Thermodynamic characteristics of water in natural water bodies with a high mineralization

To adequately describe the hydrophysical processes in water bodies with a high mineralization, it is necessary to take into account the dependence that the thermodynamic characteristics of water have on the amount of salts contained in it. This work investigates some widely known formulas for calculating a number of thermodynamic parameters of mineralized water. The density, freezing temperature, specific heat of evaporation, and relative pressure of saturated vapor over the surface are considered. The possibilities of using these formulas when modeling hydrophysical processes in water bodies with salinity in the range of 0–250 pro mille are analyzed. It is shown that the formulas under consideration should be used when the salinity does not exceed 100 pro mille. If the mineralization is higher, it is necessary to elaborate more suitable formulas on the basis of an approximation of in situ data or data from handbooks.     

Analogue study of particle segregation in pyroclastic density currents, with implications for the emplacement mechanisms of large ignimbrites

Abstract Analogue flume experiments were conducted to investigate the transport and sedimentation behaviour of turbulent pyroclastic density currents. The experimental currents were scaled approximately to the natural environment in three ways: (1) they were fully turbulent; (2) they had a very wide range of particle sizes and associated Rouse numbers (the ratio of particle settling velocity to effective turbulent eddy velocity in the current); and (3) they contained particles of two different densities. Two sets of surge‐type experiments were conducted in a 5 m long, water‐filled lock‐exchange flume at five different volumetric particle concentrations from 0·6% to 23%. In one set (one‐component experiments), the currents contained just dense particles; in the other set (two‐component experiments), they contained both light and dense particles in equal volume proportions. In both sets of experiments, the population of each component had a log‐normal size distribution. In the two‐component experiments, the size range of the light particle population was selected in order to be in hydrodynamic equivalence with that of the dense particles. Dense particles were normally graded, both vertically and downstream, in the deposits from both sets of experiments. The mass loading (normalized to the initial mass of the suspension) and grain size of the dense component in the deposits decreased with distance from the reservoir and were insensitive to initial total particle concentration in the currents. On the other hand, in the two‐component experiments, the light particles were extremely sensitive to concentration. They were deposited in hydrodynamic equivalence with the dense particles from dilute currents, but were segregated efficiently at concentrations higher than a few per cent. With increasing particle concentration, the large, light particles were carried progressively further down the flume because of buoyancy effects. Deposits from the high‐concentration currents exhibited reverse vertical grading of the large, light particles. Efficient segregation of the light component was observed even if the bulk density of the current was less than that of the light particles. In both sets of experiments, marked inflexions in the rate of downstream decline in mass loading and maximum grain size of the dense component can be attributed to the presence of two different particle settling regimes in the flow: (1) particles with Rouse numbers >2·5, which did not respond to the turbulence and settled rapidly; and (2) particles with Rouse numbers <2·5, which followed the turbulent eddies and settled slowly. The results are applied to the transport and sedimentation dynamics of pyroclastic density currents that generate large, widespread ignimbrites. Field data fail to reveal significant departures from aerodynamic equivalence between pumice and lithic clasts in three such ignimbrites: the particulate loads of some large ignimbrites are transported principally in turbulent suspensions of low concentration. In some ignimbrites, the well‐developed inflexions in curves of maximum lithic (ML) size vs. distance can be attributed to the existence of distinct high and low Rouse number particle settling regimes that mark the transition from an overcharged state to one in which the residual particulate load is transported more effectively by turbulence.     

On the causes of 18O-depletion and 18O/16O homogenization during regional metamorphism; the East Humboldt Range core complex,Nevada

