Textural Evidence for the Chromite‐Oversaturated Character of the Melt Involved in Podiform Chromitite Formation

Well‐preserved oval‐shaped dunite clots occur within the exceptionally fresh massive podiform chromitites from the Coto Block of the Zambales Ophiolite Complex, the Philippines. The dunite/chromitite boundary shows an interlocking texture; olivine inclusions in chromites in the podiform chromitites show the same optical extinction with larger adjacent olivines in the dunite clots. This texture was formed by the reaction between chromite‐oversaturated melt and its dunite inclusions. The existence of such type of melt was previously only hypothesized to explain the origin of layered and podiform chromitites but is now confirmed by this discovery.     

On the distinct element parameters used for earthquake ground motion simulation

To overcome the difficulties in the choice of parameters used for the distinct element method, some hints are presented with a main focus on earthquake ground motion simulation. As a natural period of vibration, especially the fundamental period is an important factor in any earthquake response, nature of the fundamental period of distinct element systems is closely investigated. Meanwhile, nature of the least period of vibration is also investigated because of its importance in the selection of time step of a direct integration scheme. Reduction in elastic wave velocity due to discontinuity is described on the basis of experimental measurement on aluminum blocks. In addition to analytical formulation on damping properties, accelerograms observed on a rockfill dam model are compared with simulated ones, giving a useful suggestion on the viscous damping.     

Selective detection of Fe and Mn species at mineral surfaces in weathered granite by conversion electron yield X-ray absorption fine structure

A new method for the speciation of Fe and Mn at mineral surfaces is proposed using X-ray absorption fine structure in conversion electron yield mode (CEY-XAFS). This method generally reflects information on the species at the sub-μm scale from the particle surface due to the limited escape depth of the inelastic Auger electron. The surface sensitivity of this method was assessed by experiments on two samples of granite showing different degrees of weathering. The XANES spectra of the Fe-K and Mn-K edge clearly gave different information for CEY and fluorescence (FL) modes. These XANES spectra of Fe and Mn show a good fit upon application of least-squares fitting using ferrihydrite/MnO₂ and biotite as the end members. The XANES spectra collected by CEY mode provided more selective information on the secondary phases which are probably present at the mineral surfaces. In particular, CEY-XANES spectra of Mn indicated the presence of Mn oxide in unweathered granite despite a very small contribution of Mn oxide being indicated by FL-XANES and selective chemical-extraction analyses. Manganese oxide could not be detected by micro-beam XANES (beam size: 5 × 5 μm²) in unweathered granite, suggesting that Mn oxide thinly and ubiquitously coats mineral surface at a sub-μm scale. This information is important, since Mn oxide can be the host for various trace elements. CEY-XAFS can prove to be a powerful tool as a highly sensitive surface speciation method. Combination of CEY and FL-XAFS will help identify minor phases that form at mineral surfaces, but identification of Fe and Mn oxides at mineral surfaces is critical to understand the migration of trace elements in water-rock interaction.     

Numerical model of local scour considering the unsteady sediment inflow and sediment sorting: Application to scour upstream of slit weir

The current study proposes a novel framework for the numerical model for estimating the temporal scour considering unsteady sediment inflow and the sediment sorting process. The framework was applied to local scour upstream of a slit weir. The scour model is based on an ordinary nonlinear differential equation derived from sediment continuity and scour rate equations. A one-dimensional(1-D)Boussinesq-type model coupled with nonequilibrium sediment transport was incorporated in the scour model to...