Reynolds-Number Dependence of Gas Dispersion Over a Wavy Wall

Direct numerical simulations of an Ekman layer are performed to study flow evolution during the response of an initially neutral boundary layer to stable stratification. The Obukhov length, L, is varied among cases by imposing a range of stable buoyancy fluxes at the surface to mimic ground cooling. The imposition of constant surface buoyancy flux , i.e. constant-flux stability, leads to a buoyancy difference between the ground and background that tends to increase with time, unlike the constant-temperature stability case where a constant surface temperature is imposed. The initial collapse of turbulence in the surface layer owing to surface cooling that occurs over a time scale proportional to \(L/u_*\), where \(u_*\) is the friction velocity, is followed by turbulence recovery. The flow accelerates, and a “low-level jet” (LLJ) with inertial oscillations forms during the turbulence collapse. Turbulence statistics and budgets are examined to understand the recovery of turbulence. Vertical turbulence exchange, primarily by pressure transport, is found to initiate fluctuations in the surface layer and there is rebirth of turbulence through enhanced turbulence production as the LLJ shear increases. The turbulence recovery is not monotonic and exhibits temporal intermittency with several collapse/rebirth episodes. The boundary layer adjusts to an increase in the surface buoyancy flux by increased super-geostrophic velocity and surface stress such that the Obukhov length becomes similar among the cases and sufficiently large to allow fluctuations with sustained momentum and heat fluxes. The eventual state of fluctuations, achieved after about two inertial periods (\(ft \approx 4\pi \)), corresponds to global intermittency with turbulent patches in an otherwise quiescent background. Our simplified configuration is sufficient to identify turbulence collapse and rebirth, global and temporal intermittency, as well as formation of low-level jets, as in observations of the stratified atmospheric boundary layer.     

Mass balance of heavy metals in the seto inland sea, Japan

To discuss the geochemical and environmental behavior of heavy metals in the Seto Inland Sea, the largest semi-enclosed coastal sea in Japan, mass balances of Cu and Zn were studied by application of a simple box model using sedimentation rates and heavy metal contents of core sediments. In 1980, total sedimentary loads of Cu and Zn over the whole area of the Sea were estimated to be 630 and 3500 tons year⁻¹, respectively. Further, the sedimentary loads without (natural) and with human activities were estimated separately to be, respectively, 320 and 310 tons year⁻¹ for Cu and 1800 and 1700 tons year⁻¹ for Zn. Total inputs of Cu and Zn into the Sea, in 1980 were estimated to be 870 and 4250 tons year⁻¹ about one half of this being the result of human activities. 70% of the Cu input and 80% of the Zn input are taken into the sediments. Mean residence times of Cu and Zn in the Sea are calculated to be ≈0.3 and 0.2 years, respectively. Since these values are relatively small compared to the mean residence time of the seawater (0.9 years), Cu and Zn supplied to the Sea are considered to be accumulated rapidly in the sediments.     

First-principles simulation of high-pressure polymorphs in MgAl<Subscript>2</Subscript>O<Subscript>4</Subscript>

We have used density functional theory to investigate the stability of MgAl₂O₄ polymorphs under pressure. Our results can reasonably explain the transition sequence of MgAl₂O₄ polymorphs observed in previous experiments. The spinel phase (stable at ambient conditions) dissociates into periclase and corundum at 14 GPa. With increasing pressure, a phase change from the two oxides to a calcium-ferrite phase occurs, and finally transforms to a calcium-titanate phase at 68 GPa. The calcium-titanate phase is stable up to at least 150 GPa, and we did not observe a stability field for a hexagonal phase or periclase + Rh₂O₃(II)-type Al₂O₃. The bulk moduli of the phases calculated in this study are in good agreement with those measured in high-pressure experiments. Our results differ from those of a previous study using similar methods. We attribute this inconsistency to an incomplete optimization of a cell shape and ionic positions at high pressures in the previous calculations.     

Estimating snow distribution over a large area and its application for water resources

The spatial and temporal distribution of the snow water equivalent (SWE), snow density and snow depth were estimated by a method combining remote sensing technology and degree‐day techniques over a study area of 370 000 km². The advantages of this simulation model are its simplicity and the availability of degree‐day parameters, which can be successively evaluated by referring to snow area maps created from satellite images. This simulation worked very well for estimating SWE and helped to separate the areas of thin snow cover from heavier snowfall. However, shallow snow in warm regions led to some misjudgments in the snow area maps because of the time lag between when the satellite image was acquired and the simulation itself. Vulnerable areas, where a large variation in the amount of snow affects people's life, could be identified from the differences between heavy and light snow years. This vulnerability stems from a predicted lack of irrigation water for rice production caused by future climate change. The model developed in this study has the potential to contribute to water management activities and decision‐making processes when considering necessary adaptations to future climate change. Copyright © 2007 John Wiley & Sons, Ltd.     

