Interactions among metals in the spectrochemical determination of trace amounts of cadmium in marine mussels

The determination of trace amounts of inorganic elements by electrothermal atomic absorption spectrophotometry (ETA-AAS) or inductively coupled plasma atomic emission spectrometry (ICP-AES) suffers from some kinds of interference due to the inorganic fraction of the matrix of many environmental samples. The ratio between a major matrix element and the analyzed trace element plays an important role in the spectrochemical behaviour of the latter. The resulting enhancing or depressing effect also gives rise to severe faults when the well known standard addition method (SAM) is used. The present work shows the interactions due to the presence of elements such as calcium, sodium, potassium, magnesium and iron during the spectrochemical determinations of trace amounts of cadmium in marine mussels. A possible liquid anion exchange extraction is suggested for the analysis of cadmium by ETA-AAS.     

The Mid-atlantic Ridge (31°S–34°30′S): Temporal and spatial variations of accretionary processes

The ridge located between 31° S and 34°30′S is spreading at a rate of 35 mm yr⁻¹, a transitional velocity between the very slow (≤20 mm yr⁻¹) opening rates of the North Atlantic and Southwest Indian Oceans, and the intermediate rates (60 mm yr⁻¹) of the northern limb of the East Pacific Rise, and the Galapagos and Juan de Fuca Ridges. A synthesis of multi-narrow beam, magnetics and gravity data document that in this area the ridge represents a dynamically evolving system. Here the ridge is partitioned into an ensemble of six distinct segments of variable lengths (12 to 100 km) by two transform faults (first-order discontinuities) and three small offset (< 30 km) discontinuities (second-order discontinuities) that behave non-rigidly creating complex and heterogeneous morphotectonic patterns that are not parallel to flow lines. The offset magnitudes of both the first and second-order discontinuities change in response to differential asymmetric spreading. In addition, along the fossil trace of second-order discontinuities, the lengths of abyssal hills located to either side of a discordant zone are observed to lengthen and shorten creating a saw-toothed pattern. Although the spreading rate remains the same along the length of the ridge studied, the morphology of the spreading segments varies from a deep median valley with characteristics analogous to the rift segments of the North Atlantic to a gently rifted axial bulge that is indistinguishable from the shape and relief of the intermediate rate spreading centers of the East Pacific Rise (i.e., 21°N). Like other carefully surveyed ridge segments at slow and fast rates of accretion, the along-axis profiles of each ridge segment are distinctly convex upwards, and exhibit along-strike changes in relief of 500m to 1500 between the shallowest portion of the segment (approximate center) and the segment ends. Such spatial variations create marked along-axis changes in the morphology and relief of each segment. A relatively low mantle Bouguer anomaly is known to be associated with the ridge segment characterized by a gently rifted axial bulge and is interpreted to indicate the presence of focused mantle upwelling (Kuo and Forsyth, 1988). Moreover, the terrain at the ends of each segment are known to be highly magnetized compared to the centers of each segment (Carbotte et al, 1990). Taken together, these data clearly establish that these profound spatial variations in ridge segment properties between adjoining segments, and along and across each segment, indicate that the upper mantle processes responsible for the formation of this contrasting architecture are not solely related to passive upwelling of the asthenosphere beneath the ridge axis. Rather, there must be differences in the thermal and mechanical structure of the crust and upper mantle between and along the ridge segments to explain these spatial variations in axial topography, crustal structure and magnetization. These results are consistent with the results of investigations from other parts of the ridge and suggest that the emplacement of magma is highly focused along segments and positioned beneath the depth minimum of a given segment. The profound differences between segments indicate that the processes governing the behavior of upwelling mantle are decoupled and the variations in the patterns of axis flanking morphology and rate of accretion indicate that processes controlling upwelling and melt production vary markedly in time as well. At this spreading rate and in this area, the accretionary processes are clearly three-dimensional. In addition, the morphology of a ridge segment is not governed so much by opening rate as by the thermal structure of the mantle which underlies the segment.     

Multipole expansions for wave diffraction and radiation in deep water

A multipole expansion of the velocity potential is described for two- and three-dimensional wave diffraction and radiation problems. The velocity potential is expressed in terms of a series of multipole potentials. The wave terms and the local disturbance terms are represented by separated multipole potentials. Floating bodies and submerged bodies are treated in the same way. This approach differs from that of some other authors, who considered floating bodies and submerged bodies separately and derived entirely different multipoles. Semi-analytical solutions for a circular cylinder in two-dimensional motions are given. It is found that the local disturbance decays rapidly and steadily. The general application of the multipole expansion to arbitrary geometries is also presented, based on a method coupling multipoles to a boundary integral expression. Numerical results for several floating and submerged cylinders are presented.     

