The oldest (~ 1.9 Ga) metadolerites of the southern Siberian craton: age,petrogenesis, and tectonic setting

Geological, geochronological, and isotope-geochemical studies of the metadolerites of the Angaul complex, widespread in the Urik-Iya graben of the southern Siberian craton, were carried out. The metadolerites forming separate conformal bodies (sills) among the metasandstones of the Ingash Formation were studied in detail. U-Pb zircon (SHRIMP) dating of metadolerites yielded an age of 1913 ± 24 Ma, and U-Pb baddeleyite (ID-TIMS) dating of these rocks yielded an age of 1914.0 ± 1.7 Ma. Thus, the date of 1914 ± 2 Ma can be taken as the most precise age estimate for the studied rocks. The metadolerites of the Angaul complex correspond in chemical composition to the normal-alkaline tholeiitic basalts. Metadolerites are differentiated rocks with mg# of 36 to 58. They show fractionated REE patterns: (La/Yb)_n = 1.2-3.5. All metadolerites, independently of their mg# value, have low contents of Nb (1.6-10.2 ppm) and show well-pronounced negative Nb-Ta anomalies in multielement patterns (Nb/Nb* = 0.19-0.54). The metadolerites are characterized by positive ε_Nd(T) values ranging from 0.4 to 5.2, which correlate well with their SiO₂ content and mg# value. The isotope-geochemical parameters of the metadolerites of the Angaul complex indicate that fractional crystallization, along with the assimilation of the host rocks (AFC), might have been the main process during the formation of the most differentiated metadolerites. The geochemical characteristics of metadolerites with the maximum mg# values of 57-58 and ε_Nd(T) = 5.2 suggest that the parental mantle source of the metadolerites resulted from mixing of predominant depleted mantle material with the subcontinental-lithosphere material. Intrusion of the dolerites of the Angaul complex, as well as the deposition of the sedimentary strata of the Ingash Group, took place at the Paleoproterozoic stage of intracontinental extension caused by the collapse of the orogen resulted from the collision of the Biryusa block with the Tunguska superterrane in the southern Siberian craton.     

Phenanthrene biomarkers in the organic matter of Precambrian and Phanerozoic deposits and in the oils of the Siberian Platform

The composition and distribution of phenanthrenes (polyaromatic compounds) have been studied in chloroform extracts from dispersed organic matter (OM) of clayey, siliceous, carbonate, and terrigenous rocks of different ages and facies and from some oils of the Siberian Platform. Phenanthrenes have been analyzed by gas chromatography-mass spectrometry. High contents of 1,7,8-trimethylphenanthrene and 1,1,7,8-tetramethyl-1,2,3,4-tetrahydrophenanthrene are present in the OM of Vendian and Cambrian carbonate-shale deposits and in ancient oils of the Nepa-Botuobiya and Anabar anteclises. The OM of Permian continental deposits and oils of the Vilyui syneclise is dominated by 1-methyl-7-isopropylphenanthrene (retene). A triangular diagram for identification of the types of original OM of rocks and classification of genetically related oils has been constructed based on the assessment of phenanthrene biomarker distribution. Putative pathways of the formation of phenanthrene biomarkers are discussed.     

Hydrogeology of a montane headwater groundwater system downgradient of a coal-mine waste rock dump: Elk Valley,British Columbia,Canada

Steelmaking-coal waste rock placed in mountain catchments in the Elk Valley, British Columbia, Canada, drain constituents of interest (CIs) to surface water downgradient of the waste rock dumps. The role of groundwater in transporting CIs in the headwaters of mountain catchments is not well understood. This study characterizes the physical hydrogeology of a portion of a 10-km² headwater catchment (West Line Creek) downgradient of a 2.7-km² waste rock dump placed over a natural headwater valley-bottom groundwater system. The study site was instrumented with 13 monitoring wells. Drill core samples were collected to determine subsurface lithology and geotechnical properties. The groundwater system was characterized using field testing and water-level monitoring. The valley-bottom sediments were composed of unconsolidated glacial and meltwater successions (<64 m thick) deposited as a series of cut and fill structures overlying shale bedrock. An unconfined basal alluvial aquifer located above fractured bedrock was identified as the primary conduit for groundwater flow toward Line Creek (650 m from the toe of the dump). Discharge through the basal alluvial aquifer was estimated using the geometric mean hydraulic conductivity (±1 standard deviation). These calculations suggest groundwater discharge could account for approximately 15% (ranging from 2 to 60%) of the total water discharged from the watershed. The residence time from the base of the waste rock dump to Line Creek was estimated at <3 years. The groundwater system was defined as a snowmelt (i.e., nival) regime dominated by direct recharge (percolation of precipitation) across the catchment.     