Data assimilation using the particle filter for identifying the elasto‐plastic material properties of geomaterials

A computational method, incorporating the finite element model (FEM) into data assimilation using the particle filter, is presented for identifying elasto‐plastic material properties based on sequential measurements under the known changing traction boundary conditions to overcome some difficulties in identifying the parameters for elasto‐plastic problems from which the existing inverse analysis strategies have suffered. A soil–water coupled problem, which uses the elasto‐plastic constitutive model, is dealt with as the geotechnical application. Measured data on the settlement and the pore pressure are obtained from a synthetic FEM computation as the forward problem under the known parameters to be identified for both the element tests and the ground behavior during the embankment construction sequence. Parameter identification for elasto‐plastic problems, such as soil behavior, should be made by considering the measurements of deformation and/or pore pressure step by step from the initial stage of construction and throughout the deformation history under the changing traction boundary conditions because of the embankment or the excavation because the ground behavior is highly dependent on the loading history. Thus, it appears that sequential data assimilation techniques, such as the particle filter, are the preferable tools that can provide estimates of the state variables, that is, deformation, pore pressure, and unknown parameters, for the constitutive model in geotechnical practice. The present paper discusses the priority of the particle filter in its application to initial/boundary value problems for elasto‐plastic materials and demonstrates a couple of numerical examples. Copyright © 2012 John Wiley & Sons, Ltd.     

Ion microprobe analyses of oxygen three‐isotope ratios of chondrules from the Sayh al Uhaymir 290 CH chondrite using a multiple‐hole disk

Abstract– The ion microprobe is the only technique capable of determining high‐precision stable isotope ratios in individual tiny extraterrestrial particles (≤100 μm in diameter), but these small samples present special analytical challenges. We produced a new sample holder disk with multiple holes (three holes and seven holes), in which epoxy disks containing a single unknown sample and a standard grain are cast and polished. Performance tests for oxygen two‐isotope analyses using San Carlos olivine standard grains show that the new multiple‐hole disks allow accurate analysis of tiny particles if the particles are located within the 500 μm and 1 mm radius of the center of holes for seven‐hole and three‐hole disks, respectively. Using the new seven‐hole disk, oxygen three‐isotope ratios of eight magnesian cryptocrystalline chondrules (approximately 100 μm in diameter) from the Sayh al Uhaymir (SaU) 290 CH chondrite were analyzed by ion microprobe at the University of Wisconsin. Five out of eight chondrules have nearly identical oxygen isotope ratios (Δ¹⁷O = ?2.2 ± 0.6‰; 2SD), which is consistent with those of magnesian cryptocrystalline chondrules in CH/CB and CB chondrites, suggesting a genetic relationship, i.e., formation by a common (possibly impact) heating event. The other three chondrules have distinct oxygen isotope ratios (Δ¹⁷O values from ?6.4‰ to +2.2‰). Given that similar variation in Δ¹⁷O values was observed in type I porphyritic chondrules in a CH/CB chondrite, the three chondrules may have formed in the solar nebula, similar to the type I porphyritic chondrules.     

The nature of megafaunal extinctions during the MIS 3–2 transition in Japan

The nature of late Quaternary megafaunal extinctions has been the subject of intense debate since the 1960s. Traditionally, scientists cite either climatic changes or human predation as the primary reason for worldwide megafaunal extinctions. In many island cases (e.g., Madagascar, New Zealand), scientists have had a tendency to lean toward humans as being the direct or indirect dominant cause for the relatively quick extirpation of indigenous megafaunas. This study evaluates the record for megafaunal (e.g., Palaeoloxodon, Mammuthus, Sinomegaceros) extinctions in the Japanese islands and draw the tentative conclusion that: (1) humans directly and/or indirectly influenced the extinction of some large herbivores; and (2) the megafaunal extinctions likely began earlier than originally proposed; during the marine isotope stage (“MIS”) 3–2 transition (～30–20 ka) rather than during the MIS 2–1 (～15–10 ka) shift that roughly coincides with the advent of the Jomon period in Japan. However, we temper our findings due to the current paucity of sites in Japan that have associated archaeology and vertebrate paleontological materials that date to the MIS 3–2 transition.     