Seasonal methyltin and (3-dimethylsulphonio)propionate concentrations in leaf tissue of Spartina alterniflora of the Great Bay estuary (NH)

Concentrations of total recoverable inorganic tin (TRISn), monomethyltin (MeSn³⁺), dimethyltin (Me₂Sn²⁺), trimethyltin (Me₃Sn⁺) and (3-dimethylsulphonio)propionate (DMSP) were determined in leaves of Spartina alterniflora from three sites in the Great Bay estuary (NH) from 8 May to 15 September 1989. Total methyltin concentration increased from 8·9 ng g⁻¹ (fresh weight) on 8 May to 472 ng g⁻¹ on 23 May, decreased to 52 ng g⁻¹ on 7 June and 16ng g⁻¹ on 20 June, and remained low until the last sample on 18 September. Statistical calculations showed that methyltin concentrations varied significantly with sampling week, but not with site. DMSP concentrations showed very different behaviour. During the same sampling period DMSP concentrations varied only from 7·5 to 26 μmol g⁻¹ (fresh weight). DMSP concentrations varied significantly for site, but not sampling week.     

Trophodynamic phasing in theoretical,experimental aud natural pelagic ecosystems

It is a great honour to be awarded the Oceanographical Society of Japan Prize for 1988 and to be provided with this opportunity to review our work on trophic relations in the pelagic environment of the sea. Many Japanese colleagues have participated in Canada on our experiments. These persons include Drs. H. Seki, M. Takahashi, A. Hattori, T. Ikeda, I. Koike, M. Ohtsu, S. Ichimura, K. Iseki, E. Matsumoto, N. Handa, Y. Maita, and others without whom our work on marine ecosystems would have assumed much less importance. In addition, the visit of Professor M. Uda to Nanaimo in 1959, and his lectures on fisheries oceanography, have always been an inspiration to me in the practical application of oceanography. For me, work on trophodynamic relationships grew out of my early association with Dr. J.D.H. Strickland who initiated some ecosystem studies using large plastic bags in the 1960s (Strickland and Terhune, 1961; Strickland, 1967). The CEPEX program (e.g. Parsons, 1978), which was started about a decade later, gave us the first real opportunity to break away from laboratory studies, where only species which generally grew best were studied, and to perform studies under near natural conditions on multiorganism communities. The purpose of this program was to provide some answers to practical problems as well as to gain a fundamental understanding of biological oceanographic processes. This program was started at a time when a large number of stories were circulating (e.g. Heyerdahl, 1975) that man was about to kill life in the oceans through pollution. In a practical sense what I believe that the CEPEX program showed was that the oceans were much more resilient than had been supposed. The effect of many kinds of pollutants tested during this program was to change the course of ecosystem interactions but not to cause the elimination of life. The scientific value of these experiments went much further in giving us time series data about how the physical/chemical environment interacts with different trophic levels. For the first time, the biological oceanographer was liberated from the hopeless entanglement of time and space in the sea, and it was now possible to follow population dynamics of planktonic organisms (Mullin, 1982). Presented at the annual meeting, Tokyo, 4 April 1988.     

Interference fringes on GLORIA side-scan sonar images from the Bering Sea and their implications

GLORIA side-scan sonographs from the Bering Sea Basin show a complex pattern of interference fringes sub-parallel to the ship's track. Surveys along the same trackline made in 1986 and 1987 show nearly identical patterns. It is concluded from this that the interference patterns are caused by features in the shallow subsurface rather than in the water column. The fringes are interpreted as a thin-layer interference effect that occurs when some of the sound reaching the seafloor passes through it and is reflected off a subsurface layer. The backscattered sound interferes (constructively or desctructively) with the reflected sound. Constructive/destructive interference occurs when the difference in the length of the two soundpaths is a whole/half multiple of GLORIA's 25 cm wavelength. Thus as range from the ship increases, sound moves in and out of phase causing bands of greater and lesser intensity on the GLORIA sonograph. Fluctuations (or wiggles) of the fringes on the GLORIA sonographs relate to changes in layer thickness. In principle, a simple three dimensional image of the subsurface layer may be obtained using GLORIA and bathymetric data from adjacent (parallel) ship's tracks. These patterns have also been identified in images from two other systems; SeaMARC II (12 kHz) long-range sonar, and TOBI (30 kHz) deep-towed sonar. In these, and other cases world-wide, the fringes do not appear with the same persistence as those seen in the Bering Sea.     

