The role of hydrocarbons in the lonospheres of the outer planets

The role of hydrocarbons as a possible sink for H⁺ and H₃⁺ ions in the lower ionosphere of the outer planets is examined. Calculations indicate that H⁺ and H₃⁺ are efficiently converted to hydrocarbon ions on reaction with methane. The terminal ions, CH₅⁺ and C₂H₅⁺ are rapidly neutralized in dissociative recombination with electrons. Extreme ultraviolet photolysis of hydrocarbons as a potential additional source of lower elevation ions in investigated.     

Titan's methane cycle

Methane is key to sustaining Titan's thick nitrogen atmosphere. However, methane is destroyed and converted to heavier hydrocarbons irreversibly on a relatively short timescale of approximately 10-100 million years. Without the warming provided by CH₄-generated hydrocarbon hazes in the stratosphere and the pressure induced opacity in the infrared, particularly by CH₄-N₂ and H₂-N₂ collisions in the troposphere, the atmosphere could be gradually reduced to as low as tens of millibar pressure. An understanding of the source-sink cycle of methane is thus crucial to the evolutionary history of Titan and its atmosphere. In this paper we propose that a complex photochemical-meteorological-hydrogeochemical cycle of methane operates on Titan. We further suggest that although photochemistry leads to the loss of methane from the atmosphere, conversion to a global ocean of ethane is unlikely. The behavior of methane in the troposphere and the surface, as measured by the Cassini-Huygens gas chromatograph mass spectrometer, together with evidence of cryovolcanism reported by the Cassini visual and infrared mapping spectrometer, represents a “methalogical” cycle on Titan, somewhat akin to the hydrological cycle on Earth. In the absence of net loss to the interior, it would represent a closed cycle. However, a source is still needed to replenish the methane lost to photolysis. A hydrogeochemical source deep in the interior of Titan holds promise. It is well known that in serpentinization, hydration of ultramafic silicates in terrestrial oceans produces H_2(aq), whose reaction with carbon grains or carbon dioxide in the crustal pores produces methane gas. Appropriate geological, thermal, and pressure conditions could have existed in and below Titan's purported water-ammonia ocean for “low-temperature” serpentinization to occur in Titan's accretionary heating phase. On the other hand, impacts could trigger the process at high temperatures. In either instance, storage of methane as a stable clathrate-hydrate in Titan's interior for later release to the atmosphere is quite plausible. There is also some likelihood that the production of methane on Titan by serpentinization is a gradual and continuous on-going process.     

Resonance in a geo-centric satellite due to earth’s equatorial ellipticity

The resonances in a geocentric satellite due to earth’s equatorial ellipticity have been investigated. The resonance at five points resulting from the commensurability between the mean motion of the satellite and the earth’s equatorial ellipticity is analyzed. The amplitude and the time period of the oscillation have been determined by using the procedure of Brown and Shook. A comparison of their effects on the orbital elements has also been studied. It is observed that the amplitude and the time period of the oscillation decrease as Γ (angle measured from the minor axis of the earth’s equatorial ellipse to the projection of the satellite on the plane of the equator) increases in the first quadrant for all the resonance cases.     

Diatom and chrysophyte functions and inferences of post-industrial acidification and recent recovery trends in Killarney lakes (Ontario, Canada)

The surface sediment diatom and chrysophyte assemblages from 33 Sudbury lakes were added to our published 72 lake data set to expand and refine the diatom and chrysophyte-based inference models that we had earlier developed for this region. Our calibration data set now includes 105 lakes, representing gradients for multiple environmental variables (e.g., lakewater pH, metals, and transparency). The revised models are based on the weighted averaging calibration and regression approach and include bootstrap error estimates. The pH model was the strongest (r² _boot = 0.75, RMSE _boot = 0.50). The chrysophyte-inferred pH model (r² _boot = 0.79, RMSE _boot = 0.48) that we developed was as robust as the diatom pH model. Diatom and chrysophyte inferred pH models were then applied to top (surface sediments representing current conditions) and bottom (generally from > 30 cm deep representing pre-industrial conditions) sediment diatom and chrysophyte assemblages of 19 Killarney area lakes near Sudbury. The top and bottom inferred pH results were compared to early-1970s measured pH data. These data suggest that, although many of the poorly buffered Killarney lakes had experienced acidification, marked pH recovery has occurred in many lakes within the last 25 years. Despite the stunning pH recovery, the present-day diatom and chrysophyte assemblages are significantly different from assemblages present during pre-industrial times. Our results suggest that biological recovery may require more time than chemical recovery. It is also likely that these lakes may never recover biologically because other anthropogenic stressors (e.g., climate warming and increased exposure to UV-B radiation) may now have greater influence on biological communities in Killarney/Sudbury area lakes than acidification.     

