant Eu anomaly, showing depletion in mid-range rare earth elements (REE) and no depletion in heavy REE. DG is characterized by a prominent negative Eu anomaly. Geochemical features indicate subtle differences in the nature of source rocks and/or melting processes responsible for the generation of the two granitoids. MG displays more consistent bulk chemical features and is possibly a result of crystallization from a homogeneous granodioritic melt. DG displays a greater diversity and possibly incorporated a significant felsic crustal component that contributed to the parent melt. A fluid inclusion study of quartz grains from the granitoids and barren quartz veins occurring in MG indicates identical low-temperature nature of the fluid in both cases. They differ from the fluid in the mineralized zone in MG in the absence of a high-temperature component and CO₂ in the fluid. Late-stage fluids in DG and associated barren quartz veins compare well with those from MG. The hydrothermal activity following the granite emplacement seems to have operated under identical temperature conditions, and the aqueous fluid at the two occurrences seems to have been broadly similar. In both cases, internal evolution of the exsolved fluid to low temperatures and moderate salinity are visualized. Based on the existing information, the lack of ore potential in DG may be attributed to the metal and volatile (water + halogens) deficient nature of the parental granitic melt.     

Aeolian dust experiment on climate impact: An overview of Japan–China joint project ADEC

The Aeolian Dust Experiment on Climate Impact (ADEC) was initiated in April 2000 as a joint five-year Japan–China project. The goal was to understand the impact of aeolian dust on climate via radiative forcing (RF). Field experiments and numerical simulations were conducted from the source regions in northwestern China to the downwind region in Japan in order to understand wind erosion processes temporal and spatial distribution of dust during their long-range transportation chemical, physical, and optical properties of dust and the direct effect of radiative forcing due to dust. For this, three intensive observation periods (IOP) were conducted from April 2002 to April 2004.The in situ and network observation results are summarized as follows: (1) In situ observations of the wind erosion process revealed that the vertical profile of moving sand has a clear size dependency with height and saltation flux and that threshold wind velocity is dependent on soil moisture. Results also demonstrated that saltation flux is strongly dependent on the parent soil size distribution of the desert surface. (2) Both lidar observations and model simulations revealed a multiple dust layer in East Asia. A numerical simulation of a chemical transport model, CFORS, illustrated the elevated dust layer from the Taklimakan Desert and the lower dust layer from the Gobi Desert. The global-scale dust model, MASINGAR, also simulated the dust layer in the middle to upper free troposphere in East Asia, which originated from North Africa and the Middle East during a dust storm in March 2003. Raman lidar observations at Tsukuba, Japan, found the ice cloud associated with the dust layer at an altitude of 6 to 9 km. Analysis from lidar and the radio-sonde observation suggested that the Asian dust acted as ice nuclei at the ice-saturated region. These results suggest the importance of dust's climate impact via the indirect effect of radiative forcing due to the activation of dust into ice nuclei. (3) Studies on the aerosol concentration indicated that size distributions of aerosols in downwind regions have bimodal peaks. One peak was in the submicron range and the other in the supermicron range. The main soluble components of the supermicron peak were Na⁺, Ca²⁺, NO₃⁻, and Cl⁻. In the downwind region in Japan, the dust, sea salt, and a mixture of the two were found to be dominant in coarse particles in the mixed boundary layer. (4) Observation of the optical properties of dust by sky-radiometer, particle shoot absorption photometer (PSAP), and Nephelometer indicated that unpolluted dust at source region has a weaker absorption than originally believed.A sensitivity experiment of direct RF by dust indicated that single scattering albedo is the most important of the optical properties of dust and that the sensitivity of instantaneous RF in the shortwave region at the top of the atmosphere to the refractive index strongly depends on surface albedo. A global scale dust model, MASINGAR, was used for evaluation of direct RF due to dust. The results indicated the global mean RF at the top and the bottom of the atmosphere were − 0.46 and − 2.13 W m^− 2 with cloud and were almost half of the RF with cloud-free condition.     

