Platinum-Group Elements and Gold Determination in NiS Fire Assay Buttons by UV Laser Ablation ICP-MS

The direct analysis of nickel sulfide fire assay buttons by UV laser ablation ICP-MS was used to determine the platinum-group elements and gold in the following reference materials: UMT-1, WPR-1, WMG-1, GPt-4, GPt-6 and CHR-Bkg. The instrument was calibrated with buttons prepared using quartz doped with the appropriate standard solutions. Analytical precision (RSD) was generally better than 10%, although occasional higher RSDs may infer local heterogeneities within nickel sulfide buttons. Good or excellent agreement was observed between analysed and reference material values except Rh in UMT-1 and WMG-1, which suffered an interference from copper. Detection limits calculated as 10 s quantitation limits were Au (1.7 ng g⁻¹), Pd (3.3 ng g⁻¹), Pt (8.3 ng g⁻¹), Os (1.3 ng g⁻¹), Rh (1 ng g⁻¹), Ru (5 ng g⁻¹) and Ir (0.7 ng g⁻¹).     

Europium anomaly variation under low-temperature water-rock interaction: A new thermometer

The positive europium (Eu) anomaly, enrichment of Eu abundance relative to the neighboring elements, is often observed for water interacted with the rocks. Not only high temperature (~400°C) water-rock interaction such as seafloor hydrothermal fluids, but also relatively lower temperature interaction, less than 100°C, cause positive Eu anomaly. However, relationship between the degree of Eu anomaly and interaction temperature has not been investigated. Water-rock interaction experiments at three different reaction temperatures were performed in this study to reveal the cause of positive Eu anomaly. Comparison of the results under different solution chemistry and temperature conditions showed that the basalt containing plagioclase released larger abundances of REEs than the basaltic glass. The degree of Eu anomaly assessed by Eu/Eu* value was smaller when 0.7 M NaCl solution was used for liquid phase for both solid phases. On the other hand, the Eu/Eu* became larger with increasing reaction temperature for basalts interacted with ultra-pure water. Therefore, it is suggested that the Eu anomaly is potentially used as a fluid-rock interaction thermometer under low salinity condition.     

Gravity measurements with a portable absolute gravimeter A10 in Syowa Station and Langhovde,East Antarctica

Absolute gravity values were measured with a portable absolute gravimeter A10 in East Antarctica, for the first time by the Japanese Antarctic Research Expedition. This study aims to investigate regional spatiotemporal variations of ice mass distributions and associated crustal deformations around Syowa Station by means of repeated absolute gravity measurements, and we obtained the first absolute gravity value in Southern Langhovde on the Antarctic Continent. The average absolute gravity value at the newly installed benchmark AGS01 in Langhovde (obtained on 3 February 2012) was 982535584.2 ± 0.7 μgal (1 [μgal] = 1 × 10^?8 [m/s²]), which was in agreement with the gravity values obtained by the past relative gravity measurements within 1 mgal. In addition, the average absolute gravity value obtained at AGSaux in Syowa Station was consistent with both previous absolute gravity values and those obtained by simultaneous measurements using an FG5 gravimeter, owing to adequate data corrections associated with tidal effects and time variations in atomic clock frequencies. In order to detect the gravity changes associated with the ice mass changes and other tectonic phenomena, we plan to conduct absolute gravity measurements at AGS01 again and at other campaign sites around Syowa Station as well in the near future, with careful attention paid to the impacts of severe environmental conditions in Antarctica on gravity data collection.     

Evaluation of Seasonal Sea Level Variation at Syowa Station, Antarctica, Using GPS Observations

Global Positioning System (GPS) measurements of the vertical displacement of fast ice near Syowa Station, Antarctica, were conducted between April and December 1998 to evaluate measurements of sea level variation derived with a conventional bottom pressure gauge (BPG). The BPG-derived sea level revealed a seasonal variation of about 0.13 m, with a high in April–June and a low in November–December. The GPS-derived sea level, combined with observed sea ice thickness, supported the BPG result, with an RMS error of 0.007 m. Our result also demonstrates that GPS is a powerful technique for monitoring sea level variations. This revised version was published online in July 2006 with corrections to the Cover Date.     

