Analytical and Chemometric Evaluation of the Situation of Waterbodies in the Polish Tatra Mountains

Chemometric methods are powerful in finding hidden structures and latent information in environmental and other analytical datasets. This work shows the application of cluster analysis, discriminant analysis, and support vector machines for the evaluation of waterbodies in the Polish Tatra Mountains. After the analysis of in situ parameters and the determination of concentrations of cations and anions, cluster analysis shows that the previous separation into Western Tatras and High Tatras should be reconsidered, as the Bystra stream in the border region might have been incorrectly assigned to the Western Tatras up to now. Discriminant analysis not only confirms the geographical separation of waterbodies, but also the fact that the sampling time is a crucial factor in environmental analysis. Samples taken in different months do not result in a homogenous object of investigation. A uniform date should therefore be chosen so that the results will be comparable. The influence of the sampling month on the classification of samples is also approved by support vector machines.     

Estimation of global lightning activity and observations of atmospheric electric field

Variations in the global atmospheric electric circuit are investigated using a wide range of globally spaced instruments observing VLF (∼10 kHz) waves, ELF (∼300 Hz) waves, Schumann resonances (4–60 Hz), and the atmospheric fair weather electric field. For the ELF/VLF observations, propagation effects are accounted for in a novel approach using established monthly averages of lightning location provided by the Lightning Image Sensor (LIS) and applying known frequency specific attenuation parameters for daytime/nighttime ELF/VLF propagation. Schumann resonances are analyzed using decomposition into propagating and standing waves in the Earth-ionosphere waveguide. Derived lightning activity is compared to existing global lightning detection networks and fair weather field observations. The results suggest that characteristics of lightning discharges vary by region and may have diverse effects upon the ionospheric potential.     

Particular application of a mathematical transport model incorporating sub-surface reactive pollutants

In the first part of the paper, a 2D transport equation was used, which takes into consideration only the non-linear adsorption term described by means of non-linear Freundlich isotherm. The equation of this type was the basis of numerical calculations of concentration for chosen indicators (nitrates and biochemical oxygen demand). In the second part, the presented equation took into consideration not only the nonlinear adsorption term, but also the term of biodegradation (biological denitrification), described by the first-order microbial reaction, most often applied in practice. Numerical calculations in the first and second parts of the paper were carried out using the same numerical scheme and the author’s program PCCS-2, presented in Aniszewski (2009) and compared afterwards with the measured concentration values. The calculation results made it possible to define the reduction degree of concentration reduction for the chosen chemicals as a result of reversible sorption and biodegradation processes.     

The influence of atmospheric circulation on the type of precipitation (Krak��w, southern Poland)

The paper discusses the impact of atmospheric circulation on the occurrence of various types of precipitation. A 146-year-long precipitation record from Kraków spanning the period 1863?C2008 was used alongside a calendar prepared by Nied?wied? (1981, 2009) describing circulation types covering the period 1873?C2008 and air masses and atmospheric fronts covering the period 1951?C2008 in southern Poland. The influence of atmospheric circulation on precipitation was measured using the frequency, conditional probability and average daily totals of precipitation. Circulation types, air masses and atmospheric fronts exerted influences on precipitation as a result of the seasonal variations of the thermal and moisture properties of air masses. The impact is best expressed by circulation types as these combine the aspect of cyclonicity/anticyclonicity with that of the direction of air advection, the two elements which determine the physical properties of the air. On average, liquid precipitation prevailed in all circulation types, except the Ea type in which snowfall dominated over liquid precipitation. Depending on the season, one of the three types of circulation, Wa, Wc and Bc, were shown to coincide with the greatest amount of liquid and thunderstorm precipitation. There was no single dominant circulation type for mixed precipitation or snowfall. In summer, the circulation types Nc, NEc, Cc and Bc were the most favourable to liquid and thunderstorm precipitation in terms of both probability and totals. In winter, snowfall was the most favoured by the Ec type. Frontal precipitation was twice as likely to occur as air mass precipitation, with the exception of snowfall which was predominantly an air mass type of precipitation in terms of probability, but its greatest totals were recorded on atmospheric fronts.     

