Intragrain oxygen isotope zoning in titanite by SIMS: Cooling rates and fluid infiltration along the Carthage‐Colton Mylonite Zone,Adirondack Mountains,NY, USA

Oxygen isotopes are an attractive target for zoning studies because of the ubiquity of oxygen‐bearing minerals and the dependence of mineral ¹⁸O/¹⁶O ratios on temperature and fluid composition. In this study, subtle intragrain oxygen isotope zoning in titanite is resolved at the 10‐μm scale by secondary ion mass spectrometry. The patterns of δ¹⁸O zoning differ depending on microstructural context of individual grains and reflect multiple processes, including diffusive oxygen exchange, partial recrystallization, grain‐size reduction, and grain growth. Using the chronological framework provided by structural relations, these processes can be related to specific events during the Grenville orogeny. Titanite was sampled from two outcrops within the Carthage‐Colton Mylonite Zone (CCMZ), a long‐lived shear zone that ultimately accommodated exhumation of the Adirondack Highlands from beneath the Adirondack Lowlands during the Ottawan phase (1090–1020 Ma) of the Grenville orogeny. Titanite is hosted in the Diana metasyenite complex, which preserves three sequentially developed fabrics: an early NW‐dipping protomylonitic fabric (S₁) is crosscut by near‐vertical ultramylonitic shear zones (S₂), which are locally reoriented by a NNW‐dipping mylonitic fabric (S₃). Texturally early titanite (pre‐S₂) shows diffusion‐dominated δ¹⁸O zoning that records cooling from peak Ottawan, granulite‐facies conditions. Numerical diffusion models in the program Fast Grain Boundary yield good fits to observed δ¹⁸O profiles for cooling rates of 50 ± 20 °C Ma^?1, which are considerably faster than the 1–5 °C Ma^?1 cooling rates previously inferred for the Adirondack Highlands from regional thermochronology. High cooling rates are consistent with an episode of rapid shearing and exhumation along the CCMZ during gravitational collapse of the Ottawan orogen at c. 1050 Ma. Texturally later titanite (syn‐S₂) has higher overall δ¹⁸O and shows a transition from diffusion‐dominated to recrystallization‐dominated δ¹⁸O zoning, indicating infiltration of elevated‐δ¹⁸O fluids along S₂ shear zones and continued shearing below the blocking temperature for oxygen (~≤500 °C for grain sizes at the study site). The texturally latest titanite (post‐S₃) has growth‐dominated δ¹⁸O zoning, consistent with porphyroblastic grain growth following cessation of shearing along the Harrisville segment of the CCMZ.     

Phases greater than 90° in MT data: Analysis using dimensionality tools

An example of magnetotelluric data is discussed which has distinctive phase values out of quadrant, and for which the Z_xx element of the measured tensor is greater than the Z_xy element in both real and quadrature parts. Mohr circle plots and principal value decompositions of the real and quadrature parts of the tensor clarify its understanding. An analysis of rotational invariants of the data suggests a case of galvanic distortion of a 2D structure. Results from phase tensor analysis are included, and the example is seen to be a dramatic instance of phase tensor analysis reducing an apparently 3D example to 2D characteristics.The Mohr circles of this example do not capture the axes origin, although there are phases out of quadrant. Extra intrigue is thus added to the question, noted in Lilley, F.E.M., 1998. Magnetotelluric tensor decomposition: part I, theory for a basic procedure. Geophysics 63, 1885–1897 and arising independently in Caldwell, T.G., Bibby, H. M., Brown, C., 2004. The magnetotelluric phase tensor. Geophys. J. Int. 158, 457–469 and Bibby, H.M., Caldwell, T.G., Brown, C., 2005. Determinable and non-determinable parameters of galvanic distortion in magnetotellurics. Geophys. J. Int. 163, 915–930, whether the determinant values taken separately of the real and quadrature parts of a magnetotelluric tensor should both never be negative.For data whose Mohr circles do not capture the axes origin, simple conditions are derived regarding phase. These conditions govern whether or not it is formally possible for observed phases of Z_xy to exceed 90°, for any rotation of the observing axes.     