Estimation of seasonal changes in the flow of Shirase Glacier using JERS-1/SAR image correlation

This paper presents estimates of detailed seasonal variations in ice-flow velocity for Shirase Glacier calculated using data obtained by Japanese Earth Resources Satellite-1 (JERS-1) synthetic aperture radar (SAR). We used 12 pairs of images (44-day repeat cycle) over the interval from 30 April 1996 to 1 July 1998 to estimate ice-flow fields using an image correlation method. Geometric registration was performed with reference to the RADARSAT Antarctic Mapping Project (RAMP) image dataset. Error analysis based on feature mismatch indicated an absolute error of ±0.30 km/a and relative error of ±0.04 km/a in the estimated flow velocity. The obtained ice-flow velocity increases rapidly from the upstream region (1.18 km/a) to the grounding line, where it becomes stagnant (2.32 km/a), before accelerating gradually to 2.62–2.82 km/a in the downstream region and then increasing to 3.05–3.50 km/a at the terminus of the floating ice tongue. The ice-flow velocities in the downstream region are highly variable, depending on both the distance from the grounding line and the observed epoch (season). Most of the obtained seasonal variations in ice-flow velocity at the floating ice tongue are within the range of the associated error estimate, but the annual difference between 1997 (3.11 km/a) and 1998 (3.50 km/a) is significant, reflecting a possible acceleration in the ice-flow velocity in association with the disappearance of the floating ice tongue between April and May of 1998. In terms of the summer–winter difference in averaged air temperature, the large difference recorded in 1997 (17.0 °C) relative to 1996 (13.9 °C) corresponds to a reduced ice-flow velocity in 1997 (approximately 0.20 km/a) relative to that in 1996 (approximately 0.30 km/a), indicating interactions between air, sea ice, and glacier flow in Lützow-Holm Bay.     

Large P–T gap between Ballantrae blueschist/garnet pyroxenite and surrounding ophiolite, southern Scotland, UK: Diapiric exhumation of a Caledonian serpentinite mélange

The Ballantrae ophiolite in southern Scotland includes a NEE–SWW-trending serpentinite mélange that contains blocks of mafic blueschist and high-pressure, granulite facies, metapyroxenite (Sm–Nd metamorphic age: 576 ± 32 and 505 ± 11 Ma). Tectonic blocks of mafic schist are less than 3 × 3 m in size, and have greenschist, blueschist or epidote amphibolite facies assemblages corresponding to the high-pressure intermediate-type metamorphic facies series.Adjacent rocks of the serpentinite mélange are hydrothermally-altered MORB-like ophiolitic basalt (prehnite–pumpellyite facies), dolerite (actinolite–oligoclase sub-facies) and gabbro (amphibolite facies), all with assemblages that are diagnostic of the low-pressure metamorphic facies series.The difference in metamorphic facies series and parageneses of minerals between the high-pressure mafic blocks and the adjacent, low-pressure ophiolitic meta-basic rocks suggests that the former were exhumed from > 25 km depth within a cold subducted slab, and were juxtaposed with the latter, the bottom of a MORB-like ophiolite in the hanging wall of a trench. An ENE–WSW-trending, 501 ± 12 Ma volcanic arc belt extends for 3 km south of the serpentinite mélange. We suggest that ridge subduction associated with a slab window created arc-related gabbro (483 ± 4 Ma) at Byne Hill and within-plate gabbro (487 ± 8 Ma) at Millenderdale. Final continental collision created the duplex structure of the Ballantrae complex that includes the HP blocks and serpentinite mélange. These relations define diapiric exhumation in the Caledonian orogen of SW Scotland.     

Short-Term Stability Evaluation of an Embankment Constructed on Marine Clay Foundation at Kobe Airport

This article introduces the application of a stability analysis method that accounts for strength anisotropy on the embankment constructed at the Kobe airport. Shear strength anisotropy is induced by the in-situ state of stress along a potential slip surface of the embankment. In addition, the effects of the shearing rate on the undrained shear strength of the marine clay are examined in detail based on the results of a series of constant-volume direct shear box (DSB), triaxial compression (TC), and triaxial extension (TE) tests varying shearing rates. The most critical slip surface was selected from the deterministic slope stability analysis using unconfined compression tests of undisturbed clay samples from the field. For the most critical slip surface, the potential factor of safety of the embankment is estimated to be within the range of 1.21 to 1.28, as indicated by the results of the stability analyses using the strengths obtained from the DSB, TC, and TE tests and varying shearing rates.     

Using GIS to develop a mobile communications network for disaster-damaged areas

Communications network damage resulting from a large disaster causes difficulties in the ability to rapidly understand the current situation and thus make appropriate decisions towards mitigating problems, such as where to send and dispense emergency supplies. The research outlined in this paper focuses on the rapid construction of a network after a disaster occurs. This study suggests ZigBee and geographic information systems (GIS) technologies to resolve these problems and provide an effective communication system. The experimental results of the ZigBee network system are presented, examples are provided of the mapping and analysis undertaken using GIS for the disaster-stricken area of Tsukuba City, Japan, and the communications node arrangements are determined for this region. These results demonstrate the effectiveness of establishing such a communications system for supporting efforts to relieve disaster-damaged areas.