 Previous stable isotope studies at Lizzies Basin revealed that metasedimentary rocks are ¹⁸O-depleted relative to protolith values, particularly in the lower parts of the section (Lower Zone) where the rocks are also isotopically homogeneous on a scale of hundreds of meters (quartz δ¹⁸O=+9.0 to +9.6 per mil). In contrast, metasedimentary rocks at higher levels at Lizzies Basin (Upper Zone) are less ¹⁸O-depleted and more heterogeneous in δ¹⁸O. In order to understand more fully the isotopic evolution of this terrane, a series of detailed, meter-scale traverses across various metamorphic and igneous lithologies were completed at Lizzies Basin, and at the structurally higher Angel Lake locality. Traverses in the Lizzies Basin Lower Zone and in the lower parts of Angel Lake (Angel Lake Lower Sequence) across various silicate lithologies, including abundant granitoids, reveal similar degrees of homogeneity, although the average δ¹⁸O values are higher at Angel Lake. In contrast, traverses which include substantial thicknesses of marble and calc-silicate gneiss and very little granitoid have more heterogeneous quartz δ¹⁸O values (+11.9 to +13.4 per mil), and also have a higher average δ¹⁸O (+12.9 per mil), than observed elsewhere. The scale of ¹⁸O/¹⁶O homogeneity in quartz observed at Lizzies Basin and Angel Lake (meters to hundreds of meters) requires fluid-mediated isotope exchange, which accompanied Tertiary metamorphism. There is a correlation between the degree of ¹⁸O-depletion in metasedimentary rocks, ¹⁸O/¹⁶O homogenization between lithologies, and the proportion of granitoids (leucogranites in particular) within any part of the section, and a corresponding anticorrelation with the proportion of marble. This points to a causal relationship, whereby the leucogranites (as well as the Tertiary hornblende diorite and biotite monzogranite) acted as both a relatively low-¹⁸O reservoir and a source of fluids to enhance exchange, while the marbles hindered isotope depletion and homogenization by acting as relatively high-¹⁸O reservoirs and impermeable layers. Material balance calculations help delineate the plausible mechanisms of exchange between granitoids and metasediments. Single-pass infiltration of magmatic fluids from the granitoids is not capable of reproducing all of the observations. Fluid-mediated exchange by convective recirculation of magmatic fluids on a scale of meters is the mechanism which explains all of the observations. The generalized model for the isotopic evolution of the East Humboldt Range core complex provides an excellent opportunity to establish the main causes and controlling factors of ¹⁸O-depletion and ¹⁸O/¹⁶O homogenization during regional metamorphism. Received: 27 July 1993 / Accepted: 1 July 1994     

The Pangean ice age: studies with a coupled climate-ice sheet model

 Application of an ice sheet model developed for the Pleistocene to the extensive Carboniferous glaciation on Gondwana yields an ice sheet which has several features consistent with observations. While complete deglaciation is not achieved without CO₂ changes, the Milankovich-induced fluctuations in ice sheet volume are comparable to Pleistocene glacial/ interglacial signals. This result is shown to hold for a large fraction of physically reasonable parameter space. The model also exhibits multiple equilibria and sharp bifurcations, as infinitesimal changes in the solar constant or precipitation can lead to a qualitatively different climate. The success of the model in predicting ice location in an environment quite different from the Pleistocene provides additional support for the robustness of the basic model physics and suggests that the model can be applied with some confidence to other pre-Pleistocene glaciations. Received: 30 June 1998 / Accepted: 5 January 1999     

不同温压条件下蛇纹岩和角闪岩中波速与衰减的各向异性

在实验室中研究了蛇纹岩和角闪岩样品在不同温压条件下的纵、横波速度和Q值．这两种岩样对应的主要组成矿物叶蛇纹石和普通角闪石都具有很强的晶格优选方位（LPO）．随着围压的增加,波速和Q值均增大,但是在相互正交的三个方向上（垂直或平行于层理面及线理方向）增大的速度并不相同,这与微裂隙的逐渐闭合密切相关．在600MPa的围压下升高温度直到600℃以上,由于微裂隙的热扩张受到约束,波速和Q值下降幅度很小．观测到的波速和Q值的各向异性具有不同的机理,波速各向异性主要与定向分布的微裂隙和主要矿物的LPO等构造因素有关;高围压下纵波Q值各向异性与速度各向异性正好相反,可能是由于形成层理面的定向排列的平板状矿物晶体沿不同方向边界之间接触程度不同造成的．     

Chemical classification of iron meteorites—VIII. Groups IC. IIE,IIIF and 97 other irons

Concentrations of Ni, Ga, Ge and Ir in 106 iron meteorites are reported. Three new groups are defined: IC, IIE and IIIF containing 10, 12 and 5 members, respectively, raising the number of independent groups to 12. Group IC is a cohenite-rich group distantly related to IA. Group IIE consists of those irons previously designated Weekeroo Station type and five others having similar compositions though diverse structures. The IIE irons are compositionally similar to the mesosiderites and pallasites, and the three groups probably formed at similar heliocentric distances. The mixing of the globular IIE silicates with the metal probably occurred during shock events. Group IIIF is a well-defined group of low-Ni and low-Ge irons. The compositions of these groups are summarized as follows:

     

917.

