Determination of structures of Ca2CoSi2O7, Ca2MgSi2O7, and Ca2(Mg0.55Fe0.45)Si2O7 in incommensurate and normal phases and observation of diffuse streaks at high temperature

 The structures of Ca₂CoSi₂O₇, Ca₂MgSi₂O₇, and Ca₂(Mg_0.55Fe_0.45)Si₂O₇ have been determined in the temperature range between 297 and 773 K with arbitrary intervals. The structures of the incommensurate phase of the three compounds are characterized by the presence of the six-, seven-, and eight-coordinated Ca–O polyhedra and of the bundles along the c-axes consisting of four arrays of the six-coordinated Ca–O polyhedra and an array of T¹O₄ (T¹: Co, Mg, or Mg–Fe) tetrahedra in the structures. The number of bundles in each material decreases at elevated temperatures. The incommensurate phase undergoes a phase transition into the normal phase at 493 K in Ca₂CoSi₂O₇, at 360 K in Ca₂MgSi₂O₇, and at 510 K in Ca₂(Mg_0.55Fe_0.45)Si₂O₇. The features of the structures of the normal phase are almost the same as those found in the basic structures (the averaged structures of the incommensurate structures), and this fact implies that the characteristics of the structures, such as the six-coordinated Ca–O polyhedra or fragments of the bundles, should be partially preserved at higher temperatures both in the incommensurate structures and also in the structures of the normal phase. Analyses of anisotropic displacement parameters clarified that disorder of the modulation waves is developed in the structures at higher temperatures. The evolution of a disorder in the structures was ascertained by observation of the circular diffuse streaks in the vicinity of the transition temperature between the incommensurate and normal phases. Received: 3 July 2000 / Accepted: 26 October 2000     

The use of sintered diamond anvils in the MA8 type high-pressure apparatus

A new multi-anvil type high-presure apparatus has been developed using sintered diamond anvils to generate pressures over 30 GPa and temperatures up to about 2000°C. A maximum sample volume of about 1 mm³ is available in this system. The pressure was confirmed by dissociation of forsterite into Mg-perovskite and periclase. The basic techniques and problems in utilizing sintered diamond in the MA8 type high-pressure apparatus are discussed with an emphasis on the future prospect of incorporating simultancous X-ray diffraction observation.     

Tectonic implications of damage zone-related fault-fracture networks revealed in drill core through the Nojima fault, Japan

1800 m of drill core through the Nojima fault zone, Japan, reveals subsidiary fault and fracture networks that developed in the fault zone that triggered the 1995 Ms 7.2 Kobe earthquake. The subsidiary fault zones contain a fault gouge of < 1 cm bounded by thin zones of foliated cataclasite or breccia. Fractures are filled with calcite veins, calcite-cemented breccias, clay, and iron-oxide and carbonate alternation of the granitic host rock. These features are typical of extensional fractures that form the conduit network for fluid flux close to a major fault zone. The zone of distributed deformation surrounding the main fault is 50 m in width, and the dip of the Nojima fault at > 1 km depth is 75°. The fault-fracture networks associated with the Nojima fault zone are coseismic and were filled with carbonate and fine-grained material during repeated seismic-related infiltration of the fault zone by carbonate-bearing subsurface water. This study shows that fault-related fracture networks plays an important role as fluid flow conduits within seismically active faults, and can change in character from zones of high permeability to low permeability due to cementation and/or pore collapse.     

A statistical study of field-aligned electron beams associated with ion conies events

A statistical study of field-aligned electron beams associated with upflowing ion conics is presented from Exos-D (Akebono) observations below 10 000 km. The electron beams are narrowly collimated along the field line and generally have energies of several tens of eV. They are divided in the analysis into three types: upflowing, downflowing, and counterstreaming. All the types of electron beams are almost equivalent in their energy and pitch angle characteristics and their association rate with upflowing ion events. About 50% of ion conies are found to be coincident with field-aligned electron beams. There is also a correlation in energy between the field-aligned electrons and ion conics. These show that the association is not a mere coincidence but rather that the field-aligned acceleration of electrons is related to the perpendicular energization of ions. The association rate of upflowing electrons is high on the nightside, while that of downflowing electrons is high on the dayside. The association rate of downflowing electrons is high at low altitudes, and the rates of the three types of electron beams become equivalent at high altitudes. Data indicate that the height of the electron acceleration region is lower on the nightside. It is suggested that the average height of the electron acceleration region is around the satellite apogee (–10000 km), and the average thickness of the region is about thousands km.     

