Petrographic Characteristics and Alteration Geochemistry of Granite-hosted Tungsten Mineralization at Degana, NW India

Abstract. Vein type tungsten mineralization at Degana is genetically and spatially associated with the Degana Granite. The deposit is characterized by pervasive wall rock alteration around the mineralized quartz veins. Laterally three different alteration zones, greisen, silicification and potassic zones, are marked based on the field features, mineral assemblages and geo-chemical characteristics. In the present paper, systematic mineralogical and chemical variation in these alteration zones is reported. Thick mono-mineralic (zinnwaldite) selvages around the veins characterize the deposit. Plagioclase and alkali feldspar are low in the greisen zones while K-feldspar shows more increase than plagioclase in the potassic zone. Quartz is uniformly high in all the alteration zones, but it shows an anomalous value in the silicification zone. Al₂O₃ concentration shows initial depletion in greisen zone with gradual increase away from the contact. MgO and FeO are higher in greisen zone than silicification and potassic zones. The potassic zone is characterized by the depletion of Na₂O and higher value of K₂O.
The common presence of topaz and fluorite as both primary and secondary minerals and fluorine-bearing micas suggest fluorine partitioning in substantial amount between granitic melt and coexisting aqueous fluid phase and higher HF activity during the evolution of hydrothermal fluid. The mutual relationship of the fluorine minerals (topaz and fluorite) in the different alteration zones suggests an increase in the Ca²⁺ activity and decrease of H+ activity during the fluid evolution from greisenization towards alkali-metasomatised granite and the fluid is assumed to change from low to high activity ratio of Ca²⁺/H+.     

High-Ti type N-MORB parentage of basalts from the south Andaman ophiolite suite,India

A complete dismembered sequence of ophiolite is well exposed in the south Andaman region that mainly comprises ultramafic cumulates, serpentinite mafic plutonic and dyke rocks, pillow lava, radiolarian chert, and plagiogranite. Pillow lavas of basaltic composition occupy a major part of the Andaman ophiolite suite (AOS). These basalts are well exposed all along the east coast of southern part of the south AOS. Although these basalts are altered due to low-grade metamorphism and late hydrothermal processes, their igneous textures are still preserved. These basalts are mostly either aphyric or phyric in nature. Aphyric type exhibits intersertal or variolitic textures, whereas phyric variety shows porphyritic or sub-ophitic textures. The content of alkalies and silica classify these basalts as sub-alkaline basalts and alkaline basalts. A few samples show basaltic andesite, trachy-basalt, or basanitic chemical composition. High-field strength element (HFSE) geochemistry suggests that studied basalt samples are probably derived from similar parental magmas. Al₂O₃/TiO₂ and CaO/TiO₂ ratios classify these basalts as high-Ti type basalt. On the basis of these ratios and many discriminant functions and diagrams, it is suggested that the studied basalts, associated with Andaman ophiolite suite, were derived from magma similar to N-MORB and emplaced in the mid-oceanic ridge tectonic setting.     

Saraca indica leaf powder for decontamination of Pb: removal, recovery, adsorbent characterization and equilibrium modeling

The present study explores the effectiveness of Saraca indica leaf powder, a surplus low value agricultural waste, in removing Pb ions from aqueous solution. The influence of pH, biomass dosage, contact time, particle size and metal concentration on the removal process were investigated. Batch studies indicated that maximum biosorption capacity for Pb was 95.37% at the pH 6.5. The sorption process followed the first order rate kinetics. The adsorption equilibrium data fitted best to both Langmuir and Freundlich isotherms. Morphological changes observed in scanning electron micrographs of untreated and metal treated biomass confirmed the phenomenon of biosorption. Fourier transform infrared spectroscopy of native and exhausted leaf powder confirmed lead biomass interactions responsible for sorption. Acid regeneration was tried for several cycles with a view to recover the sorbed metal ion and also to restore the sorbent to its original state. The findings showed that Saraca indica leaf powder can easily be envisaged as a new, vibrant, low cost biosorbent for metal clean up operations.     

