Fate and tidal transport of butyltin and mercury compounds in the waters of the tropical Bach Dang Estuary (Haiphong, Vietnam)

In this work, two field campaigns were performed in July 2008 (wet season) and March 2009 (dry season) to produce original data on the concentration, partition and distribution of mercury and butyltin compounds along the tropical Bach Dang Estuary located in North Vietnam (Haiphong, Red River Delta). The results demonstrate that mercury and butyltin speciation in the surface waters of this type of tropical estuary is greatly affected by the drastic changes in the seasonal conditions. During high river discharge in the wet season, there was a large estuarine input of total Hg and tributyltin, while the longer residence time of the waters during the dry season promotes increasing MMHg formation and TBT degradation. Although most of the Hg and TBT is transported into the estuary from upstream sources, tidal cycle measurements demonstrate that this estuary is a significant source of TBT and MMHg during the wet (～3kgTBT/day) and dry (～3gMMHg/day) seasons.     

Observing water-level variations from space-borne high-resolution Synthetic Aperture Radar (SAR) image correlation

The potential of correlating high-resolution Synthetic Aperture Radar images to estimate local water-level variations is analysed based on observing the motions of floating structures. By computing range and azimuth offsets on a COSMO-SkyMed multi-temporal data-set in an area of the French Atlantic Coast, displacement signatures were detected in several harbours of the region. They can be associated with specific floating structures, whose vertical motion is mostly driven by tides. Although the image resolution is not the best achievable for the COSMO-SkyMed sensor, comparison with ground-based tide information revealed that the obtained space-borne measurements are consistent with the tide gauges to a decimetric accuracy. Even if the requirements for traditional users of tidal data are not met by the current revisit time of the COSMO-SkyMed constellation, the method proposed here provides complementary measures, which are already well aligned to requirements of users concerned with long-term sea-level variation and river or lake water stocks.     

In situ LA-ICP-MS U–Pb titanite dating of Na–Ca metasomatism in orogenic belts: the North Pyrenean example

In the Pyrenees, in association with the rotation of the Iberian plate around Europe during the Mid-Cretaceous, a Na–Ca metasomatism is recognized as a complementary record of the hydrothermal activity that led to Na-metasomatism (albitization) and talc–chlorite mineralization. It affected metasedimentary rocks as well as Hercynian granites. In situ laser ablation ICP-MS U–Pb analyses of titanite grains formed in albitites during metasomatism date the Na–Ca metasomatism between 110 and 92 Ma. The temperature of the Na–Ca metasomatism is estimated to be approximately 550 °C. Both the time constraints and temperature estimates suggest that the Na–Ca metasomatism is related to the low-P high-T North Pyrenean metamorphism.     

Edge Flow and Canopy Structure: A Large-Eddy Simulation Study

Sharp heterogeneities in forest structure, such as edges, are often responsible for wind damage. In order to better understand the behaviour of turbulent flow through canopy edges, large-eddy simulations (LES) have been performed at very fine scale (2 m) within and above heterogeneous vegetation canopies. A modified version of the Advanced Regional Prediction System (ARPS), previously validated in homogeneous conditions against field and wind-tunnel measurements, has been used for this purpose. Here it is validated in a simple forest-clearing-forest configuration. The model is shown to be able to reproduce accurately the main features observed in turbulent edge flow, especially the “enhanced gust zone” (EGZ) present around the canopy top at a few canopy heights downwind from the edge, and the turbulent region that develops further downstream. The EGZ is characterized by a peak in streamwise velocity skewness, which reflects the presence of intense intermittent wind gusts. A sensitivity study of the edge flow to the forest morphology shows that with increasing canopy density the flow adjusts faster and turbulent features such as the EGZ become more marked. When the canopy is characterized by a sparse trunk space the length of the adjustment region increases significantly due to the formation of a sub-canopy wind jet from the leading edge. It is shown that the position and magnitude of the EGZ are related to the mean upward motion formed around canopy top behind the leading edge, caused by the deceleration in the sub-canopy. Indeed, this mean upward motion advects low turbulence levels from the bottom of the canopy; this emphasises the passage of sudden strong wind gusts from the clearing, thereby increasing the skewness in streamwise velocity as compared with locations further downstream where ambient turbulence is stronger.     