Long-term variations of available solar radiation on seasonal timescales in 1955–2006 at Tartu-Tõravere Meteorological Station, Estonia

The time series of the daily sums of global and direct irradiance recorded at Tartu-Tõravere Meteorological Station site (58°16′N, 26°28′E, 70 m a.s.l.) in 1955–2006 have been analyzed in seasonal timescales. The average daily ratio G/G _clear of available global irradiance to its local climatic clear-sky value in the summer half-year corresponds to 65.5%, while that of the direct irradiance on the horizontal surface I′/I′ _clear was 41% of the climatic clear-sky value. In the case of dry Rayleigh atmosphere as a reference, these ratios are 53.5% and 28%, respectively. The time series of the summer season totals reveal a longer interval of reduced values in 1976–1993 as well as two periods of frequent sunny summers in 1967–1975 and since 1994. The probability density distribution of the summer season totals during the observed period is strongly asymmetric; in spring, however, it is close to the normal distribution. In winter, there is a moderate negative correlation between the G/G _clear and the North Atlantic Oscillation as well as the Arctic Oscillation indices.     

Dynamic characteristics of non-classically damped structures

The equations of motion of a structure in undamped modal coordinates may have non-zero off-diagonal terms in the damping matrix. Although these terms are commonly neglected, studies have shown that they may have a significant influence on the response to dynamic loads. In this paper, two independent criteria are developed to determine when these damping terms will affect the structure's modal properties and response. It is found that even small off-diagonal damping values can be significant if the structure has closely spaced natural frequencies. To quantify and understand the influence of these damping terms, closed-form analytical expressions are derived for the modal properties and harmonic and stochastic response of structures with closely spaced natural frequencies. One conclusion is that off-diagonal damping terms will decrease a modal damping ratio for each pair of closely spaced modes. This is significant, since a response analysis performed by neglecting these off-diagonal terms will underestimate the true response.     

Observation of lake breeze penetration and subsequent development of the thermal internal boundary layer for the Nanticoke II Shoreline Diffusion Experiment

The turbulent structure of the lake breeze penetration and subsequent development of the thermal internal boundary layer (TIBL) was observed using a kytoon-mounted ultrasonic anemometer-thermometer. The lake breeze penetrated with an upward rolling motion associated with the upward flow near the lake breeze front. After the lake breeze front passed, the behaviors of the velocity and temperature at the top of the lake breeze layer were similar to those found in convective boundary layers (CBL). Comparing _gq/_*, _u /w _* and _w /w _* between the present observation of TIBL development after the passage of the lake breeze front and CBL data from the literature, the /_* values showed reasonable agreement; however, _u /w _* and _w /W_* had smaller values in the TIBL than in the CBL at higher altitudes. This is due to the differences in the mean velocity profiles. While the CBL has a uniform velocity profile, the TIBL has a peak at lower elevation due to the lake breeze penetration; the velocity then decreases with height.Present address: The Institute of Behavioral Science, 1-35-7 Yoyogi, Tokyo 151, Japan.     

Numerical modeling of the nocturnal urban boundary layer

A numerical case study with a second-order turbulence closure model is proposed to study the role of urban canopy layer (UCL) for the formation of the nocturnal urban boundary layer (UBL). The turbulent diffusion coefficient was determined from an algebraic stress model. The concept of urban building surface area density is proposed to represent the UCL. Calculated results were also compared with field observation data. The height of the elevated inversion above an urban center was simulated and found to be approximately twice the average building height. The turbulent kinetic energy k, energy dissipation rate , and turbulence intensities u ² and w ² increase rapidly at the upwind edge of the urban area. The Reynolds stress uw displayed a nearly uniform profile inside the UBL, and the vertical sensible heat flux w had a negative value at the inversion base height. This indicates that the downward transport of sensible heat from the inversion base may play an important role in the formation of the nocturnal UBL.     

A simple extension of the Louis method for rough surface layer modelling

The surface flux calculation method proposed by Louis (1979) is extended by allowing momentum and heat to have different roughness lengths (z ₀ andz T respectively). Our approach is to extend the traditional analysis by a more careful consideration of potential temperature structure near the surface. This consideration leads to a redefinition of the bulk Richardson number. For bulk transfer coefficients, our method shows a significant improvement over the original Louis method when compared with the theoretical surface-layer model applied to rough surfaces. Numerical experiments simulating sea breezes in 2D show that our extension is crucially important in simulating light wind and low humidity conditions.