PGE geochemistry of low-Ti high-Mg siliceous mafic rocks within the Archaean Central Indian Bastar Craton: implications for magma fractionation

Boninite-norite (BN) suites emplaced in an intracratonic setting in Archaean Cratons, are reported from many parts of the world. Such high-Mg low-Ti siliceous rocks are emplaced during Neoarchaean-Paleoproterozoic. The Archaean central Indian Bastar Craton also contains such a boninite-norite suite, which occurs in the form of dykes and volcanics. The spatial and temporal correlation of these high-Mg low-Ti siliceous rocks with similar rocks occurring around the northern Bastar and Dharwar Cratons probably represent a Bastar-Dharwar Large Igneous Province during the Neoarchaean-Paleoproterozoic. Platinum group element (PGE) abundances in these rocks provide constraints on their geochemical evolution during the Neoarchaean-Paleoproterozoic. The PGE geochemistry of the boninite-norite suite from the southern part of the central Indian Bastar Craton is presented to understand their behaviour during magma fractionation. In primitive mantle-normalized plots all samples have similar PGE fractionated patterns that are enriched in Pd, Pt and Rh relative to Ru. The Pd/Ru ratios for eight samples range from 2.0 to 7.0 which is higher than primitive mantle (primitive mantle Pd/Ru ≈1.2). The Pd/Pt ratios range between 0.2–2.5 with an average value of 0.7 which is near chondritic (primitive mantle Pd/Pt ≈0.5). PGE variations in these rocks together with those of major and other trace elements are consistent with a model involving olivine fractionation along with chromite as a cotectic phase. The Pt fractionation from Pd and Rh is controlled by both olivine and chromite crystallization at an early stage during high temperature crystal fractionation when the Pt was strongly compatible and Pd and Rh were incompatible. Strong negative correlations of the S content with iron and TiO₂ plus lithophile element contents of the rock suggest a decrease of the S solubility in the parental high-Mg magma and separation of an immiscible sulfide liquid with decreasing temperature. Palladium plus other available chalcophile elements (e.g., Re, Au, Ag) have been fractionated in this immiscible sulfide liquid after considerable olivine fractionation of the magma.     

Change detection of linear features in temporally spaced remotely sensed images using edge-based grid analysis

Automatic change detection of land cover features using high-resolution satellite images, is a challenging problem in the field of intelligent remote sensing data interpretation, and is becoming more and more effective for its applications viz. urban planning and monitoring, disaster assessment etc. In the present study, a change in detection approach based on the image morphology that analyses change in the local image grids is proposed. In this approach, edges from both the images are extracted and grid wise comparison is made by probabilistic thresholding and power spectral density analysis for identifying change area. One of the advantages of the proposed methodology is that the temporal images used in the change analysis need not be radiometrically corrected as analysis is based on edge extractions. The grid-based analysis further reduces the error, which might have been introduced by image mis-registration. The proposed methodology is validated by finding the temporal changes in the linear land cover features in parts of Kolkata city, India using three different image data-sets from LISS IV, Cartosat-1 and Google earth having varied spatial resolutions of 5.8 m, 2.5 m and about 1 m, respectively. The overall accuracy in identifying changes is found to be 64.82, 73.86 and 80.93% for LISS IV, Cartosat-1 and Google earth data-set, respectively.     

Detection of major geological structures in the Eastern offshore of India using Geosat altimeter data

Satellite altimetry can be used to infer subsurface geological structures analogous to gravity anomaly maps generated through ship-borne survey. The Eastern offshore was taken up for analysis using Geosat Exact Repeat Mission (ERM) altimeter data. A methodology is developed to use altimeter data as an aid to offshore hydrocarbon exploration. Processing of altimeter data involves corrections for various atmospheric and oceanographic effects, stacking and averaging of repeat passes, cross-over correction, removal of deeper earth and bathymetric effects, spectral analysis and conversion into free-air gravity anomaly. The final processed results were derived for Eastern offshore in the form of prospecting geoid and gravity anomaly maps and their spectral components. The highs and lows observed in those maps were derived in terms of a number of prominent megastructures e.g., gravity linears, 85°E and 90°E ridges, the Andaman trench complex etc. Satellite-derived gravity profiles along 12°N latitude match well with the existing structures.     