Temporal changes in electrical resistivity at Sakurajima volcano from continuous magnetotelluric observations

Continuous magnetotelluric (MT) measurements were conducted from May 2008 to July 2009 at Sakurajima, one of the most active volcanoes in Japan. Two observation sites were established at locations 3.3 km east and 3 km west–northwest of the summit crater. At both observation sites, the high-quality component of the impedance tensor (Zyx) showed variations in apparent resistivity of approximately ± 20% and phase change of ± 2°, which continued for 20–180 days in the frequency range between 320 and 4 Hz. The start of the period of changes in apparent resistivity approximately coincided with the start of uplift in the direction of the summit crater, as observed by a tiltmeter, which is one of the most reliable pieces of equipment with which to detect magma intrusion beneath a volcano. A 2D inversion of MT impedance suggests that the resistivity change occurred at a depth around sea level. One of the possible implications of the present finding is that the degassed volatiles migrated not only vertically through the conduit but also laterally through a fracture network, mixing with shallow groundwater beneath sea level and thereby causing the observed resistivity change.     

Recognition of an Early Triassic accretionary complex in the Nedamo Belt of the Kitakami Massif,Northeast Japan: New evidence for correlation with Southwest Japan

The Kitakami Massif of the Tohoku district, Northeast Japan, consists mainly of the South Kitakami Belt (Silurian–Cretaceous forearc shallow-marine sediments, granitoids, and forearc ophiolite) and the North Kitakami Belt (a Jurassic accretionary complex). The Nedamo Belt (a Carboniferous accretionary complex) occurs as a small unit between those two belts. An accretionary unit in the Nedamo Belt is lithologically divided into the Early Carboniferous Tsunatori Unit and the age-unknown Takinosawa Unit. In order to constrain the accretionary age of the Takinosawa Unit, detrital zircon U–Pb dating was conducted. The new data revealed that the youngest cluster ages from sandstone and tuffaceous rock are 257–248 Ma and 288–281 Ma, respectively. The Early Triassic depositional age of the sandstone may correspond to a period of intense magmatic activity in the eastern margin of the paleo-Asian continent. A 30–40 my interval between the youngest cluster ages of the sandstone and the tuffaceous rock can be explained by the absence of syn-sedimentary zircon in the tuffaceous rock. The new detrital zircon data suggest that the Takinosawa Unit can be distinguished as an Early Triassic accretionary complex distinct from the Early Carboniferous Tsunatori Unit. This recognition establishes a long-duration northeastward younging polarity of accretionary units, from the Carboniferous to Early Cretaceous, in the northern Kitakami Massif. Lithological features and detrital zircon spectra suggest that the Early Triassic Takinosawa Unit in the Nedamo Belt is comparable with the Hisone and Shingai units in the Kurosegawa Belt in Shikoku. The existence of this Early Triassic accretionary complex strongly supports a pre-Jurassic geotectonic correlation and similarity between Southwest and Northeast Japan.     

Uniformly mantle-like δ<Superscript>18</Superscript>O in zircons from oceanic plagiogranites and gabbros

Lower ocean crust is primarily gabbroic, although 1–2% felsic igneous rocks that are referred to collectively as plagiogranites occur locally. Recent experimental evidence suggests that plagiogranite magmas can form by hydrous partial melting of gabbro triggered by seawater-derived fluids, and thus they may indicate early, high-temperature hydrothermal fluid circulation. To explore seawater–rock interaction prior to and during the genesis of plagiogranite and other late-stage magmas, oxygen-isotope ratios preserved in igneous zircon have been measured by ion microprobe. A total of 197 zircons from 43 plagiogranite, evolved gabbro, and hydrothermally altered fault rock samples have been analyzed. Samples originate primarily from drill core acquired during Ocean Drilling Program and Integrated Ocean Drilling Program operations near the Mid-Atlantic and Southwest Indian Ridges. With the exception of rare, distinctively luminescent rims, all zircons from ocean crust record remarkably uniform δ¹⁸O with an average value of 5.2 ± 0.5‰ (2SD). The average δ¹⁸O(Zrc) would be in magmatic equilibrium with unaltered MORB [δ¹⁸O(WR) ~ 5.6–5.7‰], and is consistent with the previously determined value for equilibrium with the mantle. The narrow range of measured δ¹⁸O values is predicted for zircon crystallization from variable parent melt compositions and temperatures in a closed system, and provides no indication of any interactions between altered rocks or seawater and the evolved parent melts. If plagiogranite forms by hydrous partial melting, the uniform mantle-like δ¹⁸O(Zrc) requires melting and zircon crystallization prior to significant amounts of water–rock interactions that alter the protolith δ¹⁸O. Zircons from ocean crust have been proposed as a tectonic analog for >3.9 Ga detrital zircons from the earliest (Hadean) Earth by multiple workers. However, zircons from ocean crust are readily distinguished geochemically from zircons formed in continental crustal environments. Many of the >3.9 Ga zircons have mildly elevated δ¹⁸O (6.0–7.5‰), but such values have not been identified in any zircons from the large sample suite examined here. The difference in δ¹⁸O, in combination with newly acquired lithium concentrations and published trace element data, clearly shows that the >3.9 Ga detrital zircons did not originate by processes analogous to those in modern mid-ocean ridge settings.