Contamination of organotin compounds and imposex in molluscs from Vancouver,Canada

Gastropods and bivalves were collected at 15 sites at Vancouver and Victoria, Canada between 24 May and 7 June, 1999, to establish tissue concentrations of butyltin and phenyltin compounds, to record imposex symptoms in gastropods, and to assess the present status of organotin contamination around Vancouver. No neogastropods (such as Nucella lima) were found around Vancouver. Neogastropod populations could have been extirpated by severe TBT contamination in Vancouver, as relatively high concentrations of TBT were detected in tissues of Mytilus trossulus from Vancouver, and the neogastropods distributed in Vancouver might be sensitive to TBT. Recovery from imposex, however, was observed in neogastropod populations from three sites at Victoria and Mission Point. TBT contamination has continued around Vancouver, arising from continuous use of TBT in antifouling paints for vessels larger than 25 m in length; however, TBT has decreased around Victoria and Mission Point. Different patterns of TBT accumulation in tissue were observed among the bivalve species from Vancouver. The highest TBT concentration detected in Tresus capax suggested some possible adverse effects. TBT was the most predominant butyltin component in almost all bivalve specimens surveyed, suggesting a low rate of TBT metabolism. Phenyltin compounds were not detected in any molluscan specimens in this study.     

Characterization of Asian Dust during ACE-Asia

ACE-Asia was a multi-national collaboration organized to investigate and understand the chemistry, radiative properties, and climatic effects of mineral dust and other aerosol particles in the East Asia/Northwest Pacific region. Studies conducted at the Gosan and Zhenbeitai surface supersites show striking variations in aerosol concentrations and properties that were affected by the occurrence and origins of the Asian dust storms, air mass pathways, and mixing during the transport. Investigations conducted on the R/V Ronald H. Brown (RHB) showed that dust had a pervasive influence on the chemical composition, size distribution, and optical properties of the aerosol. Analyses using an aerosol time-of-flight mass spectrometer on the RHB showed that most of the coarse-particle nitrate and sulfate in post-frontal air was associated with dust, and more remarkably, that competitive or exclusionary processes evidently are involved in the uptake or production of these substances. Studies conducted onboard the NCAR C-130 aircraft showed that coarse-mode dust was less absorbing and less hygroscopic than pollution aerosol and that there was little correlation in light scattering and absorption by the sub- vs. super-micrometer aerosol. Below 2 km, dust was commonly mixed with pollutants, and this had a stronger influence on the optical properties of the submicrometer particles than the coarse-mode dust; at higher altitudes, the dust was less affected by pollution. Single particle analyses of C-130 samples showed that the mixing of black carbon (BC) with dust was common, but only certain types of BC particles were aggregated. Models were used in the planning, execution and interpretative phases of ACE-Asia; and summaries of modeling results are presented to illustrate the progress being made in identifying new dust sources; in depicting the time-varying, three-dimensional structure of dust plumes; and in quantifying the production, transport, and deposition of Asian dust.     

Entrainment and emplacement of englacial debris bands near the margin of Storglaciären,Sweden

Internal structure, stable isotope composition and tritium concentration were measured in and around debris‐bearing ice at the margin of Storglaciären, where englacial debris bands have previously been inferred to form by thrusting. Two types of debris bands were distinguished: (i) an unsorted diamicton band that is laterally continuous for more than 200 m, and (ii) well‐sorted sand and gravel bands that are lenticular and discontinuous. Above‐background tritium levels and enrichment of δ¹⁸ O and δD in ice from the diamicton band indicate entrainment by basal freeze‐on since 1952. Isotopic enrichment and tritium‐free ice in the sandy debris bands also indicate entrainment in freezing water, but prior to 1952. The lenticular cross‐section, sorting and stratification of the sandy bands suggest that they were deposited englacially. The basally accreted diamicton band has been elevated tens of metres above the bed and presently overlies the englacially deposited sandy bands, suggesting that the stratigraphy has been disrupted. Three interpretations could account for these observations: (i) thrusting of fast‐moving ice over slow, marginal ice uplifting recently accreted basal ice along the fault; (ii) folding near the margin, elevating young basal ice over older basal and englacial ice; and (iii) debris‐band formation by an unknown mechanism and subsequent contamination of ice geochemical properties by meltwater flow through debris bands. Although none of these interpretations is consistent with all measurements, folding is most compatible with observations and local ice‐flow kinematics.     