The First Hop: Use of Beaufort Sea Deltas by Hatch-Year Semipalmated Sandpipers

River deltas along Alaska’s Beaufort Sea coast are used by hatch-year semipalmated sandpipers (Calidris pusilla) after leaving their terrestrial natal sites, but the drivers of their use of these stopover sites on the first “hop” of fall migration are unknown. We quantified sandpiper temporal distribution and abundance as related to food resources at three river deltas during the beginning of their fall migration (post-breeding period) to compare the habitat quality among these deltas. We conducted population counts, sampled invertebrates, and captured birds to collect blood samples from individuals for triglyceride and stable isotope analyses to determine fattening rates and diet. Patterns of sandpiper and invertebrate abundance were complex and varied among deltas and within seasons. River deltas were used by sandpipers from late July to late August, and peak sandpiper counts ranged from 1000 to 4000 individuals, of which 98% were hatch-year semipalmated sandpipers. Isotopic signatures from blood plasma samples indicated that birds switched from a diet of upland tundra to delta invertebrate taxa as the migration season progressed, suggesting a dependence on delta invertebrates. Despite differences in diet among deltas, we found no differences in fattening rates of juvenile sandpipers as indicated by triglyceride levels. The number of sandpipers was positively associated with abundance of Amphipoda and Oligochaeta at the Jago and Okpilak-Hulahula deltas; an isotopic mixing model indicated that sandpipers consumed Amphipoda and Oligochaeta at Jago, mostly Chironomidae at Okpilak-Hulahula and Spionidae at Canning. Regardless of the difference in sandpiper diets at the Beaufort Sea deltas, their similar fattening rates throughout the season indicate that all of these stopover sites provide a critical food resource for hatch-year sandpipers beginning their first migration.     

Water stress index and its implication for agricultural land-use policy in Thailand

Land-use change and expansion for agriculture significantly affect freshwater resource availability which in turn results in different levels of water scarcity and competition among users in different areas and time. The study uses the water stress index as an indicator for determining the potential impact of water use considering water deprivation potential. Considering the case of Thailand, the temporal aspects of water withdrawal and availability have been analyzed and characterized as the monthly water stress index for the 25 watersheds in the country. Wide variations of monthly water stress index are obtained; extreme water stress is observed in the areas of the Chao Phraya and Tha Chin watersheds (the central region) during the dry season because of the large areas cultivating second rice (rice planted in dry season). The target of the Thai government on agricultural land-use change and zoning toward the conversion of about 0.37 M·ha of the upland paddy fields with low productivity to sugarcane was evaluated showing serious implications on the monthly water stress index of the relevant watersheds and the water scarcity footprint potentials of rice and sugarcane production. The results reveal that proper policy can help reduce the amount of water requirement for agriculture in June, July, August and September by about 60–220 M·m³, which in turn results in the decrease in monthly water stress index values. Nevertheless, appropriate measures of water resource management for agriculture still need to be designed to avoid water competition as well as protect the ecosystem.     

Paleogene–Neogene Boundary of Primorye,Russian Far East

Complex geological and paleobotanic analysis of sections of the boundary Oligocene–Miocene sediments of southern Primorye is conducted. The presence of a stratigraphic hiatus is identified in the transitional complexes of the Pushkino and Pavlovka depressions but not in the sections of the Rakovka depression; thus, it is suggested to use one of them (borehole no. 15) to choose the stratotype of the Paleogene–Neogene boundary. The previous conclusion on the presence of economic coal deposits of Primorye within the Paleogene part of the Tertiary complex is supported. It is suggested to use the section which is exposed by the Rakovka brown coal open pit (point 9209) as a stratotype of the upper subformation of the Pavlovka Formation.     

Creep behaviour of intact and remoulded fibrous peat

This paper presents the creep behaviour of intact and remoulded specimens of fibrous peat obtained from a field site near Anzac, Alberta, Canada. The creep behaviour was investigated by means of long-term drained and undrained triaxial tests. The development of volumetric, axial, and undrained axial strain and strain rate during drained and undrained creep tests under variable stress conditions is presented. The stress _– strain _– strain rate (p′–ε _v–\(\dot{\varepsilon }_{\text{v}}\)) relationship is found to be unique for different stress and loading durations. The p′–ε _v–\(\dot{\varepsilon }_{\text{v}}\) relationship is analysed and represented by creep isotaches. The applicability of different creep models developed for normally consolidated clay is discussed and applied to define the development of creep strain in fibrous peat under varying isotropic and deviator stresses. The secondary consolidation coefficient for evaluating the volumetric strain rate of peat is found to be applicable with some limits. The drained creep behaviour of remoulded peat specimens differs from the behaviour shown by Shelby tube specimens, whereas the undrained creep behaviour in remoulded and Shelby tube specimens is similar.     

