Change in tectonic force inferred from basin subsidence: Implications for the dynamical aspects of back-arc rifting in the western Mediterranean

A method has been developed that allows temporal changes in tectonic force during rift basin formation to be inferred from observed tectonic subsidence curves and has been applied to the Gulf of Lions (the Provençal Basin) and the Valencia Trough in order to gain some understanding of the dynamical aspects of back-arc basin rifting in the western Mediterranean Sea. Two distinct tectonic force regimes active at different times during the evolution of each of these back-arc basins are identified. The first, which can be seen in both basins, is characterized by tensional forces that gradually abate with time to vanish some ～ 20 my after the onset of rifting. The magnitude of tectonic force required to initiate the rifting process is significantly greater in the Valencia Trough than in the Provençal Basin. Subsequently, the dynamic development of these back-arc basins differs. In the Provençal Basin, there is a renewal of force, with extensional deformation concentrated in the central part of the rift whereas, in the Valencia Trough, the second tectonic force regime is inferred to be one that causes compression that subsequently relaxes. Such temporal patterns of tectonic force are interpreted to be related to the causative driving processes, allowing constraints to be placed on the transient interaction between the overriding and subducting plates in a back-arc setting. The models also allow inferences to be made about the rheological structure of the lithosphere. A significant variation of initial crustal thickness is inferred for the Provençal Basin but not for the Valencia Trough. In both basins, a wet rheology is required in order to initiate rifting given currently accepted bounds on tectonic force magnitudes; adoption of a dry rheology leads to insufficiently high strain rates for significant lithosphere extension in both cases.     

Estrogen equivalent concentration of individual isomer-specific 4-nonylphenol in Ariake sea water, Japan

Concentrations of 4-nonylphenol (NP) were determined by isomer-specific quantification of individual NP isomers based on relative response factor (RRF) quantification with GC–MS in combination with steam distillation extraction. Concentrations of NP in the Ariake Sea decreased with distance from the river mouth (St.A; 49 ng NP/l) to offshore areas (St.C; 11 ng NP/l). Even the least concentration in water from St.C in Ariake Sea was sufficient to have adverse effects on barnacles. The isomers, NP1–NP14 were separated by GC–PFC and identified structurally with NMR. The isomers varied in estrogenic activity with NP7 exhibiting the greatest estrogenic activity with a potency that was approximately 1.9 × 10⁻³ that of 17β-estradiol (E2) in recombinant yeast screen system. The coefficient of variation (CV) of NP isomer’s concentrations among three samples at St.A, B and C were 4–75%. This suggests that NP isomers might be independently degraded in aquatic environmental samples. The predicted estrogenic activity of measured concentrations of NP in Ariake Sea was 2.7–3.0-fold greater than the measured estrogen agonist activity.     

Iron-water reaction at high pressure and temperature, and hydrogen transport into the core

We observed a direct reaction of metallic iron with water to form iron hydride and iron oxide, 3Fe + H₂O–>2FeH_x + FeO, at pressures from 6 GPa to 84 GPa and temperatures above 1,000 K in diamond anvil cell (DAC). Iron hydride is dhcpFeH_x or -FeH_x, and iron oxide has the rhombohedral or B1 structure at pressures at least up to 37 GPa. The formation of an assembly composed of dhcpFeH_x and FeO with the B8 structure was observed at 84 GPa. In primordial Earth, water formed by dehydration of the low temperature primitive materials reacts with metallic iron in the high temperature component to form iron hydride FeH_x and iron oxide FeO. The former would be incorporated in the iron forming the core. Thus hydrogen could be an important element of the Earths core. This reaction would be essential for transport of hydrogen into the core in the accretion stage of the Earth.     

Reappearance of ordered motions in strongly nonlinear Hamiltonian systems

A strongly nonlinear Hamiltonian system which occurs in Celestial Mechanics is studied by the method of surface of section. The reappearance of ordered motions is observed and the numerical experiments suggest that this phenomenon could be predicted by the criterion of interaction of resonances.     

