Depositional processes in a kimberlite crater: the Upper Cretaceous Orapa South Pipe (Botswana)

The Orapa A/K1 Diamond Mine, Botswana, exposes the crater facies of a bilobate kimberlite pipe of Upper Cretaceous age. The South Crater consists of layered volcaniclastic deposits which unconformably cross‐cut massive volcaniclastic kimberlite of diatreme facies in the North Pipe. Based on the depositional structure, grain‐size, sorting and composition of kimberlite in the South Crater, six units are distinguished in the ～70 m thick stratiform crater‐fill sequence and talus slope deposits close to the crater wall, which represents a multistage infill of the volcanic crater. Monolithic basalt breccias (Unit 1) near the base of the crater‐fill are interpreted as rock‐fall avalanche deposits, generated by the sector collapse of the crater walls. These deposits are overlain by a basal imbricated lithic breccia and upper massive sub‐unit (Unit 2), interpreted as the deposits of a pyroclastic flow that entered the South Crater from another source. Vertical degassing structures within the massive sub‐unit show evidence for elutriation of fines and probably were formed after emplacement by fluidization due to air entrainment. Units 3 and 5 are thinly stratified deposits, characterized by diffuse bedding, reverse and normal grading, coarse lenticular beds, mudstone beds, small‐scale scour channels and load casts. These units are attributed to rapidly emplaced sheet floods on the crater floor. Units 3 and 5 are directly overlain by poorly sorted volcaniclastic kimberlite (Units 4 and 6) rich in basalt boulders, attributed to debris flows formed by the collapse of crater walls. Unit 7 comprises medium sandstones to cobble conglomerates representing talus fans, which were active throughout the deposition of Units 1 to 6. The study demonstrates that much of the material infilling the South Crater is derived externally after eruption, including primary pyroclastic flow deposits probably from another kimberlite pipe. These findings have important implications for predicting diamond grade. Results may also aid the interpretation of crater sequences of ultra‐basic, basaltic and intermediate volcanoes, together with the deposits of topographic basins in sub‐aerial settings.     

BAROQUE DISRUPTIONS IN VAL DI NOTO,SICILY*

Two earthquakes that struck Sicily nearly three centuries apart provide the basis for an interpretation of subsequent events. After the 1693 earthquake, local inhabitants rebuilt their towns in a version of baroque architecture that is unique to the region. After the 1990 quake, their descendants mounted a campaign to restore the crumbling landscapes and then, years later, to unite in opposition against an oil company that threatened the newly restored sites. Michel Serres's theory of the “parasite” informs a reading of the earthquakes and the events that followed them as agents that disrupted the flow of human‐environment relationships and produced hybridized landscapes and political alliances. In this way the Sicilian baroque is both a style of architecture and a mode of social and political mobilization.     

On the effect of moisture bonding forces in air-dry soils on threshold friction velocity of wind erosion

Wind erosion is a dominant geomorphological process in arid and semi-arid regions with major impacts on regional climate and desertification. The erosion process occurs when the wind speed exceeds a certain threshold value, which depends on a number of factors including surface soil moisture. The understanding and modelling of aeolian erosion requires a better understanding of the soil erodibility associated with different moisture conditions. In arid regions during the dry season, the atmospheric humidity plays an important role in determining the surface moisture content and the threshold shear velocity. By a series of wind tunnel tests and theoretical analyses, this dependence of threshold velocity on near surface air humidity is shown for three soils of different textures: sand, sandy loam, and clay loam. The results show that the threshold shear velocity decreases with increasing values of relative humidity for values of relative humidity between about 40% and 65%, while above and below this range the threshold shear velocity increases with air humidity. A theoretical framework is developed to explain these dependencies assuming an equilibrium between the surface soil moisture and the humidity of the overlying atmosphere. The conditions under which soil-atmosphere equilibrium occurs were tested experimentally in the laboratory for different soils in order to determine the effect of grain surface area and texture on the time required to reach equilibrium starting from different initial conditions.     