Low-resolution spectra of the Io plasma torus 2 days after the Ulysses encounter     

H. Rauer  T. Bonev  K. Jockers  N. Thomas 《Planetary and Space Science》1993,41(11-12)

Low-resolution spectra of the Io plasma torus have been obtained on 10 and 11 February 1992 (2 days after the Ulysses encounter) using the 2 m telescope of the Bulgarian National Observatory. The spectra show the forbidden line emissions of S⁺ (λλ 6716, 6731 Å) and S²⁺ (λ 6312 Å). Measured intensities are compared with a Voyager-type model. The intensity distribution of [SII] is found to deviate from the model predictions which indicates a change in the torus at the Ulysses encounter when compared with the Voyager epoch. A corotating structure was observed, both in [SII] and [SIII], at λ_III = 170°, showing that the torus was not azimuthally symmetric. The λ 6716/λ 6731 and λ 6731/ λ 6312 line ratios indicate a higher electron density at the time of the Ulysses observations. Additionally, the shift of the torus caused by the dawn-dusk electric field could be observed. Peak intensities in [SII] were found at 5.66 ± 0.02 R_J on the West ansa and 5.91 ± 0.04 R_J on the East.     

918.

Assessment of village-wise groundwater draft for irrigation: a field-based study in hard-rock aquifers of central India     

R. K. Ray  T. H. Syed  Dipankar Saha  B. C. Sarkar  A. K. Patre 《Hydrogeology Journal》2017,25(8):2513-2525

Extracted groundwater, 90% of which is used for irrigated agriculture, is central to the socio-economic development of India. A lack of regulation or implementation of regulations, alongside unrecorded extraction, often leads to over exploitation of large-scale common-pool resources like groundwater. Inevitably, management of groundwater extraction (draft) for irrigation is critical for sustainability of aquifers and the society at large. However, existing assessments of groundwater draft, which are mostly available at large spatial scales, are inadequate for managing groundwater resources that are primarily exploited by stakeholders at much finer scales. This study presents an estimate, projection and analysis of fine-scale groundwater draft in the Seonath-Kharun interfluve of central India. Using field surveys of instantaneous discharge from irrigation wells and boreholes, annual groundwater draft for irrigation in this area is estimated to be 212 × 10⁶ m³, most of which (89%) is withdrawn during non-monsoon season. However, the density of wells/boreholes, and consequent extraction of groundwater, is controlled by the existing hydrogeological conditions. Based on trends in the number of abstraction structures (1982–2011), groundwater draft for the year 2020 is projected to be approximately 307 × 10⁶ m³; hence, groundwater draft for irrigation in the study area is predicted to increase by ～44% within a span of 8 years. Central to the work presented here is the approach for estimation and prediction of groundwater draft at finer scales, which can be extended to critical groundwater zones of the country.     

919.

Continental break-up and collision in the Neoproterozoic and Palaeozoic — A tale of Baltica and Laurentia     

T.H. Torsvik  M.A. Smethurst  J.G. Meert  R. Van der Voo  W.S. McKerrow  M.D. Brasier  B.A. Sturt  H.J. Walderhaug 《Earth》1996,40(3-4):229-258

     

920.

Geoarchaeological evidence on a Late Bronze Age earthquake,Ohrid Basin (North Macedonia)     

J. Hošek  M. Verčík  P. Pokorný  J. Beneš  V. Komárková  T. Radoměřský  N. Atanasoska  V. Todoroska  P. Ardjanliev 《第四纪科学杂志》2021,36(6):1003-1012

Geoarchaeological investigations on the northeastern shore of Lake Ohrid revealed 3.5 m thick deepwater lacustrine sediments overlying terrestrial vegetation macrofossils, worked wood and abundant potsherds dated to the Late Bronze Age (LBA). Distinct contact of deepwater sediment with the sub-aerial weathered limestone bedrock point to a sudden increase in lake level. According to radiocarbon data, catastrophic flooding occurred shortly after 1214 yr bc. Because the area is located in a highly active seismic zone, we propose that this event was caused by tectonically induced, metre-scale coseismic subsidence related to faults bordering the Ohrid alluvial plain. Moreover, this event coincides well with a dramatic switch in the habitation and settlement strategy in the region. More important, however, is the finding that the age of the proposed massive tectonic event and change in habitation lies within the interval of the proposed ‘earthquake storm’ in the eastern Mediterranean dated to 1225–1175 bc. As the Ohrid-Korça zone belongs to the same tectonic province, a relationship between the abovementioned earthquakes and the proposed event can be expected. This research therefore might provide the first direct evidence of a large-scale earthquake event linkable to the LBA collapse of Europe's first urban civilisation in the Aegean.     