Site characterization model using least‐square support vector machine and relevance vector machine based on corrected SPT data (Nc)

Statistical learning algorithms provide a viable framework for geotechnical engineering modeling. This paper describes two statistical learning algorithms applied for site characterization modeling based on standard penetration test (SPT) data. More than 2700 field SPT values (N) have been collected from 766 boreholes spread over an area of 220 sqkm area in Bangalore. To get N corrected value (N_c), N values have been corrected (N_c) for different parameters such as overburden stress, size of borehole, type of sampler, length of connecting rod, etc. In three‐dimensional site characterization model, the function N_c=N_c (X, Y, Z), where X, Y and Z are the coordinates of a point corresponding to N_c value, is to be approximated in which N_c value at any half‐space point in Bangalore can be determined. The first algorithm uses least‐square support vector machine (LSSVM), which is related to a ridge regression type of support vector machine. The second algorithm uses relevance vector machine (RVM), which combines the strengths of kernel‐based methods and Bayesian theory to establish the relationships between a set of input vectors and a desired output. The paper also presents the comparative study between the developed LSSVM and RVM model for site characterization. Copyright © 2009 John Wiley & Sons, Ltd.     

Structural geometry and controls on basement‐involved deformation in the northern Flinders Ranges,Adelaide Fold Belt,South Australia

In the northern Flinders Ranges, Neoproterozoic and Cambrian sedimentary rocks were deformed and variably metamorphosed during the ca 500 Ma Cambro‐Ordovician Delamerian Orogeny. Balanced and restored structural sections across the northern Flinders Ranges show shortening of about 10–20%. Despite the presence of suitable evaporitic detachment horizons at the basement‐cover interface, the structural style is best interpreted to be thick‐skinned involving basement with only a minor proportion of the overall shortening accommodated along stratigraphically controlled detachments. Much of the contractional deformation was localised by the inversion of former extensional faults such as the Norwest and Paralana Faults, which both controlled the deposition of Neoproterozoic cover successions. As such, both faults represent major, long‐lived structures which effectively define the present boundaries of the northern Flinders Ranges with the Gawler Craton to the west and the Curnamona Craton to the east. The most intense deformation, which resulted in exhumation of the basement along the Paralana Fault to form the Mt Painter and Babbage Inliers, coincides with extremely high heat flows related to extraordinarily high heat‐production rates in the basement rocks. High heat flow in the northern Flinders Ranges suggests that the structural style not only reflects the pre‐Delamerian basin architecture but is also a consequence of the reactivation of thermally perturbed, weakened basement.     

On the relationship between historical land‐use change and water availability: the case of the lower Tarim River region in northwestern China

Natural ecosystems in the region of the lower Tarim River in northwestern China strongly deteriorated since the 1950s due to an expanding desertification. As a result, the downstream Tarim River reaches became permanently dry land. This historical evolution in land‐use change is typically the result of the anthropogenic impact on natural ecosystems. On the basis of a spatially distributed hydrological catchment model bidirectionally linked with a fully hydrodynamic MIKE11 river model, land‐use changes characterized by historical changes in leaf area index (LAI) of vegetation, as well as the evolution of irrigated surface areas, can be causally related to changes in water resources (groundwater storage and surface water resources). An increased surface area of irrigated (agricultural) land, together with a majority of inefficient irrigation methods, did lead to a strong increase of water resources consumption of the farmlands located in the upper Tarim River area. Evidently, this evolution influenced available water resources downstream in the Tarim basin. As a result, farmland has been gradually relocated to the upstream regions. This has led to reduced flows from the upper Tarim stream, which subsequently accelerated the dropping of the groundwater level downstream in the basin. This study moreover demonstrates that land surface biomass changes (cumulative LAI) along the lower Tarim River are strongly related to the changes in groundwater storage. Copyright © 2012 John Wiley & Sons, Ltd.