The influence of precipitation intensity growth on the urban drainage systems designing

For 50 years of long observation period (1960–2009), on a high level of statistical significance (95 %), a decreasing trend of annual precipitation amounts and an increasing trend of the number of rainy days during the year (64 %) were found. For the seasonal changes (V–X), similarly, there was found a statistically significant (94 %) decreasing precipitation amount trend and an increasing trend of the number of rainy days (50 %). As far as the intensity of maximum precipitation is concerned, a very statistically significant increasing trend (95 %) was found. Taking as the basis, the model for a trend, defined for the period of 1960–2009, the increase of weighted average interval values of maximum precipitation amounts (h?≥?0.75?t ^0.5) in the year 2059 was estimated to be about 26 %, in comparison with the starting year 1960. An increasing trend of maximum precipitation frequency in Wroc?aw was also proved. To a safe sewerage systems designing in Wroc?aw according to current standards (EN 752 2008; DWA-A118 2006), the precipitation frequency to the simulations of excessive accumulation occurrences to the land level should be changed.     

On some methodological problems in the use of environmental tracers to estimate hydrogeologic parameters and to calibrate flow and transport models

Environmental tracers are used qualitatively for a better formulation of conceptual models and quantitatively for assessing groundwater ages with the aid of box models or for calibrating numerical transport models. Unfortunately, tracers often yield different ages that do not represent uniquely the water ages. Difficulties result also from different definitions of age, e.g. water age, advective age, tracer age, or radiometric tracer age, that are measured differently and depend on aquifer parameters and characteristics of particular tracers. Even the movement of an ideal tracer can be delayed with respect to the advective movement of water due to diffusion exchange between mobile and immobile water zones, which for fissured rocks or thin aquifers, may lead to significant differences between advective and tracer ages, i.e. also between advective and tracer velocities. The advective velocity is of importance in water resources considerations as being related to Darcy velocity, whereas the tracer velocity is a more useful term for the prediction of pollutant transport. When a groundwater system changes from one hydrodynamic steady state to another, environmental tracers need much more time to reach a new steady state. Several tracer studies are recalled as examples of tracer-specific effects on the estimations of groundwater age.     

Geochemical and statistical approach to evaluate background concentrations of Cd,Cu, Pb and Zn (case study: Eastern Poland)

An attempt was made to evaluate background concentrations of Cd, Cu, Pb and Zn by means of geochemical and statistical approach. As many as 753 samples taken from 51 profiles located in Eastern Poland were analysed. For the estimation of geochemical background values, direct geochemical methods and a statistical analysis for the whole population of samples were applied. Average values of heavy metal concentration in loess sediments (bedrock) as well as in profiles not affected by human activity were measured. The iterative 2σ technique and calculated distribution function were chosen as statistical methods. The resulting values (background concentrations range) were as follows: Cd 0.5–0.9 mg kg⁻¹, Cu 5–16 mg kg⁻¹, Pb 12–26 mg kg⁻¹ and Zn 31–47 mg kg⁻¹. All the methods applied gave similar results. The highest deviation of the background was noted for Cu and the lowest for Zn. The lowest values of background were obtained for loess sediments and the highest in the case of the multiple 2σ method.     

The significance of Chara vegetation in the precipitation of lacustrine calcium carbonate

A significant portion of calcium carbonate is deposited in lake sediments as a result of biological processes related to the photosynthetic activity of phytoplankton in the pelagic realm and, in addition, macrophytes in the littoral zone. Lake Wigry, one of the largest lakes in Poland (north‐east Poland), is characterized by: (i) carbonate sediments with a CaCO₃ content exceeding 80% within the littoral zone; and (ii) large areas of submerged vegetation dominated by charophytes (macroscopic green algae, Characeae family). It is claimed that charophytes are highly effective in utilizing HCO₃^? and forming thick CaCO₃ encrustations. Thus, this study was aimed at evaluating the CaCO₃ production by dense Chara stands overgrowing the lake bottom reaching a depth of 4 m. In late July 2009, the fresh and dry mass of plants, the percentage contribution of calcium carbonate and the production of CaCO₃ per 1 m² were investigated along three transects at three depths (1 m, 2 m and 3 m, with each sample area equal to 0·0625 m²) per transect. The composition and structure of phytoplankton and the physico‐chemical properties of the water analysed in both the littoral and pelagic zones served as the environmental background and demonstrated moderately low fertility in the lake. The greatest dry plant mass exceeded 1000 g m^?2 and CaCO₃ encrustations constituted from 59% to over 76% of the charophyte dry weight. Thus, the maximum and average values of carbonates precipitated by charophytes were 685·5 and 438 g m^?2, respectively, which exceeded previously reported results. A correlation of carbonate production with the depth of Chara stands was detected, and intermediate depths offered the most favourable conditions for carbonate precipitation (589 g m^?2 on average). As precipitated carbonates are ultimately stored in bottom deposits, the results highlight the significance of charophytes in lacustrine CaCO₃ sedimentation.