Resonance sticking in the scattered disk

We investigate the dynamical evolution of trans-neptunian objects (TNOs) in typical scattered disk orbits (scattered TNOs) by performing simulations using several thousand particles lying initially on Neptune-encountering orbits. We explore the role of resonance sticking in the scattered disk, a phenomenon characterized by multiple temporary resonance captures (‘resonances’ refers to external mean motion resonances with Neptune, which can be described in the form r:s, where the arguments r and s are integers). First, all scattered TNOs evolve through intermittent temporary resonance capture events and gravitational scattering by Neptune. Each scattered TNO experiences tens to hundreds of resonance captures over a period of 4 Gyr, which represents about 38% of the object's lifetime (mean value). Second, resonance sticking plays an important role at semimajor axes , where the great majority of such captures occurred. It is noteworthy that the stickiest (i.e., dominant) resonances in the scattered disk are located within this distance range and are those possessing the lowest argument s. This was evinced by r:1, r:2 and r:3 resonances, which played the greatest role during resonance sticking evolution, often leading to captures in several of their neighboring resonances. Finally, the timescales and likelihood of temporary resonance captures are roughly proportional to resonance strength. The dominance of low s resonances is also related to the latter. In sum, resonance sticking has an important impact on the evolution of scattered TNOs, contributing significantly to the longevity of these objects.     

Precipitation chemistry and ozone and sulfate concentrations in the ocean atmosphere observed by multi-year cruising in East Asia and West Oceania (35°N–35°S, 100–135°E) in August and September

A comprehensive study on the chemistry of deposition and the concentration of tropospheric ozone and particulate sulfate in the ocean atmosphere was carried out for the data sets in 1990’s. It is important to study the atmospheric situation over the past years as well as the latest, especially in the East Asian region where emission amount of anthropogenic air pollutants have increased year by year due to rapid economic growth. The survey was conducted for 5 years in East Asia and West Oceania (35°N–35°S, 100–135°E) in August and September in 1990’s. The purpose of the survey was to study and understand the chemistry of deposition and the concentration of tropospheric ozone and particulate sulfate in the ocean atmosphere comprehensively in one project. Rainfall over the ocean was insufficiently neutralized. Gas and aerosol over the ocean were mature, i.e., well-mixed, during the period of the transportation. The characteristic latitudinal dependence was observed in the tropospheric ozone concentration, namely, higher in the southern hemisphere and lower in the northern hemisphere (approximately 25 ppb in the 10–40°S region and 5–15 ppb in the 20–40°N region). On the other hand, high concentrations of tropospheric ozone of over 30 ppb were observed in the northern hemisphere, which was attributable to the long-range transportation. The TSP concentration was approximately under the level of 40 μg m^?3 irrespectively of the latitude; in contrast, the nss-SO₄ ^2- concentration showed a clear latitudinal dependence, i.e., higher in the northern hemisphere and lower in the southern hemisphere. The background levels of the nss-SO₄ ^2- concentration were approximately 0.5 μg m^?3 in the 10–40°S region and 2–3 μg m^?3 and 4–5 μg m^?3 in the 0–20°N and 20–40°N regions, respectively.     

Pressure dependence of Néel transition in (Mg,Fe)O

Pressure dependence of Néel temperature (T _N) in (Mg_0.20Fe_0.80)O, (Mg_0.25Fe_0.75)O, and (Mg_0.30Fe_0.70)O was newly measured up to 1.14 GPa, using superconducting quantum interference device magnetometer and piston–cylinder-type pressure cell under hydrostatic condition. The dT _N/dP values of (Mg_0.20Fe_0.80)O, (Mg_0.25Fe_0.75)O, and (Mg_0.30Fe_0.70)O were determined as 4.0 ± 0.3, 2.7 ± 0.3, and 4.4 ± 0.4 K/GPa, respectively, in linear approximation; however, the T _N deviated from the linearity under nonhydrostatic conditions. The compositional dependence of dT _N/dP in (Mg_1?X Fe _X )O showed a rapid decay with increasing Mg components at X ≥ 0.75 and the trend ended at X = 0.70. The estimated Néel transition pressure at room temperature by extrapolating these linearities are very similar to the rhombohedral distortion determined by previous X-ray diffraction studies for X ≥ 0.75, which suggests that the rhombohedral phase of (Mg_1?X Fe _X )O (X ≥ 0.75) at room temperature is antiferromagnetic under hydrostatic conditions.     