Reassessment of historical sections from the Paleogene marine margin of the Congo Basin reveals an almost complete absence of Danian deposits

The early Paleogene is critical for understanding global biodiversity patterns in modern ecosystems. During this interval, Southern Hemisphere continents were largely characterized by isolation and faunal endemism following the breakup of Gondwana. Africa has been proposed as an important source area for the origin of several marine vertebrate groups but its Paleogene record is poorly sampled, especially from sub-Saharan Africa. To document the early Paleogene marine ecosystems of Central Africa, we revised the stratigraphic context of sedimentary deposits from three fossil-rich vertebrate localities: the Landana section in the Cabinda exclave(Angola), and the Manzadi and Bololo localities in western Democratic Republic of Congo.We provide more refined age constraints for these three localities based on invertebrate and vertebrate faunas, foraminiferal and dinoflagellate cyst assemblages, and carbon isotope records. We find an almost complete absence of Danian-aged rocks in the Landana section, contrary to prevailing interpretations over the last half a century(only the layer 1, at the base of the section, seems to be Danian). Refining the age of these Paleocene layers is crucial for analyzing fish evolution in a global framework, with implications for the early appearance of Scombridae(tunas and mackerels) and Tetraodontiformes(puffer fishes). The combination of vertebrate fossil records from Manzadi and Landana sections suggests important environmental changes around the K/Pg transition characterized by an important modification of the ichthyofauna. A small faunal shift may have occurred during the Selandian. More dramatic is the distinct decrease in overall richness that lasts from the Selandian to the Ypresian. The Lutetian of West Central Africa is characterized by the first appearance of numerous cartilaginous and bony fishes. Our analysis of the ichthyofauna moreover indicates two periods of faunal exchanges: one during the Paleocene, where Central Africa appears to have been a source for the European marine fauna, and another during the Eocene when Europe was the source of the Central Africa fauna. These data indicate that Central Africa has had connections with the Tethyian realm.     

Suitability of airborne laser scanning for the assessment of forest protection effect against rockfall

Rockfall simulation models are now able to quantify the protective effect of forest with the integration of rock impacts on trees. Those models require spatially explicit forest characteristics which are costly to acquire in operational conditions. The present study compares rockfall simulation results obtained with different forest input data sources: field data with different levels of spatial detail and two methods based on airborne Lidar data. Three different forest stands are tested with several virtual terrain configurations. When rockfall energies are below 200 kJ, the forest protection effect is significant. For higher energies, it also exists but it is minor compared to the effects of topography and rock volume. For all forest input data sources, the estimated rockfall intensity is within ?13 and 16 % of the reference value, whereas the frequency is generally overestimated. Both Lidar methods yield a satisfactory forest protection effect evaluation, but single tree detection tends to underestimate it. Improvements are possible regarding the spatial heterogeneity of stem density and the diameter distribution by tree species.     

Coupes Sismiques des Structures Superficielles dans les Petites Antilles—II: Martinique

Résumé En 1977, deux profils sismiques ont été réalisés en Martinique, un dans la région volcanique de la Montagne Pelée, l'autre dans la partie est de l'île. Le premier couvrait des distances de 3 à 23 km et le second de 2 à 50 km.Les structures superficielles du volcan sont interprétées par un modèle à trois couches. Sur une couche déjà connue, à 6,1 km/s nous trouvons, avec une épaisseur de 0,4 à 2,6 km, une vitesse de 4,3 km/s. En surface et jusqu'à une profondeur de 0,8 à 1,4 km la vitesse est d'environ 2,7 à 2,9 km/s.Dans la partie est de la Martinique, il existe une vitesse élevée-6,5 km/s—à partir d'une profondeur faible, de l'ordre de 3 km.