A Melt Inclusion Record of Volatiles, Trace Elements and Li-B Isotope Variations in a Single Magma System from the Plat Pays Volcanic Complex, Dominica, Lesser Antilles

Glass inclusions in plagioclase and orthopyroxene from daciticpumice of the Cabrits Dome, Plat Pays Volcanic Complex in southernDominica reveal a complexity of element behavior and Li–Bisotope variations in a single volcanic center that would gounnoticed in a whole-rock study. Inclusions and matrix glassesare high-silica rhyolite with compositions consistent with about50% fractional crystallization of the observed phenocrysts.Estimated crystallization conditions are 760–880°C,200 MPa and oxygen fugacity of FMQ + 1 to +2 log units (whereFMQ is the fayalite–magnetite–quartz buffer). Manyinclusion glasses are volatile-rich (up to 6 wt % H₂O and 2900ppm Cl), but contents range down to 1 wt % H₂O and 2000 ppmCl as a result of shallow-level degassing. Sulfur contents arelow throughout, with <350 ppm S. The trace element compositionof inclusion glasses shows enrichment in light rare earth elements(LREE; (La/Sm)_n = 2·5–6·6) and elevatedBa, Th and K contents compared with whole rocks and similaror lower Nb and heavy REE (HREE; (Gd/Yb)_n = 0·5–1·0).Lithium and boron concentrations and isotope ratios in meltinclusions are highly variable (20–60 ppm Li with ⁷Li= +4 to +15 ± 2; 60–100 ppm B with ¹¹B = +6 to+13 ± 2) and imply trapping of isotopically heterogeneous,hybrid melts. Multiple sources and processes are required toexplain these features. The mid-ocean ridge basalt (MORB)-likeHREE, Nb and Y signature reflects the parental magma(s) derivedfrom the mantle wedge. Positive Ba/Nb, B/Nb and Th/Nb correlationsin inclusion glasses indicate coupled enrichment in stronglyfluid-mobile (Ba, B) and less-mobile (Th, Nb) trace elements,which can be explained by fractional crystallization of plagioclase,orthopyroxene and Fe–Ti oxides. The ⁷Li and ¹¹B valuesare at the high end of known ranges for other island arc magmas.We attribute the high values to a ¹¹B and ⁷Li-enriched slabcomponent derived from sea-floor-altered oceanic crust and possiblyfurther enriched in heavy isotopes by dehydration fractionation.The heterogeneity of isotope ratios in the evolved, trappedmelts is attributed to shallow-level assimilation of older volcanicrocks of the Plat Pays Volcanic Complex. KEY WORDS: subduction; volcanic arcs; igneous processes; melt inclusions; SIMS; trace elements; lithium and boron isotopes; diffusion     

Dislocated Quaternary deposits in southeastern Kattegat – a glacial or gravitational phenomenon?

The Quaternary deposits in the Store Middelgrund–Rørdebanke area midway between the island of Anholt and Hallandsåsen on the Swedish coast are described on the basis of reflection seismic profiles with a vertical resolution of 5–10 m. The Quaternary rests on Upper Cretaceous limestone, the surface of which is nearly horizontal. Three Quaternary sequences are defined and interpreted as: (1) Late Weichselian marine or lacustrine deposits, (2) Late Weichselian glaciogenic deposits, and (3) Late Saalian–Eemian and Early–Middle Weichselian deposits. Sequence 3 is probably comparable to the upwards-coarsening sequence known from Skaerumhede in Vendsyssel. The layers in sequence 3 are dislocated in the eastern part of the Store Middelgrund–Rødebanke area mainly by gentle folding, but other types of deformations occur. Folding could be the result of horizontal push from an ice sheet approaching from the east. Alternatively the folding is an effect of vertical, gravitational forces acting on the sediments due to an unstable density profile, as described by the Rayleigh–Taylor instability model. The zone of deformation is located close to the northern flank of the tectonically active Sorgenfrei–Tornquist Zone. It is suggested that the initiation of the folding process was facilitated by tremors from small earthquakes.     

Holocene palaeoenvironments at the timberline in the French Alps—a multidisciplinary approach

An attempt is made to reconstruct the palaeoenvironmental Holocene history at the timberline on the basis of the analysis of various palaeoecological proxy indicators available on a marshy area and its surroundings in the Taillefer Massif (Isère. France). The multidisciplinary approach involves analyses of pollen assemblages. plant macrofossils, coleoptera remains. subfossil trunks extracted from lakes or peat-bogs. and charcoals derived from the surrounding soils. This enables definition of the respective roles of five forest taxa ( Pinus uncinata Mill., Pinus cembra L., Larix decidua Mill., Abies alba Mill, and Picea abies L. Karsten) in the evolution of high altitude forests during the Holocene. Pinus uncinata was present on the plateau throughout the Holocene. Larix and Pinus cembra were present only during two periods: 7500-5000 BP and 3500-2000 BP. All trees disappeared from the plateau at about 2000 BP, while, at lower altitude. Abies was replaced by Picea. The action of both climate and early human impact can explain these changes.     

