Method Development and Optimisation of Sodium Peroxide Sintering for Geological Samples

This work provides a measurement procedure for the complete digestion of rock samples containing refractory minerals such as zircon and chromite. Their dissolution by wet acid digestion is often incomplete but, although providing complete digestions, alkali fusion techniques can result in solutions with a high blank and total dissolved solid content. It was established by the systematic study with reference material trachyandesite MTA‐1 that a 1:6 sample to sodium peroxide (Na₂O₂) ratio is conservative for the complete digestion and recovery of all the analytes especially those contained in zircon. The sample decomposition time was 120 min for the zircon‐bearing rhyolite reference material MRH‐1. Complete digestion of chromite was obtained in the harzburgite RM MUH‐1. The sample solutions were stable for at least 1 year. Accurate measurements of SiO₂, Al₂O₃, TiO₂, P₂O₅ and K₂O could be made with ICP‐MS by not discarding the supernatant of the sinter solution and by using geological reference materials for external calibration. HF digestions are slow, not universal, and may form new mineral/phases that are insoluble under high temperature conditions. The validated sample decomposition procedure combined with ICP‐MS presents an alternative to the use of HF in routine analysis of difficult to digest geological materials.     

Occurrence of uraniferous iron and manganese oxides in biotite granite North East Gabal El Sela area, South Eastern Desert, Egypt

Optical microscopy, X-ray diffraction (XRD), and back-scattered electron imaging (BSE) have been used to determine the mineralogical composition of the uraniferous iron and manganese oxides and the associated U-minerals hosted in biotite granite that occurred north east Gabal El Sela area south Eastern Desert, Egypt. These mineralizations were found as veinlets fractures filling associated with strongly kaolinitic alteration of the coarse-grained biotite granite. XRD determined that the geothite mineral form the main constituent of uraniferous iron oxide in addition to tapiolite, and kaolinite minerals, where as uraniferous manganese oxide composed of pyrolusite, ramsdellite, and cryptomelane. BSE confirmed that the associated uranium minerals represented by uranothorite, kazolite, and zentime in addition to columbite-bearing minerals. Uranothorite and columbite-bearing minerals are the most abundant minerals in this mineralization. Petrographically, biotite granite is composed mainly of quartz, in addition to K-feldspars, biotite and muscovite with minor zircon, garnet, apatite, uranium-rich thorite and iron oxide. Petrochemical studies and tectonic discrimination diagrams for this granite reveal that they are classified as granite to alkali feldspar granite, originated from calc-alkaline magma having peraluminous nature and developed in within-plate tectonic environment. Field radiometric measurements revealed the localization of two high radiometric anomalies associated with iron and manganese oxides, within this anomaly uranium content range from 65 to 85 ppm. Alpha Track-etch Detectors of radon gas registrations revealed high track density reach up to 15,448.7 Bq/m³.     

Steel rings as seismic fuses for enhancing ductility of cross braced frames

A new remedy is proposed in this study to increase the ductility of cross-braced frames to a level comparable with ductile moment frames. The suggested system consists of one or two concentric steel rings installed in the cross-braced bay vertically. The steel rings are designed such that they fail in bending sooner than failure of the braces in compression.Then the rings act as seismic fuses with multiple bending plastic hinges. Using nonlinear static analysis, it is shown that the proposed sys...     

The Aghajari (Upper Fars) Formation in the Folded Zagros Zone, Iran:Insights to Identify Facies, Architectural Elements, Fluvial Systems,Petrography and Provenance