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In 1977, two seismic profiles were carried out in Martinique, one in the area of Montagne Pelée volcano, and the second in the eastern part of the island. The length of the first profile ranges from 3 to 23 km and the second from 2 to 50 km. The interpretation shows that the superficial structures of the volcano may be characterized by a three layer model: in the first layer the compressional velocity is about 2.7 to 2.9 km/s, the thickness varying from 0.8 to 1.4 km. The second layer has a velocity of 4.3 km/s and the thickness goes from 0.4 to 2.6 km. The deeper layer known at Leeward West Indies has a 6.1 km/s velocity.The second profile shows that the eastern part of Martinique is marked by a high velocity of 6.5 km/s, found at a depth of 3 km.

     

Volatile transport on inhomogeneous surfaces: I – Analytic expressions,with application to Pluto’s day

The two orders of magnitude drop between the measured atmospheric abundances of non-radiogenic argon, krypton and xenon in Earth versus Mars is striking. Here, in order to account for this difference, we explore the hypothesis that clathrate deposits incorporated into the current martian cryosphere have sequestered significant amounts of these noble gases assuming they were initially present in the paleoatmosphere in quantities similar to those measured on Earth (in mass of noble gas per unit mass of the planet). To do so, we use a statistical-thermodynamic model that predicts the clathrate composition formed from a carbon dioxide-dominated paleoatmosphere whose surface pressure ranges up to 3 bars. The influence of the presence of atmospheric sulfur dioxide on clathrate composition is investigated and we find that it does not alter the trapping efficiencies of other minor species. Assuming nominal structural parameters for the clathrate cages, we find that a carbon dioxide equivalent pressure of 0.03 and 0.9 bar is sufficient to trap masses of xenon and krypton, respectively, equivalent to those found on Earth in the clathrate deposits of the cryosphere. In this case, the amount of trapped argon is not sufficient to explain the measured Earth/Mars argon abundance ratio in the considered pressure range. In contrast, with a 2% contraction of the clathrate cages, masses of xenon, krypton and argon at least equivalent to those found on Earth can be incorporated into clathrates if one assumes the trapping of carbon dioxide at equivalent atmospheric pressures of ～2.3 bar. The proposed clathrate trapping mechanism could have then played an important role in the shaping of the current martian atmosphere.     

Land clearance and hydrological change in the Sahel: SW Niger

In the West African semiarid belt of the Sahel, for the second half of the XXth century, lasting droughts (1970s–1980s) and one of the World's highest population growths have resulted in major land cover and hydrological changes that can be quantified using aerial photographs. This paper aims to provide one of the longest combined observations of land cover and hydrological changes for semiarid areas using a time series of normalised mosaics of aerial photographs dating back from 1950, field inquiries, and updated groundwater data. The 500 km² study area in southwest Niger was chosen (i) for its rural environment representative of the rain-fed agriculture belt of the Sahel and (ii) to encompass the main hydrological study sites investigated in this region over the past two decades (Hapex-Sahel and AMMA experiments, 1990–2000s). Results have significant implications for future freshwater availability and food security in the Sahel.Between 1950 and 1992,  80% of the study area has been cleared, firstly to open new areas for agriculture and secondly for firewood supply (59% of the plateaux, 42% of the valley bottoms, and 87% of the hillslopes). Intermediate aerial photograph surveys (1960, 1975) attest an accelerated loss in the woody savannah that could not be recovered on the short term. A strong, indirect impact of land clearance is observed on the water resources. Land clearance has resulted in a modification of the soil properties and infiltration capacity and has led to an increase in Hortonian runoff collected in numerous gullies and ponds. Between 1950 and 1992, aerial photographs show a  2.5 fold increase of the drainage density with the development of large drainage systems and new ponds. Groundwater data also indicate a continuous rise in the water table, mostly noticeable since the 1980s with a mean groundwater level rise of  4 m for the 1963–2005 period (+ 15% in aquifer reserves). The relatively short  30 year time-lag between the onset of land clearance and the beginning of the water table rise is linked to the process of indirect groundwater recharge and is timed with the connectivity of the drainage network and the formation of new ponds. Finally, the sustained increase in surface runoff and groundwater recharge during the past four decades indicates that the indirect impact of land clearance on the terrestrial water balance has been stronger than that of the long-lasting Sahelian drought. As the rate of land clearance increased for the past century in semiarid Africa, its main hydrological effects may not yet be fully perceptible.