The causes of land-use and land-cover change: moving beyond the myths

Common understanding of the causes of land-use and land-cover change is dominated by simplifications which, in turn, underlie many environment-development policies. This article tracks some of the major myths on driving forces of land-cover change and proposes alternative pathways of change that are better supported by case study evidence. Cases reviewed support the conclusion that neither population nor poverty alone constitute the sole and major underlying causes of land-cover change worldwide. Rather, peoples’ responses to economic opportunities, as mediated by institutional factors, drive land-cover changes. Opportunities and constraints for new land uses are created by local as well as national markets and policies. Global forces become the main determinants of land-use change, as they amplify or attenuate local factors.     

Timing of remanent magnetization acquisition in red beds: A case study from a syn-folding sedimentary basin

We propose to explain the origin of the double trend in seismicity of the Macas swarm in the Subandean Cordillera of Cutucú (Ecuador) and characterize the corresponding active deformation of that region. For that purpose, seismological and geological data have been used, with the deployment of a temporary seismological array, with geological field observations and image processing. We found that some earthquakes are aligned on a well known NNE–SSW trend corresponding to the orientation of the nodal planes of the reverse focal mechanism of the M_w=7.0 1995 Macas earthquake as for its aftershocks. Nevertheless, many smaller events are aligned on an unexpected NNW–SSE trend inside the Cutucú Cordillera. We interpret these two orientations of the Macas swarm as linked to Subandean basement thrusts inherited from the inversion tectonics of a NNE–SSW trending Triassic–Jurassic rift, which has been uplifted and partly extruded in the Cutucú Cordillera. The present partitioning of this part of the Subandean deformation is controlled by pre-existing NNE–SSW to NNW–SSE Triassic–Jurassic normal faults that have been subsequently compressed–transpressed and reactivated into reverse faults. Major boundary faults of the rift were NNE–SSW oriented and correspond now to some main Subandean thrusts as confirms the focal mechanism of the 1995 main shock located on the eastern border (Morona frontal thrust) and the orientation of its aftershocks. In the Cutucú Cordillera, the double orientation of present swarm can be interpreted as the result of accommodation of deformation along NNW–SSE pre-existing faults inside the inverted rift system, linked to the motion of the Morona frontal NNE–SSW thrust.     

Numerical Study On Cloud Lines Over An Urban Street In Tokyo

`Kanpachi Street Cloud (KSC)' is an unusual small-scalecumulus cloud line visible during calm summer conditions over a major street in the Tokyo metropolitanarea. In order to understand the mechanism leading to the formation of this cloud line,numerical simulations have been performed using the Regional Atmospheric Modelling System.The general characteristics of the simulated KSC agree well with observations. On alarge-scale view, the KSC can be characterized as a cumulus cloud line generated at the convergenceline of two sea breezes on the western side of Tokyo Bay, while on the microscale view, it resemblesBenard-type thermal convection modified longitudinally by wind shear.The location of the convergence line leading to the KSCformation coincides withthe Kanpachi street location, although the street itself does notmake any direct effect on the KSC formation. Additional numerical experiments were performed toidentify causes of the KSC formation in accordance with urbanization, by changing anthropogenicheat impact, land-cover and grid resolution.They confirmed that the formation of the KSC requirestwo meteorological processes at the same time:(1) the convergence of two sea breezes – the localsouth-eastern sea breeze from Tokyo Bay andan extended southern sea breeze from thePacific Ocean, respectively; (2) Forcing due to an urban heat island. It is shown that urbanization couldchange the intensity and position of the KSC through enhancement of local upward motions and changesin the near-surface horizontal pressure gradient between urban and sub-urban areas. Further,fine horizontal grid resolution is needed to be able to resolve these local thermal convection issues.     

Dynamic characteristics of non-classically damped structures

The equations of motion of a structure in undamped modal coordinates may have non-zero off-diagonal terms in the damping matrix. Although these terms are commonly neglected, studies have shown that they may have a significant influence on the response to dynamic loads. In this paper, two independent criteria are developed to determine when these damping terms will affect the structure's modal properties and response. It is found that even small off-diagonal damping values can be significant if the structure has closely spaced natural frequencies. To quantify and understand the influence of these damping terms, closed-form analytical expressions are derived for the modal properties and harmonic and stochastic response of structures with closely spaced natural frequencies. One conclusion is that off-diagonal damping terms will decrease a modal damping ratio for each pair of closely spaced modes. This is significant, since a response analysis performed by neglecting these off-diagonal terms will underestimate the true response.