Scaling of adsorption reactions: U(VI) experiments and modeling

Iron-coated sands were prepared via two common protocols, a precipitation method, where Fe was precipitated directly onto the sand in a single step, and an adsorption method, where pure goethite was prepared in the first step and then adsorbed onto the sand in a second step. The coated sands from both the systems were characterized using scanning electron microscopy, energy-dispersive spectroscopy, X-ray diffraction, and selective Fe extraction. Although neither of the methods produced a completely crystalline Fe coating, the precipitation method produced sands with larger portions of amorphous Fe than the adsorption method, with the fraction of amorphous Fe decreasing with increasing Fe content. Uranium(VI) adsorption isotherms and pH adsorption edges were measured on three coated sands with Fe contents ranging from 0.04% to 0.3%. Experimentally, the adsorption of U(VI) onto the three sands was more comparable when normalized to surface area than when normalized to Fe content. A surface complexation model, although originally developed for U(VI) adsorption onto amorphous Fe oxide, captured the differences in adsorption when adjusted for the surface area of the coated sand. The findings indicate that surface area is a better scaling parameter than Fe content in predicting U(VI) adsorption to Fe-dominated media. These findings are significant because many common surface complexation models are parameterized on the basis of Fe content rather than specific surface area. Although the interactions of U(VI) and Fe-coated sands were used as representative adsorbate and adsorbent, the general principles may be applicable to other adsorbate–adsorbent systems as well.     

The 2007 Aurigid meteor outburst

A rare outburst of the Aurigid meteor shower was predicted to occur on 2007 September 1 at 11:36 ± 20 min  ut due to Earth's encounter with the one-revolution dust trail of long-period comet C/1911 N1 (Kiess). The outburst was predicted to last ∼1.5 h with peak zenithal hourly rate of ∼200 h⁻¹, which is ∼20 times higher than the annual Aurigid shower. Three members of Armagh Observatory observed this outburst from the general area of San Francisco, CA, USA, where the shower was anticipated to be best seen. Observed radiant, velocity and activity peak time were consistent with the predictions, whereas the zenithal hourly rate was about half of the predicted value. Five Aurigids were observed by two stations simultaneously, enabling their spatial trajectory to be worked out. The orbits of these double station meteors are in good agreement with that of their parent comet Kiess. The outburst was abundant in bright (−2 to +1 mag) meteors. The first high-altitude Aurigid, with a beginning height of 137.1 km, was recorded.     

Responses of Two New Hampshire (USA) Lakes to Human Impacts in Recent Centuries

This study contrasts the effects of human disturbances on two very different lake/catchment systems: Hatch Pond and Beaver Lake, New Hampshire. Hatch is in a steep mountain catchment remote from urban/industrial centers, and is a small, relatively deep, primarily seepage lake with moderate flushing rate. The catchment has been continuously forested, but disturbed by partial loggings and a forest fire. Beaver’s more extensive and gently sloping catchment is much closer to urban/industrial centers, and has been agricultural and recently suburban. Beaver is a larger but shallower drainage lake with much more rapid flushing than Hatch. We compared the sedimentary records and inferred limnological responses to catchment land uses and air pollution inputs of these mesotrophic lakes, and interpreted differing responses as a function of basic differences between the lakes and their catchments. Some chemical and biological variables in the sediment of both lakes respond sensitively to the first disturbances of the catchments by Euro-American settlers. Diatom-inferred Cl at both lakes indicates a modest increase of salinity at this time. Hatch sediment contains a record of soil erosion starting 1810 with first logging and fire. For ~125 years, erosion was largely of upper eluviated soil, but by 1935 it reached deeper into the illuviated (enriched) horizon. Maximal lake trophic state based on diatom-inferred limnological variables occurred in the mid-1900’s period of maximum sedimentation of illuviated soil. The sediment record since 1964 reflects forest maturation, and soil stabilization and acidification, but not lake acidification. At Beaver, the limnological effects of forest clearance and agriculture starting ~1700 were relatively mild due to gentleness of slopes and soil characteristics favoring stability. A near doubling of earth elements, and major increases in trace metal pollutants and coal combustion particles (CCP) occurred in sediment dating around 1900. Landscape analysis as well as historical and sedimentary records preclude the catchment as the major source of these increases. The most likely source is atmospheric fallout of CCP with its metal load. Despite controls on CCP and other emissions starting 1960, concentrations of earth elements and trace metals in Beaver sediment remain high due to soil mobilization by residential development of the catchment. The trophic state of Beaver Lake has increased, but the relative increase has been smaller than at Hatch, despite more intensive land uses and greater aerial inputs at Beaver. We propose that this lesser eutrophication is due to rapid flushing of Beaver Lake with stream water from relatively undeveloped parts of the extensive catchment, and lower sensitivity to nutrient inputs of this naturally more eutrophic lake. A major shift from unicellular to colonial chrysophytes at Hatch starts in the late-1800’s, and at Beaver in the early 1900’s. Colonial taxa in lesser quantities appear at the time of first settlement of the Beaver catchment. At both lakes the shifts are correlated with increasing metal fluxes from the opening of catchment biogeochemical cycles, as with the aforementioned erosional sequence at Hatch. But at Hatch aerial inputs of trace metals, and at Beaver aerial inputs major and trace metals associated with CCP are also correlated with the major chrysophyte shift. It appears that the chrysophytes have responded to stressors associated with both catchment disturbance and regional atmospheric inputs.