Soil wettability in ground engineering: fundamentals,methods, and applications

Wettability is a fundamental property controlling the extent of wetting in flat and granular solids. In natural soils, wettability affects a wide variety of processes including infiltration, preferential flow and surface runoff. In mineral processing, wettability is paramount in enhancing the efficiency of separation of minerals from gangue. The manipulation of surface wettability is equally crucial in many industrial applications. For instance, superhydrophobic surfaces are those on which water drops roll off easily and as such are used for self-cleaning applications. Therefore, while wettability is strongly cross-disciplinary, its evolution has been discipline-specific with a direct extrapolation or transfer of concepts, approaches, and methods to ground engineering unlikely to remain valid. This paper synthesizes relevant aspects from surface chemistry, materials science, mining engineering, and soil science, and discusses their implications within the context of new granular materials that resist wetting, for use in barriers or ground improvement and, in unsaturated soils, where the effects of wettability have been documented.     

Effects of historical and projected land use/cover change on runoff and sediment yield in the Netravati river basin,Western Ghats,India

In this study, the effects of changes in historical and projected land use land cover (LULC) on monthly streamflow and sediment yield for the Netravati river basin in the Western Ghats of India are explored using land use maps from six time periods (1972, 1979, 1991, 2000, 2012, and 2030) and the soil and water assessment tool (SWAT). The LULC for 2030 is projected using the land change modeller with the assumption of normal growth. The sensitivity analysis, model calibration, and validation indicated that the SWAT model could reasonably simulate streamflow and sediment yield in the river basin. The results showed that the spatial extent of the LULC classes of urban (1.80–9.96%), agriculture (31.38–55.75%), and water bodies (1.48–2.66%) increased, whereas that of forest (53.04–27.03%), grassland (11.17–4.41%), and bare land (1.09–0.16%) decreased from 1972 to 2030. The streamflow increased steadily (7.88%) with changes in LULC, whereas the average annual sediment yield decreased (0.028%) between 1972 and 1991 and increased later (0.029%) until 2012. However, it may increase by 0.43% from 2012 to 2030. The results indicate that LULC changes in urbanization and agricultural intensification have contributed to the increase in runoff, amounting to 428.65 and 58.67 mm, respectively, and sediment yield, amounting to 348 and 43 ton/km², respectively, in the catchment area from 1972 to 2030. The proposed methodology can be applied to other river basins for which temporal digital LULC maps are available for better water resource management plans.     

Hydrothermal fracture controlled vein type uranium mineralization in the Paleoproterozoic Bijawar Group of rocks,Sonrai basin,Lalitpur district,U.P. – Fresh findings from subsurface borehole data

Sonrai basin, located along the southwestern margin of Bundelkhand Granite-Gneiss Complex (BGC) is known for its base metal and phosphorite mineralization. Uranium mineralization of appreciable grade and thickness was reported in Pisnari block in the northern part of this basin during sub-surface exploration activity in 1976-97. This was in the form of uranium-bitumin association within fractures in the carbonate-terrigenous sediments of Gorakalan shale, Rohini carbonate and Bandai sandstone of Sonrai Formation of Bijawar Group. Similar mineralization was also noted within the lower chloritic shale member of Solda Formation of the same Group. During subsequent drilling activity at a later phase (2005-09), uranium rich zones within Rohini carbonate and chloritic shale members were corroborated by the interception of mineralized bands in two boreholes drilled near Pisnari. Petrographic study of radioactive core samples reveal that uranium mineralization is closely associated with globular carbonaceous matter and sulphides along the fractures. Uranium is either adsorbed in carbonaceous matter or occurs as ultrafine inclusions of coffinite within carbonaceous matter. An additional phase of secondary uranium mineral (uranophane) is also noted in one of the boreholes. The uranium minerals, in association with sulphides, fill up moderately dipping fractures (approximately 15o towards North) which are oblique to the core axis of the inclined borehole and thus, the mineralization is characterized as hydrothermal fracture-controlled vein type mineralisation. C-HN- S analysis of carbonaceous matter occurring in close association with the uranium minerals reveal heterogeneity in composition with respect to carbon and sulfur. The present paper aims at discussing the geological, petrological and radiometric aspects of this mineralization, so as to enhance the understanding of the same.