Preliminary attempt to characterize the rotation of seafloor in the Pito Deep area of the Easter Microplate using a submersible magnetometer

Several mechanisms have been proposed to account for the rotation of the nearly north-south abyssal hill fabric formed on the East Pacific Rise north of the Easter Microplate to the nearly east-west trends in the northern microplate interior. Proposed mechanisms include rigid microplate rotation, transform fault – parallel shear, and bookshelf faulting during the transfer of lithosphere from the Nazca Plate to the microplate. We used a submersible magnetometer on a NAUTILE dive program to measure the magnetic vector rotation of a pillow basalt and dike spur near Pito Deep, the present location of the tip of the propagating rift system that created the microplate. Our results, although too limited to draw strong conclusions from, suggest clockwise rotations of the seafloor magnetic vectors inconsistent with the transform-parallel shear model, and larger than can be explained solely by rigid microplate rotation.     

Invertebrates in the trophic webs of the white sea near-shore ecosystem (using the example of Gryaznaya Inlet)

In the food clods of the mass species of macrobenthos of the Gryaznaya Inlet, nonstructured matter plays a great role. We identify this matter as derivates from plant tissues, which are the products of their external metabolism and degradation, with associated microorganisms. This way, the near-shore community considered is supported by a detrital trophic web. This feature distinguishes it from the similar community of the near-Atlantic waters that is based on a pasture web, at least as far as the bivalve mass species are concerned. The groups of the near-shore species of Gryaznaya Inlet separated by a cluster analysis are identified as consortia, combined by the biogeochemical conditions (edifice factor), which can hardly be analyzed at present.     

Evolution of oceanographic conditions off Baja California: 1997–1999

This paper examines the oceanic response off Baja California, Mexico, to the 1997–1998 El Niño and the transition to La Niña conditions. The data presented were gathered during seven cruises over a grid based on the CalCOFI station plan, from lines 100–130, out to station 80. T–S diagrams with data obtained during the peak phase of El Niño, demonstrate that warmer and saltier (spicier) than normal conditions prevailed in the upper 600 m over this region. Temperature and salinity anomalies calculated for CalCOFI line 120 revealed waters near the coast at 50 m depth to be up to 8.7 °C warmer and S=0.8 saltier than the climatology during October 1997. These large anomalies persisted through January 1998, with some slight diminution in the magnitudes near the surface. This study suggests that anomalously warm and salty waters were fed from a source of spicy water to the southwest, identified as Subtropical Surface Water (StSW), and that low-salinity Tropical surface waters (TSW) were blocked to the southeast in the vicinity of the tip of the Peninsula. Subsurface waters associated with the California undercurrent (CU), fed from the Eastern Tropical Pacific (ETP), were also warmer and saltier than normal, and indicate a significant expansion in volume of the CU, presumably a result of intensification of poleward flow at depth. We postulate that the well defined near-surface and deep poleward flows in the study area reflect anomalous large-scale cyclonic circulation affecting the flow in the southeastern region of the North Pacific subtropical gyre east of 125°W. Following the El Niño event, warm and salty upper waters retreated to latitudes south of Punta Eugenia. With the return to normal and cooler conditions, equatorward flow over the sampling grid predominated with an increased meandering and mesoscale activity. Transition to La Niña conditions would have been associated with re-establishment of normal anticyclonic flow in the southeastern quadrant of the Pacific subtropical gyre.     

Observations of the countercurrent on the inshore side of the Kuroshio northeast of Taiwan

Intensive current measurements in the area northeast of Taiwan indicate subsurface, southwestward flow existed between the inshore edge of the Kuroshio and the East China Sea continental slope. At 70 km away from Taiwan, this countercurrent has a mean speed about 30 cm s^–1 at mid-depth. Closer to Taiwan, the flow turns along with the topography, and subjects to sidewall and bottom friction. Both the magnitude and the vertical shear of this countercurrent are comparable with that inferred from hydrographic survey. The wind field features short-period (a few days) fluctuations associated with the cold front passages, however, this is not reflected on the current records. It appears that the countercurrent is fairly steady. Together with similar reversing flow found at places much further to the north, the overall pattern seems to be a general quasi-steady feature along most part of the shelf edge of the East China Sea.     

Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas

The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (L_s), ranging from 19 to 93 pM with an average conditional stability constant (K_HgLs) of 10²⁸, and a weak class (L_w) ranging from 1.4 to 9.8 nM with an average K_HgLs of 10²³. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgCl_x, Hg(OH)_x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters.     

Geomorphological evidence for upslope canyon-forming processes on the northern KwaZulu-Natal shelf,SW Indian Ocean,South Africa

A geomorphological and statistical analysis of slope canyons from the northern KwaZulu-Natal continental margin is documented and compared with submarine canyons from the Atlantic margin of the USA. The northern KwaZulu-Natal margin is characterized by increasing upslope relief, concave slope-gradient profiles and features related to upslope growth of the canyon forms. Discounting slope-gradient profile, this morphology is strikingly similar to canyon systems of the New Jersey slope. Several phases of canyon incision indicate that downslope erosion is also an important factor in the evolution of the northern KwaZulu-Natal canyon systems. Despite the strong similarities between the northern KwaZulu-Natal and New Jersey slope-canyon systems, key differences are evident: (1) the concavity of the northern KwaZulu-Natal slope, contrasting with the ∼linear New Jersey slope; (2) the relative isolation of the northern KwaZulu-Natal canyons, rather than the dense clustering of the New Jersey canyons; and (3) the absence of strongly shelf-breaching canyons along the northern KwaZulu-Natal margin. In comparison with the New Jersey margin, we surmise a more youthful stage of canyon evolution, a result of either the canyons themselves being younger or the formative processes being less active. Less complicated patterns of erosion resulting from reduced sediment availability have developed in northern KwaZulu-Natal. The reduction in slope concavity on the New Jersey margin may be the result of grading of the upper slope by intensive headward erosion, a process more subdued—or less evident—on the KwaZulu-Natal margin.     

A time-varying parameter model of a body oscillating in pitch

Among the assumptions upon which linear time-invariant models of floating bodies are based is that the body motions are so small that any change in the body’s angular position can be disregarded. However, it is often a major design requirement of a wave energy conversion device that the response amplitude is large, thereby invalidating one of the assumptions of the linear model. In particular, the immersed geometry of a body undergoes considerable variation when it is moved in pitch. With regard to this we investigate the difference in performance between a quasi-linear model in which the change of immersed surface is modelled by time-varying parameters and a basic linear model in which the immersed surface is time-invariant. The time-varying parameter model is realized by interpolation between the appropriate parameter values of a set of linear time-invariant (LTI) models derived for the different immersed surfaces that occur at discrete body displacements. It is shown that the responses predicted using the time-varying parameter model are closer to those measured experimentally than those of a standard frequency-domain model. Particular improvement occurs when the responses are large, such as at or near the resonance frequency. A problem which may limit the general use of the model is also discussed.     

The capacity of marine plankton, macrophytes and particulate matter to adsorb Cu in the presence of Mg

A complexometric titration technique was employed to measure the total capacity of a variety of marine organisms to adsorb Cu²⁺. Measured adsorption capacities were 0.22 meq g⁻¹ for phytoplankton, 0.3–1.0 meq g⁻¹ for macrophytes, 1.0–2.5 meq g⁻¹ for zooplankton and 0.3 meq g⁻¹ for suspended particulate matter. The capacity of these materials to adsorb Cu²⁺ was reduced significantly in the presence of Mg²⁺ at seawater concentrations. Competition between Mg^t2+ and Cu²⁺ for adsorption sites at pH 6 is described by an average conditional equilibrium constant of 10^3.7. This constant is such that very little Cu²⁺ may be adsorbed onto particulates and marine phytoplankton in the presence of Mg²⁺. Further, primary productivity data and estimates of the detrital carbon sedimentation in Long Island Sound suggest that the flux of particulate carbon is insufficient to remove significant amounts of Cu from the water column to sediments by adsorption mechanisms.     

An Annotated Check-List of Planktonic Diatoms from the Gulf of Naples

Abstract. New data on the planktonic diatoms from the Gulf of Naples are presented together with those from the literature. Information is given on abundances, seasonal cycles and distributions of 183 taxa, including species, varieties and forms.