The Aghajari Formation, called also the Upper Fars, develops throughout the Folded Zagros Zone and its thickness in the type section in southwest of Iran is 2966 meters. To analyze the sedimentary basin of this Formation, lithofacies, architectural elements and petrofacies of the related deposits in a section in southeast of Sarvestan in Fars Province of Iran with a thickness of 2221.45 meters were examined. Microscopically studying thin sections, the petrography and the occurrence of the deposits were determined. In this section, 16 lithofacies, 10 architectural elements and 2 sandstone petrofacies were identified. The lithofacies were divided into two major and minor groups, in which the major lithofacies consist of coarse-grained (Gh, Gp, Gt and Gm), medium-grained (Sh, Sp, St, Sl, Sm, Sr and Ss and fine-grained ones (Fm, Fl and Fsm), and the minor lithofacies were evaporative and mixed silisiclastic-carbonate. The identified architectural elements are CH, SB, GB, LA, DA, CR, CS, LV, LS, CH (FF) and FF. By combining evidences from facies analysis and architectural elements together, the Aghajari Formation was divided into three parts in which the related sedimentation environments, from top to bottom, are gravel, gravel-sand and fine-grained meandering river respectively. There have also been playas and shoreface in the lower part. Based on petrography, the sandstones of this formation were classified into two groups: litharenite and sublitharenite. The origin of these deposits (sandstones) was appointed to the recycled orogeny and the source of quartz is low and medium to high metamorphic rank. Using the field evidences, the paleocurrent direction was achieved indicating the direction of the paleocurrent from northwest to southeast at the time of deposition. It is hoped that these data can be used in the interpretation of the basin and reconstruction of the paleogeography in the local and regional scales.     

Investigating the impact of sample desiccation on Itrax XRF core scanner signal reproducibility

Sediment samples tend to dry out during storage and are, therefore, stored refrigerated at about 4°C after wrapping in plastic foil. During XRF core scanning however, the samples must be taken out of their cover, increasing the risk of drying and formation of desiccation cracks on the surface. Because scan times can often amount to several hours and at highest resolution may take over a day to complete, the core will progressively dry out during scanning. With this study we aim to increase our understanding of how this slow drying of the samples during scanning and storage influences the XRF signal because of changes in water content, sediment surface topography, and the development of small, but slowly expanding cracks in the sediment core. Results show that the desiccation of samples during scanning and storage influence the XRF measurements in several ways. Most importantly, slow desiccation of the cores results in both a general lowering of the sample surface, and a shortening of the core due to shrinkage. Larger distance between sediment surface and detector leads to increased noise levels and poor reproducibility for many elements, while the shrinking of cores may shift individual data points between runs, resulting in poor reproducibility and offsets between datasets obtained at different times. Moreover, the loss of light elements, such as hydrogen and oxygen, can influence the matrix effect, especially for organic-rich sediment. Because the XRF signals of individual elements are affected to different degrees, these changes may induce artificial shifts and biases in many elemental ratios commonly used for paleoenvironmental reconstruction.     

洋中脊扩张速率对洋壳速度结构的约束

洋中脊速度结构是揭示大洋岩石圈演化过程的重要约束.为探讨不同扩张速率下洋中脊的洋壳速度结构特征,挑选了全球152处快速（全扩张速率> 90 mm·a^-1）、慢速（全扩张速率20~50 mm·a^-1）和超慢速（全扩张速率 < 20 mm·a^-1）扩张洋中脊和非洋中脊的洋壳1-D地震波速度结构剖面,通过筛选统计、求取平均值等方法对分类的洋壳1-D速度结构进行对比研究,获得了不同扩张速率下洋中脊洋壳速度结构差异以及洋中脊与非洋中脊洋壳速度结构差异的新认识：（1）快速、慢速和超慢速扩张洋中脊的平均正常洋壳厚度分别为6.4 km、7.2 km和5.3 km,其中洋壳层2的厚度基本相似,洋壳厚度差异主要源自洋壳层3;其洋壳厚度变化范围分别为4.9~8.1 km、4.6~8.7 km和4.2~10.2 km,随着洋中脊扩张速率减小,洋壳厚度的变化范围逐渐增大;（2）快速扩张洋中脊的洋壳速度大于慢速和超慢速,可能与快速扩张脊洋壳生成过程中深部高密度岩浆上涌比较充足有关;（3）非洋中脊（>10 Ma）的洋壳比洋中脊（< 10 Ma）的洋壳厚~0.3 km,表明洋壳厚度与洋壳年龄有一定的正相关性.

     

Numerical Evaluation of Local Site Effects on Amplification of the 2017 Mw 7.3 Sarpol-e-Zahab,Iran, Earthquake Waves Using Near and Far-Field Records

Geotechnical and Geological Engineering - This is the first study to quantitatively evaluate the local site effects in the most severely affected neighborhoods of Sarpol-e-Zahab city following the...     

Full-scale experimental investigations on the response of a flooded passenger vehicle under subcritical conditions

Natural Hazards - Vehicles can be easily swept away by floodwaters once the flow velocity and depth reach certain critical limits, with probabilities toward fatality reported to be nearly 50%....