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Group	Ni (%)	Ga (ppm)	Ge (ppm)	Ir (ppm)
IC	6.1–6.8	42–54	85–250	0.07–10
IIE	7.5–9.7	21–28	62–75	0.5–8
IIIF	6.8–7.8	6.3–7.2	0.7–1.1	1.3–7.9

Low-resolution spectra of the Io plasma torus 2 days after the Ulysses encounter

Low-resolution spectra of the Io plasma torus have been obtained on 10 and 11 February 1992 (2 days after the Ulysses encounter) using the 2 m telescope of the Bulgarian National Observatory. The spectra show the forbidden line emissions of S⁺ (λλ 6716, 6731 Å) and S²⁺ (λ 6312 Å). Measured intensities are compared with a Voyager-type model. The intensity distribution of [SII] is found to deviate from the model predictions which indicates a change in the torus at the Ulysses encounter when compared with the Voyager epoch. A corotating structure was observed, both in [SII] and [SIII], at λ_III = 170°, showing that the torus was not azimuthally symmetric. The λ 6716/λ 6731 and λ 6731/ λ 6312 line ratios indicate a higher electron density at the time of the Ulysses observations. Additionally, the shift of the torus caused by the dawn-dusk electric field could be observed. Peak intensities in [SII] were found at 5.66 ± 0.02 R_J on the West ansa and 5.91 ± 0.04 R_J on the East.     

Assessment of village-wise groundwater draft for irrigation: a field-based study in hard-rock aquifers of central India

Extracted groundwater, 90% of which is used for irrigated agriculture, is central to the socio-economic development of India. A lack of regulation or implementation of regulations, alongside unrecorded extraction, often leads to over exploitation of large-scale common-pool resources like groundwater. Inevitably, management of groundwater extraction (draft) for irrigation is critical for sustainability of aquifers and the society at large. However, existing assessments of groundwater draft, which are mostly available at large spatial scales, are inadequate for managing groundwater resources that are primarily exploited by stakeholders at much finer scales. This study presents an estimate, projection and analysis of fine-scale groundwater draft in the Seonath-Kharun interfluve of central India. Using field surveys of instantaneous discharge from irrigation wells and boreholes, annual groundwater draft for irrigation in this area is estimated to be 212 × 10⁶ m³, most of which (89%) is withdrawn during non-monsoon season. However, the density of wells/boreholes, and consequent extraction of groundwater, is controlled by the existing hydrogeological conditions. Based on trends in the number of abstraction structures (1982–2011), groundwater draft for the year 2020 is projected to be approximately 307 × 10⁶ m³; hence, groundwater draft for irrigation in the study area is predicted to increase by ～44% within a span of 8 years. Central to the work presented here is the approach for estimation and prediction of groundwater draft at finer scales, which can be extended to critical groundwater zones of the country.     

Geoarchaeological evidence on a Late Bronze Age earthquake,Ohrid Basin (North Macedonia)

Geoarchaeological investigations on the northeastern shore of Lake Ohrid revealed 3.5 m thick deepwater lacustrine sediments overlying terrestrial vegetation macrofossils, worked wood and abundant potsherds dated to the Late Bronze Age (LBA). Distinct contact of deepwater sediment with the sub-aerial weathered limestone bedrock point to a sudden increase in lake level. According to radiocarbon data, catastrophic flooding occurred shortly after 1214 yr bc. Because the area is located in a highly active seismic zone, we propose that this event was caused by tectonically induced, metre-scale coseismic subsidence related to faults bordering the Ohrid alluvial plain. Moreover, this event coincides well with a dramatic switch in the habitation and settlement strategy in the region. More important, however, is the finding that the age of the proposed massive tectonic event and change in habitation lies within the interval of the proposed ‘earthquake storm’ in the eastern Mediterranean dated to 1225–1175 bc. As the Ohrid-Korça zone belongs to the same tectonic province, a relationship between the abovementioned earthquakes and the proposed event can be expected. This research therefore might provide the first direct evidence of a large-scale earthquake event linkable to the LBA collapse of Europe's first urban civilisation in the Aegean.