Low-Temperature, Low-Pressure Metamorphism of Mn-rich Rocks in the Lienne Syncline, Venn--Stavelot Massif (Belgian Ardennes), and the Role of Carpholite

Low-grade Mn-rich metamorphic rocks of the Lienne syncline (westernpart of the Venn–Stavelot Massif, Belgian Ardennes) havebeen re-examined to evaluate the petrological significance ofcarpholite proper, Mn^2$ Al₂[Si₂O₆](OH)₄. Metamorphic P–Tconditions of these rocks are estimated to be {small tilde}300C1–2 kbar, which is in accordance with the exclusive occurrenceof carpholite in low-P rocks such as hydrothermal environmentselsewhere. Carpholite of the Lienne syncline exclusively occursin quartz-rich segregations. Its composition is close to end-member.Thermodynamic calculations confirm that carpholite is a stablephase at low-pressure–low-temperature conditions, in contrastto ferro- and magnesiocarpholite, which are high-pressure minerals.No information is available on the high-P behaviour of carpholite.The occurrence of carpholite is partly closely associated withspessartine-bearing country rocks, or carpholite is alteredto assemblages with spessartine, sudoite, chlorite, muscoviteand paragonite. Spessartine in these rocks contains minor amountsof hydrogarnet component {(H/4)/[Si$(H/4)] = 0.03–0.06}.The presence of carpholite-spessartine assemblages in theselow-P rocks is in contrast to high-pressure metamorphic rocksfrom other areas, where parageneses such as fem/magnesiocarpholite–chloritoidor magnesiocarpholite–chlorite–kyanite occur. Theappearance of carpholite–garnet assemblages in low-P Mn-richrocks can be explained by contrasting phase relations becauseof a high Mn–Mg partition coefficient between the mineralsunder consideration. In rhodo-chrosite-bearing veins in theLienne syncline, nearly complete replacement of carpholite byspessartine and chlorite is due to the continuous reaction carpholite$ rhodochrosite $ quartz = spessartine $ chlorite $ H₂O $ CO₂,which defines a very low X_co, in the temperature range underconsideration. It is suggested that spessartine (possibly containingsome hydrogarnet component), during prograde metamorphism atlow pressure, becomes stable at a temperature of {small tilde}300C KEY WORDS: carpholite; spessartine; sudoite; Venn–Stavelot Massif; Ardemes ^*Corresponding author. Fax: x49/531/3918131. e-mail: t.theye{at}tu.bs.de     

Weathering and polymerization of tektites: An x-ray photoelectron spectroscopy (XPS) investigation

Abstract— Tektites are natural glasses formed from terrestrial material that was melted and displaced by the impact of an extraterrestrial body. The surface and near-surface compositions of tektite glass results from fractionation during impact and ejection, and/or postsolidification weathering. The first goal of this study was to characterise the surface and near-surface (in the order of tens of angstroms) chemical composition of two tektites by x-ray photoelectron spectroscopy (XPS), and to estimate the importance of weathering vs. fractionation during flying. In order to separate the chemical modification due to weathering from that due to fractionation during ballistic flight, we studied two samples from the Australasian tektite strewn field. One of them was collected in a hot desert area (Nullarbor Plain, Australia) and the other, in a humid climate (Thailand). Our study reveals the presence of well-developed leached layers in both tektites. In the Australian tektite, Si is depleted in the topmost layers (a few tens of angstroms). A more complex chemical zoning is defined in the tektite from Thailand. These leached layers are comparable to those observed in weathered glasses, and therefore we conclude that weathering is responsible for the chemical composition of the surface and near-surface compositions. The second goal was to investigate the chemical environment of O, N and C in the glass. The O peak was resolved into two bridging O components (Si-O-Si and Al-O-Si) that are comparable to O environments in artificial glasses. The binding energy of the C_1s electron is typical for C-C and C-H bonds in hydrocarbons; minor organic acid components are also present. Nitrogen is only observed on the surface of the Thailand tektite. The binding energy of N_1s is comparable to that of ammonia, and the surface enrichment in N is interpreted as due to sorption related to interactions between glass and fluid buffered by the organic material in the soil.