Particulate flux in the water column overlying Santa Monica Basin

Fluxes of particulate carbon, nitrogen, phytoplankton pigments, biogenic silica and dry mass were measured using free-floating and moored sediment trap arrays in the Santa Monica Basin during the period from October 1985 to August 1990 as part of the California Basin Study (CaBS) Program. In field testing for potential sources of sediment trap biases, we found little significant or consistent difference in rate estimates between short-term drifting traps and long-term moored traps, between preserved and unpreserved traps in short-term experiments, between different preservatives (mercury or formalin) in long-term experiments, between different designs of small cylindrical traps, and between deep-moored cylindrical traps and large conical traps. We did, however, find that sediment trap samples collected and analyzed on 0.45 μm silver filters gave estimates of carbon and nitrogen fluxes about 25% higher than samples collected on GF/F glass-fiber filters. Concurrent trap deployments at two stations 18km apart revealed low mesoscale variability in flux estimates. Seasonal patterns in carbon and nitrogen flux were not evident in our data, but strong seasonality, with spring maxima and summer minima, were observed for fluxes of phaeopigments and biogenic silica out of the euphotic zone.Time-averaged rates of particulate flux for long-term trap deployments from January to August 1990, were 121, 18.8, 1.5, 67 and 633mg m⁻²d⁻¹ at 110–135m for carbon, nitrogen, phaeopigment, biogenic silica and mass, respectively. Flux estimates to the basin floor (835–860m) were 50, 6.5, 0.64, 41.6 and 575mg m⁻²d⁻¹ for the same parameters. The former estimates are constrained by and in good agreement with independent assessments of new production from nitrate uptake in the euphotic zone. The latter agree with rates previously inferred from the sedimentary record using ²¹⁰Pb as a tracer. In addition, the difference in carbon estimates in the water column between the euphotic zone and the basin floor is consistent with the requirements for bacterial growth and metabolism at intermediate depths as measured by the thymidine method.     

Trace metal concentrations in sediments of the Eastern Mississippi Bight

Sediments collected from 3 onshore-offshore transects (12 stations total) in the Eastern Mississippi Bight at 5 different times during 1987–1988 have been analyzed for total Ag, As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Se, Sn, Th and Zn. The data show considerable variation both spatially and temporally, largely as a result of natural variability in grain size and mineralogy. Clay-rich samples from deep water were always more metal-rich than sandy samples from shallow areas. Many samples from near the Mississippi River Delta appeared to be enriched in Ba by about a factor of two, probably as a result of contamination from oil well drilling mud, but there were few other indications of pollution influences. Many samples from throughout the area gave Mn/Fe and Cd/Fe ratios a factor of two or more lower than their Mississippi River source material. This shows that biochemical activity in the sediment is capable of solubilizing reducible and adsorbed metals.     

The role of organic coatings in the enrichment of marine particles with selenium. The fixation of selenite on an adsorbed amino acid

The enrichment of marine particles with selenium cannot be explained as that with metals present in cationic form by complexation with anionic functional groups of adsorbed organic matter. Physicochemical data obtained using a model system are reported. The surface of the particles is modelized by a mercury electrode whose surface charge density can be easily changed, covered by a layer of adsorbed polymers. Studies with different kinds of macromolecules and salts show a specific interaction between adsorbed polyalanine and selenite. The results can be explained by the concordance of the distances between two oxygen atoms in this oxyanion and between two amine groups of the adsorbed polypeptide. A similar mechanism could occur in marine aggregates whatever their nature, as long as they contain amine groups at their surface which result in this concordance. Some prospects derived from the results are discussed.     

Whitefish wars: Pangasius, politics and consumer confusion in Europe

Rapid growth in production of the farmed Vietnamese whitefish pangasius and its trade with the European Union has provoked criticism of the fish's environmental, social and safety credentials by actors including WWF and Members of the European Parliament and associated negative media coverage. This paper reviews the range of claims communicated about pangasius (identified as a form of mass mediated risk governance), in light of scientific evidence and analysis of data from the EU's Rapid Alert System for Food and Feeds food safety notification system for imported seafood. This analysis shows pangasius to be generally safe, environmentally benign and beneficial for actors along the international value chains that characterise the trade. The case is made that increasingly politicised debates in Europe around risk and uncertainty are potentially counterproductive for EU seafood security and European aquaculture industry, and that the trade in pangasius can contribute to sustainable seafood consumption in a number of ways. Transparent evidence-based assessment and systems for communicating complex issues of risk for products such as pangasius are required in order to support continuance of fair and mutually beneficial trade.