Characteristics of Porphyry Cu Mineralization at Waisoi (Namosi District), Viti Levu, Fiji

The porphyry Cu deposits at Waisoi in Namosi district, Viti Levu are separated into two deposits: the Waisoi East deposit and the Waisoi West deposit. In the Waisoi East deposit, quartz porphyry is exposed and in the Waisoi West deposit, diorite porphyry is sporadically exposed in addition to a small body of quartz porphyry. The mineralization in the Waisoi East deposit is characterized by the bornite–chalcopyrite–pyrite assemblage associated with traces of molybdenite and native gold. Polyphase fluid inclusions in stockwork quartz veinlets show homogenization temperatures ranging from 210 to >500°C. The high‐grade Cu mineralization in the Waisoi West deposit is characterized by the bornite–chalcopyrite–pyrite assemblage accompanied with sheeted and stockwork quartz veinlets. Polyphase fluid inclusions occasionally containing hematite flakes in quartz veinlets in the center of the Waisoi West deposit homogenize at temperatures ranging from 450°C to >500°C. However, fluid inclusions in stockwork quartz veinlets in the periphery, homogenize at lower temperatures around 210°C. Both in the Waisoi East and Waisoi West deposits, primary bornite–chalcopyrite–pyrite assemblage in the high Cu‐grade zone was deposited at the upper stability limit of chalcopyrite with respect to sulfur fugacity. Thus, the principal Cu mineralization at the Waisoi deposits occurred at a relatively high sulfur fugacity, that is, in a high‐sulfidation environment.     

Comparison of stable isotopes,ratios of Cl/Cl and I/I in brine and deep groundwater from the Pacific coastal region and the eastern margin of the Japan Sea

Fifty-three samples, including brines associated with oil and natural gas reservoirs and groundwater samples from deep boreholes, were collected from the Pacific and Japan Sea coastal regions in Japan. The ¹²⁹I/¹²⁷I and ³⁶Cl/Cl ratios, and stable isotopes (δD and δ¹⁸O) are compared to investigate differences related to the geotectonic settings of the two regions. The δD and δ¹⁸O data indicate that brine and groundwater from the Pacific coastal region reflect mixing of meteoric water with connate seawater in the pores of sedimentary rocks. On the other hand, brine and groundwater from the Japan Sea coastal region have been hydrothermally altered. In particular, brines associated with petroleum accumulations at Niigata and Akita showed the same isotopic characteristics as fluids found in the Kuroko deposits of the Green Tuff region in northeastern Japan. There is little difference in the ³⁶Cl/Cl ratios in brine and groundwater from the Pacific and Japan Sea coasts. Most brine and some deep groundwater, except those from the Pleistocene Kazusa Group, have already reached the average secular equilibrium ratio of 9.9 ± 2.7 × 10⁻¹⁵ for their mudstone and sandstone reservoirs. There was no correlation between the ³⁶Cl/Cl ratios and differences in geotectonic setting between the Pacific and the Japan Sea coast. The molar I/Br ratio suggests that the I in all of water samples was of biogenic origin. The average ¹²⁹I/¹²⁷I ratio was 290 ± 130 × 10⁻¹⁵ to 294 ± 105 × 10⁻¹⁵ in both regions, showing no relationship to the different geotectonic settings. The uncontaminated brine and groundwater samples are likely to have retained the original ¹²⁹I/¹²⁷I ratios of marine I released from the old organic matter stored in sedimentary rock.     

Particle-tracking simulation for the drift/diffusion of spilled oils in the Sea of Okhotsk with a three-dimensional, high-resolution model

To conduct the simulation of oil spills in the Sea of Okhotsk, we developed a three-dimensional, high-resolution ocean circulation model. The model particularly improved the reproducibility of velocity field during the strong stratification period. Particle-tracking experiments with the effects of evaporation and biodegradation were performed using the combined data of daily ocean currents from the present model and the hourly diurnal tidal currents from the tidal model. The results are shown by the relative concentration of the particles averaged over the 8 years of 1998–2005 based on the ensemble forecast idea. For the case of particles released from the Sakhalin II oil field, the particles deployed in September–January are carried southward by the East Sakhalin Current, finally arriving at the Hokkaido coast, after 60–90 days. The particles deployed in March–August are diffused offshore by the synoptic wind drift, and hardly transported to regions south of Sakhalin. For the case of particles released from the region off Prigorodnoye, the oil export terminal, after the diffusion by the synoptic wind drift, a part of them are carried offshore of Hokkaido by the Soya Warm Current. The particles released in November–April flow out to the Japan Sea through the Soya Strait, mainly by the synoptic wind drift and secondly by the diffusion due to strong tidal currents around the Soya Strait. By considering the effects of evaporation and biodegradation, the relative concentration of the particles is considerably decreased before arriving at the Hokkaido coast, particularly in the case of drift from the Sakhalin II oil field.     