Mycorrhizal Colonization Affects the Survival of Vetiveria zizanioides (L.) Nash Grown in Water Containing As(III)

The presence of arsenic (As) in water is of great public concern. Arsenic exists in three common valence states viz., As(0) metalloid arsenic, As(III) (arsenite) and As(V) (arsenate). Arsenite [As(III)] is the most toxic form among arsenicals which, predominates in anaerobic conditions, generally in flooded soils and in the water with high BOD. Experiments were conducted to investigate the effect of As(III) on the mycorrhization in vetiver (Vetiveria zizanioides (L.) Nash) grass in hydroponics. Studies showed significant alteration in the mycorrhizal colonization in the roots of vetiver exposed to higher concentrations of As(III) starting from 1.0, 2.0, 3.0, 4.0 to 5.0 mg/L prepared in 5% Hoagland nutrient solution without addition of phosphate ions. Considerable reduction in the mycorrhizal intensity (M) was observed in all the treatment sets as compared to the control suggesting a negative impact of the As(III) on the mycorrhizal association. Simultaneously, the study also showed that, As(III) is toxic to the vetiver plants having mycorrhizal association however plants with non‐mycorrhizal (cleansed) roots were found to be able to survive for a longer period exposed to As(III).     

New period and period variations of DX Aquarii

The new period (P=0 _. ^d 461700) of the eclipsing binary system DX Aqr has been presented, which is based on available times of minima. O–C diagram of DX Aqr has been presented for the first time, and the period variations present in the system have been analysed. In all five period increases and five period decreases are nothed, and four period increases and five period decreases have been discussed. The strongest period increase occurs between 1975 and 1976. The total period change in different portions of the O–C diagram ranges from 1.40×10^–4 d to 3.61×10^–6 d. Appreciable period fluctuations have been noted to have occurred in the time intervals, 1964–1965 and 1974–1975.     

Spectra of seismic waves of Matsushiro micro-earthquakes

Summary The spectra of Matsushiro micro-earthquakes were studied using a spectrum analyser and discussed in relation to their magnitude and the epicentral distance. It was found that the spectra of seismic waves by Matsushiro micro-earthquakes did not depend upon the epicentral distance since the sonagrams showed a peak around 5 cps at Matsushiro as well as Suzaka. The spectrum also failed to show any distinct peak for micro-earthquakes of magnitude lower than 1.0 due to the decrease of signal to noise ratio.     

Late Pleistocene–Holocene hydrologic changes in the interfluve areas of the central Ganga Plain, India

Abandoned channel belts, ponds and point bar deposits of palaeochannels in the interfluve regions of the central Ganga Plain suggest changes in the morphohydrologic conditions during the Latest Pleistocene–Holocene. Stratigraphy of these ponds comprises channel sand at the base overlain by shell-bearing clayey silt. The contact of the two facies marks the phase when channels converted into standing water bodies. Point bar deposits of some palaeochannels are overlain by oxidised aeolian sand, indicating that the channel abandonment possibly occurred due to the desiccation and aridity in the region.Optically stimulated luminescence (OSL) chronometry of the pond sediments suggests that the deposition of the basal channel sand started before 13 ka and continued up to 8 ka. The ponds formed around 8–6 ka when the channel activity ceased. Evidence from the point bar deposits also indicates that the fluvial activity in the region ended sometime during 7–5 ka. This was followed by aeolian aggradation. The present study thus suggests that the hydrologic conditions in the Gangetic plains, i.e. initiation of channels and their abandonment, formation of microgeomorphologic features such as ponds and their eventual siltation, were controlled largely by climatic changes (i.e. monsoon changes) supported by tectonic activity. For the past 2 ka, increasing human and related agricultural activity has substantially accentuated the natural siltation rate of ponds.