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961.
962.
Amphiboles were synthesized from bulk compositions prepared along the join Ca1.8Mg5.2Si8O22(OH)2–Ca1.8Mg3Ga4Si6O22(OH)2 hydrothermally at 750–850 °C and 1.0–1.8 GPa, and along the join Ca2Mg5Si8O22F2–Ca2Mg3Ga4Si6O22F2, anhydrously at 1000 °C and 0.7 GPa to document how closely the tschermak-type substitution is obeyed in these analogues
of aluminous amphiboles. Electron-microprobe analyses and Rietveld X-ray diffraction structure refinements were performed
to determine cation site occupancies. The extent of Ga substitution was found to be limited in both joins, but with the fluorine
series having about twice the Ga content (0.6 atoms per formula unit, apfu) of the hydroxyl-series amphiboles (0.3 apfu).
The tschermak-type substitution was followed very closely in the hydroxyl series with essentially equal partitioning of Ga
between tetrahedral and octahedral sites. The fluorine-series amphiboles deviated significantly from the tschermak-type substitution
and, instead, appeared to follow a substitution that is close to a Ca-pargasite substitution of the type: [6]Ga3++2[4]Ga3++1/2[A] Ca2+ = [6]Mg2++2[4]Si4++1/2[A]□. Infrared spectroscopy revealed an inverse correlation between the intensity of the OH-stretching bands and the Ga content
for the hydroxyl- and fluorine-series amphiboles. The direct correlation between the Ga and F content and inverse relationship between the Ga and
OH content may be a general phenomenon present in other minerals and suggests, for example, that high F contents in titanite
are controlled by the Al content of the host rock and that there may be similar direct Al–F correlations in tschermakitic
amphiboles. Evidence for the possibility that Al (Ga) might substitute onto only a subset of the tetrahedral sites in tschermakitic
amphiboles was sought but not observed in this study.
Received: 5 March 2001 / Accepted: 31 July 2001 相似文献
963.
We have investigated a well-ordered sample of natural Cr-bearing dickite from Nowa Ruda (Lower Silesia, Poland) using electron
paramagnetic resonance (EPR) at X- and Q-band frequencies (9.42 and 33.97 GHz, respectively) and optical diffuse reflectance
spectroscopy. The observation of the spin-forbidden transitions at 15500 and 14690 cm−1 allows us to unambiguously identify the major contribution of octahedrally coordinated Cr3+ ions in the optical spectrum. The X- and Q-band EPR spectra show two superposed Cr3+ signals. The corresponding fine-structure parameters were determined at room temperature and 145 K. These results suggest
the substitution of Cr3+ for Al3+ in equal proportions in the two unequivalent octahedral sites of the dickite structure. In kaolin group minerals, the distortion
around Cr3+ ions (λ≈ 0.2–0.4) in Al sites is significantly less rhombic than that observed around Fe3+ ions (λ≈ 0.6–0.8).
Received: 29 June 2001 / Accepted: 22 October 2001 相似文献
964.
I. E. Paukov N. K. Moroz Yu. A. Kovalevskaya I. A. Belitsky 《Physics and Chemistry of Minerals》2002,29(4):300-306
The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured
in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented
with the formula (Na1.90K0.22Ca0.06)[Al2.24Si2.76O10]·nH2O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function)
have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K−1 mol−1 for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K−1 mol−1 for tetranatrolite.
Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework
cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two
extraframework cations per formula yields: C
p
(298.15)=359.1 J K−1 mol−1, S(298.15) −S(0)=362.8 J K−1 mol−1. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral
atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated
zeolite may become unstable at temperatures above 200 K.
Received: 30 July 2001 / Accepted: 15 November 2001 相似文献
965.
A three-dimensional parametric study of the use of soil nails for stabilising tunnel faces 总被引:4,自引:0,他引:4
Applying an effective nailing system at a tunnel heading, not only improves the stability of the tunnel heading and limits deformation at the tunnel face, but it also reduces volume loss during excavation and hence reduces ground surface settlement. The effectiveness of a soil nail system is affected by many factors such as the diameter and stiffness of the nails. In this paper, a systematic parametric study was conducted to study the axial rigidity of a nail, EnAn, for improving the stability of tunnel headings and reducing ground movements in stiff clay. The parametric study involved a series of three-dimensional elasto-plastic coupled-consolidation finite element analyses. The stability of the tunnel face is improved with increasing EnAn. For a given nail density applied at the tunnel face, an optimum axial rigidity of the nail (EnAn)opt can be identified. The efficiency of the nailing system diminishes when (EnAn)opt is reached. The use of a soil nailing system reduces the magnitude of stress relief at the tunnel heading during excavation. Thus, this reduction of stress relief minimises the amount of soil yielding and excess pore water pressure generated in the soil around the tunnel heading. 相似文献
966.
967.
968.
A. K. Varma R. M. Gairola A. K. Mathur B. S. Gohil Vijay K. Agarwal 《Journal of Earth System Science》2002,111(3):247-256
In this paper, MSMR geophysical products like Integrated Water Vapour (IWV), Ocean Surface Wind Speed (OWS) and Cloud Liquid
Water (CLW) in different grids of 50, 75 and 150 kms are compared with similar products available from other satellites like
DMSP-SSM/I and TRMMTMI. MSMR derived IWV, OWS and CLW compare well with SSM/I and TMI finished products. Comparison of MSMR
derived CLW with that derived from TMI and SSM/I is relatively in less agreement. This is possibly due to the use of 37 GHz
in SSM/I and TMI that is highly sensitive to CLW, while 37 GHz channels are not available on MSMR. Monthly comparison of MSMR
geophysical products with those from TMI is all carried out for climatological purpose. The monthly comparisons were much
better compared to instantaneous comparisons. In this paper, details of the data analysis and comparison results are presented.
The usefulness of the MSMR vis-à-vis other sensors is also discussed. 相似文献
969.
Hydraulic Characteristics of Rough Fractures in Linear Flow under Normal and Shear Load 总被引:19,自引:3,他引:19
Summary
A hydro-mechanical testing system, which is capable of measuring both the flow rates and the normal and shear displacement
of a rock fracture, was built to investigate the hydraulic behaviour of rough tension fractures. Laboratory hydraulic tests
in linear flow were conducted on rough rock fractures, artificially created using a splitter under various normal and shear
loading. Prior to the tests, aperture distributions were determined by measuring the topography of upper and lower fracture
surfaces using a laser profilometer. Experimental variograms of the initial aperture distributions were classified into four
groups of geostatistical model, though the overall experimental variograms could be well fitted to the exponential model.
The permeability of the rough rock fractures decayed exponentially with respect to the normal stress increase up to 5 MPa.
Hydraulic behaviours during monotonic shear loading were significantly affected by the dilation occurring until the shear
stress reached the peak strength. With the further dilation, the permeability of the rough fracture specimens increased more.
However, beyond shear displacement of about 7 to 8 mm, permeability gradually reached a maximum threshold value. The combined
effects of both asperity degradation and gouge production, which prohibited the subsequent enlargement of mean fracture aperture,
mainly caused this phenomenon. Permeability changes during cyclic shear loading showed somewhat irregular variations, especially
after the first shear loading cycle, due to the complex interaction from asperity degradations and production of gouge materials.
The relation between hydraulic and mechanical apertures was analyzed to investigate the valid range of mechanical apertures
to be applied to the cubic law.
Received June 12, 2001; accepted February 26, 2002 Published online September 2, 2002 相似文献
970.