RECENT TRENDS IN TREE-RING RECORDS FROM HIGH ELEVATION SITES IN THE ANDES OF NORTHERN PATAGONIA

A new set of tree-ring records from the Andes of northern Patagonia, Argentina (41° S) was used to evaluate recent (i.e., last 250 years) regional trends in tree growth at upper treeline. Fifteen tree-ring chronologies from 1200 to 1750 m elevation were developed for Nothofagus pumilio, the dominant subalpine species. Samples were collected along three elevational transects located along the steep west-to-east precipitation gradient from the main Cordillera (mean annual precipitation >4000 mm) to an eastern outlier of the Andes (mean annual precipitation >2000 mm). Ring-width variation in higher elevation tree-ring records from the main Cordillera is mainly related to changes in temperature and precipitation during spring and summer. However, the response to climatic variation is also influenced by local site factors of elevation and exposure. Based on the relationships between Nothofagus growth and climate, we reconstructed changes in snow cover duration in late spring and variations in mean annual temperature since A.D. 1750. Abrupt interannual changes in the mean annual temperature reconstruction are associated with strong to very strong El Niño-Southern Oscillation events. At upper treeline, tree growth since 1977 has been anomalously high. A sharp rise in global average tropospheric temperatures has been recorded since the mid-1970s in response to an enhanced tropical hydrologic cycle due to an increase in temperature of the tropical Pacific. Temperatures in northern Patagonia have been anomalously high throughout the 1980s, which is consistent with positive temperature anomalies in the tropical Pacific and along the western coast of the Americas at c.a. 40° S latitude. Our 250-year temperature reconstruction indicates that although the persistently high temperatures of the 1980s are uncommon during this period, they are not unprecedented. Tropical climatic episodes similar to that observed during the 1980s may have occurred in the recent past under pre-industrial carbon dioxide levels.     

Saharan dust absorption and refractive index from aircraft-based observations during SAMUM 2006

During the Saharan Mineral Dust Experiment (SAMUM) conducted in summer 2006 in southeast Morocco, the complex refractive index of desert dust was determined from airborne measurements of particle size distributions and aerosol absorption coefficients at three different wavelengths in the blue (467 nm), green (530 nm) and red (660 nm) spectral regions. The vertical structure of the dust layers was analysed by an airborne high spectral resolution lidar (HSRL). The origin of the investigated dust layers was estimated from trajectory analyses, combined with Meteosat 2nd Generation (MSG) scenes and wind field data analyses. The real part n of the dust refractive index was found almost constant with values between 1.55 and 1.56, independent of the wavelength. The values of the imaginary part k varied between the blue and red spectral regions by a factor of three to ten depending on the dust source region. Absolute values of k ranged from 3.1 × 10⁻³ to 5.2 × 10⁻³ at 450 nm and from 0.3 × 10⁻³ to 2.5 × 10⁻³ at 700 nm. Groupings of k values could be attributed to different source regions.     

Pyrite geochemistry in the Toarcian Posidonia Shale of south‐west Germany: Evidence for contrasting trace‐element patterns of diagenetic and syngenetic pyrites

Authigenic pyrite grains from a section of the Lower Toarcian Posidonia Shale were analysed for their trace‐element contents and sulphur‐isotope compositions. The resulting data are used to evaluate the relationship between depositional conditions and pyrite trace‐element composition. By using factor analysis, trace‐elements in pyrite may be assigned to four groups: (i) heavy metals (including Cu, Ni, Co, Pb, Bi and Tl); (ii) oxyanionic elements (As, Mo and Sb); (iii) elements partitioned in sub‐microscopic sphalerite inclusions (Zn and Cd); and (iv) elements related to organic or silicate impurities (Ga and V). Results indicate that trace‐element contents in pyrite depend on the site and mechanism of pyrite formation, with characteristic features being observed for diagenetic and syngenetic pyrites. Diagenetic pyrite formed within anoxic sediments generally has a high heavy metals content, and the degree of pyritization of these elements increases with increasing oxygen deficiency, similar to the degree of pyritization of reactive Fe. The highest gradient in the increase of the degree of trace element pyritization with bottom‐water oxygenation was found for the elements Ni < Cu < Mo = As < Tl. In contrast, syngenetic pyrite formed within a euxinic water column typically is enriched in As, Mo and Sb, but is low in heavy metals, and the geochemical variation reflects changes in sea water composition.