Effects of environmental gradients concerning water qualities on the structure of the phytoplankton community in the coastal sea

The effects on the structure of the phytoplankton community of in situ environmental gradients concerning water qualities, formed during the mixing process of coastal with oceanic waters, were investigated on macro scale over a wide area of the Seto Inland Sea, Japan.The community structure of the phytoplankton varied almost constantly along the in situ environmental gradients in the community, which was shown by use of the diversity index rather than a mere listing of the phytoplankton community. These observations were considered to be the result of the direct or indirect response of the phytoplankton community to environmental gradients which occur in situ, which mean a series of variations of the habitat of the phytoplankton community. Their effects were reflected not in biomass but in the structure of the phytoplankton community. It was difficult to establish quantitatively the extent of their effects because of the variability in the degree of the environmental gradients which occur in situ.     

Infrared properties of haze particles of Venus

The computed variation of the infrared flux and polarization of Venus as a function of phase angle, based upon multiple-scattering calculations for the cloud model of Kawabata et al. (1980) with an internal heat source, precludes the possibility of sulfuric acid as the composition of the haze particles located above the main cloud. Furthermore, our calculations reveal that the hazticle should have a large absorption coefficient at these wavelengths, i.e, $\text{k(}\text{imaginary part of the complex refractive index}\text{) ? 1.3}\text{at a wavelength}\text{λ = 3.4 μ}\text{m}$. The optical thickness of the haze layer must be about 0.15 at λ = 3.4 μm.     

Optical constants of the mixture of ices

The Maxwell-Garnett mixing rule (MG) was applied to estimate the optical constant m ^* of the mixture of ices. A fairly good agreement between the resulting values of m ^* and those of our laboratory measurements suggests that the MG rule becomes a powerful tool to derive the unknown optical constants of natural dirty-ice, when there are no chemical bonds between the guest and host materials. Our results would provide the knowledge of the optical constants of dirty-ice for studies of icy substances on the surface of satellites, cometary nucleus and interplanetary dust grains based on their reflectance spectra.     

Propagation of seismic slip from brittle to ductile crust: Evidence from pseudotachylyte of the Woodroffe thrust, central Australia

The Woodroffe thrust, central Australia, is a > 1.5-km-wide mylonitized shear zone marked by large volumes of mm- to cm-scale pseudotachylyte veins. The pseudotachylytes display typical melt-origin features, including rounded and embayed clasts, spherulitic and dentritic microlites, and flow structures within a fine-grained matrix. Three types of pseudotachylyte are identified on the basis of deformation texture, vein morphology, and host-rock lithology: cataclasite-related (C-Pt), mylonite-related (M-Pt), and ultramylonite-related (Um-Pt). The M-Pt and Um-Pt veins intrude into mylonite and ultramylonite and are themselves overprinted by subsequent mylonitization. These pseudotachylytes contain an internal foliation defined by flattened porphyroclasts and layering of the fine-grained vein matrix, and the foliation is generally oriented parallel to foliation in the surrounding mylonite and ultramylonite. These observations constrain the timing and environment of M-Pt and Um-Pt pseudotachylyte formation to a protracted period of deformation and mylonitization within the ductile regime of the crust. The M-Pt and Um-Pt veins, as well as the host mylonite, are overprinted by cataclasis and multiple generations of late-stage C-Pt veins that were generated in the brittle-dominated regime of the upper crust during uplift and exhumation of the shear zone.The coexistence of multiple generations of voluminous C-Pt, M-Pt, and Um-Pt veins indicates that the pseudotachylyte veins represent a large number of large earthquakes and accompanying seismic slip over an extended period of seismicity on the Woodroffe thrust. The timing and distribution of pseudotachylyte indicate that the earthquakes nucleated at the base of the brittle-dominated seismogenic zone and propagated down through the brittle–ductile transition into the ductile-dominated regime of the crust.     

Characterization of a landslide-triggered debris flow at a rainforest-covered mountain region in Brazil

Natural Hazards - Debris flows represent great hazard to humans due to their high destructive power. Understanding their hydrogeomorphic dynamics is fundamental in hazard assessment studies,...