Vertical distribution of heavy metals and its seasonal variations in Beppu Bay

From July to November, the thermocline which has strong temperature gradient (0.7C m^–1) is formed in the bottom water of Beppu Bay, and it prevents the downward mixing of surface water. This has caused the bottom water of the basin to become depleted in oxygen, and in November the bottom water below about 60 m depth becomes anoxic. Accordingly manganese and iron are reduced and more soluble under the anoxic condition, those concentrations are high relative to surface water, and the maximums are 1,240g l^–1 and 80g l^–1. Under the anoxic condition, the flux of dissolved manganese from the sediment is about 10g cm^–2 day^–1.     

Water mass exchange and diapycnal mixing at Bussol’ Strait revealed by water mass properties

Intensive CTD observations that resolve the mean and tidal components were done with a total of 129 casts in summer of 2001 at Bussol’ Strait. Based on these data and all the available historical data, we have revealed the outflow from Bussol’ Strait to the Pacific and the significant diapycnal mixing in the strait. In the range 27.0−27.3σ _θ , the water property in Bussol’ Strait is almost identical to that of the Kuril Basin Water (KBW). The KBW out of Bussol’ Strait forms a water mass front with the East Kamchatka Current Water (EKCW). This front also corresponds to the front of the Oyashio Current. In the lower part of the intermediate layer (27.3−27.6σ _θ ), part of the water in the strait is characterized by lower temperature, lower salinity, and higher dissolved oxygen than that of KBW and EKCW, which can be explained only by the diapycnal mixing. The strong diapycnal mixing in the strait can also be shown by the density inversion, occurrence frequency of which corresponds well to the amplitude distribution of the diurnal current. In the density range 26.7−26.8σ _θ , the water in Bussol’ Strait has the lowest potential vorticity, suggesting that it is a source region of the low potential vorticity water. Seasonal change of the water can reach up to a density of 26.8σ _θ around Bussol’ Strait. This leads us to propose that the combination of winter convection and local tidal mixing leads to effective ventilation of the intermediate layer.     

Alteration and mass transfer inferred from the Hirabayashi GSJ drill penetrating the Nojima Fault, Japan

Abstract Mineralogical and geochemical studies on the fault rocks from the Nojima–Hirabayashi borehole, south-west Japan, are performed to clarify the alteration and mass transfer in the Nojima Fault Zone at shallow depths. A complete sequence from the hornblende–biotite granodiorite protolith to the fault core can be observed without serious disorganization by surface weathering. The parts deeper than 426.2 m are in the fault zone where rocks have suffered fault-related deformation and alteration. Characteristic alteration minerals in the fault zone are smectite, zeolites (laumontite, stilbite), and carbonate minerals (calcite and siderite). It is inferred that laumontite veins formed at temperatures higher than approximately 100°C during the fault activity. A reverse component in the movement of the Nojima Fault influences the distribution of zeolites. Zeolite is the main sealing mineral in relatively deep parts, whereas carbonate is the main sealing mineral at shallower depths. Several shear zones are recognized in the fault zone. Intense alteration is localized in the gouge zones. Rock chemistry changes in a different manner between different shear zones in the fault zone. The main shear zone (MSZ), which corresponds to the core of the Nojima Fault, shows increased concentration of most elements except Si, Al, Na, and K. However, a lower shear zone (LSZ-2), which is characterized by intense alteration rather than cataclastic deformation, shows a decreased concentration of most elements including Ti and Zr. A simple volume change analysis based on Ti and Zr immobility, commonly used to examine the changes in fault rock chemistry, cannot account fully for the different behaviors of Ti and Zr among the two gouge zones.     

Magnetic detection of heated soils at paleolithic sites in Japan

We present a methodological approach to detect heated soil on ancient sites, using magnetic measurements. The method is based on changes in magnetic signals of soil by heating. The following three types of soil were used for testing the method: silty soil (SS), weathered volcanic ash (WVA, = loam) and fairly fresh volcanic ash (VA) called Odori tephra. On heating above 250–600°C, the magnetic susceptibility and remanent magnetization intensity increased for the SS and WVA samples, reflecting chemical alteration of magnetic minerals (from goethites to magnetites through hematites). The VA sample showed no susceptibility change suggesting the absence of goethites within it. On heating below 250°C, only the intensities of all the samples increased. This is possibly due to acquisition of thermal remanent magnetization. The largest change of the magnetic signals was identified for the SS sample and the smallest one was seen for the VA sample. Therefore, the in situ susceptibility measurement, which is the nondestructive and indirect method, seems to be effective to detect heated soil for sites of aqueous deposits as the SS. On the other hand, for sites of aeolian deposits as the WVA (loam) and VA, the intensity measurement of collected soils seems to be the most reliable method to detect evidence of heating. The degree of the magnetic stability (coercivity) against progressive alternating-field demagnetization was also an important parameter, indicating whether the investigated soils were heated or unheated. © 1999 John Wiley & Sons, Inc.