Influence of Changes in Solar Radiation on Changes of Surface Temperature in China

The long-term trends of total surface solar radiation(SSR),surface diffuse radiation,and surface air temperature were analyzed in this study based on updated 48-yr data from 55 observational stations in China,and then the correlation between SSR and the diurnal temperature range(DTR) was studied.The effect of total solar radiation on surface air temperature in China was investigated on the basis of the above analyses.A strong correlation between SSR and DTR was found for the period 1961-2008 in China.The highest correlation and steepest regression line slope occurred in winter,indicating that the solar radiation effect on DTR was the largest in this season.Clouds and water vapor have strong influences on both SSR and DTR,and hence on their relationship.The largest correlations between SSR and DTR occurred in wintertime in northern China,regardless of all-day(including clear days and cloudy days) or clear-day cases.Our results also showed that radiation arriving at the surface in China decreased significantly during 1961-1989(dimming period),but began to increase during 1990-2008(brightening period),in agreement with previous global studies.The reduction of total SSR offset partially the greenhouse warming during 1961-1989.However,with the increase of SSR after 1990,this offsetting effect vanished;on the contrary,it even made a contribution to the accelerated warming.Nonetheless,the greenhouse warming still played a controlling role because of the increasing of minimum and mean surface temperatures in the whole study period of 1961-2008.We estimated that the greenhouse gases alone may have caused surface temperatures to rise by 0.31-0.46℃(10 yr) 1 during 1961-2008,which is higher than previously estimated.Analysis of the corresponding changes in total solar radiation,diffuse radiation,and total cloud cover indicated that the dimming and brightening phenomena in China were likely attributable to increases in absorptive and scattering aerosols in the atmosphere,respectively.     

XMM–Newton observations of UW CrB: detection of X-ray bursts and evidence for accretion disc evolution

UW CrB (MS 1603+2600) is a peculiar short-period X-ray binary that exhibits extraordinary optical behaviour. The shape of the optical light curve of the system changes drastically from night to night, without any changes in overall brightness. Here we report X-ray observations of UW CrB obtained with XMM–Newton . We find evidence for several X-ray bursts, confirming a neutron star primary. This considerably strengthens the case that UW CrB is an accretion disc corona system located at a distance of at least 5–7 kpc (3–5 kpc above the Galactic plane). The X-ray and Optical Monitor (ultraviolet–optical) light curves show remarkable shape variation from one observing run to another, which we suggest are due to large-scale variations in the accretion disc shape resulting from a warp that periodically obscures the optical and soft X-ray emission. This is also supported by the changes in phase-resolved X-ray spectra.     

North-south asymmetries of solar particle events in upper stratospheric ozone

Stratospheric ozone depressions, following intense solar particle events (SPE) observed by the backscattered ultraviolet (BUV) experiment on the Nimbus-4 satellite, indicate the existence of distinct asymmetries between the Northern and Southern Hemispheres. These asymmetries are observed in the magnitude of the depressions above the 5-mb level, their temporal variations, and the spatial (i.e., latitude and longitude) dependence of these variations. Possible causes of asymmetries, shown by two events on 4 August 1972 and 25 January 1971, can be attributed to: (1) tilt of the interplanetary magnetic field (IMF) with respect to the Earth's dipole magnetic field which influences the precipitation of energetic solar particles into the polar atmospheres; (2) differences in ozone chemistry caused by the large change in atmospheric temperature between summer and winter hemispheres; (3) seasonal differences of the stratosphere's dynamic states which are affected by upward propagating planetary waves in winter in contrast to the relatively undisturbed zonal flow in summer; (4) topographic asymmetry between Northern and Southern Hemispheres.These effects are shown by three-dimensional plots of the events in geographic coordinates and by color contour plots of the stratospheric ozone distributions in geomagnetic and geographic polar coordinates, respectively.