A large methane plume east of Bear Island (Barents Sea): implications for the marine methane cycle

A pockmark field extending over 35 km² at 74°54N, 27°3E, described by Solheim and Elverhøi (1993), was re-surveyed and found to be covered with more than 30 steep-sided craters between 300 and 700 m in diameter and up to 28 m deep. The craters are thought to have been formed by an explosive gas eruption. Anomalously high concentrations of methane in the shelf waters around the craters suggest that a strong methane source near this area is still active today. Methane enrichment more than 10 km away from the crater field indicates the large dimensions of a plume and the amount of gas released from sources below the seafloor of the Barents Sea shelf. From the characteristic vertical decrease of methane towards the sea surface, it is concluded that biota are extensively using this energy pool and reducing the methane concentration within the water column by about 98% between 300 m depth and the sea surface. Degassing to the atmosphere is minimal based on the shape of the methane concentration gradient. Nevertheless, the net flux of methane from this area of the Barents Sea is about 2.9 × 10⁴ g CH₄ km^–2 yr^–1 and thus in the upper range of the presently estimated global marine methane release. This flux is a minimum estimate and is likely to increase seasonally when rough weather leads to more effective vertical mixing during autumn and winter. The amount of methane consumed in the water column, however, is about 50 times greater and hence should significantly contribute to the marine carbon inventory.     

Sedimentary environment dynamics and the formation of coal in the Pennsylvanian Variscan foreland in the Ruhr Basin (Germany, Western Europe)

During the Pennsylvanian, formation of coal was a phenomenon that was spread over many continents. It is the aim of this paper to illustrate factors that led to the formation of coal seams in paralic clastic sedimentary environments in the Ruhr Basin (German Variscan foreland) during the Pennsylvanian in terms of sequence stratigraphy and the structural evolution of the basin. Lithostratigraphic sections from exploration wells in the currently explored zone of the coal basin allowed the generation of volumetric lithofacies models, using geostastical methods. These models support the analysis of sedimentary facies and a sequence stratigraphic interpretation of the successions that are widely correlated throughout the basin. We then evaluate the relation of the sequence stratigraphic elements derived from the facies models with the abundance of coal seams.     

The Geometric Spreading of Coronal Plumes and Coronal Holes

The geometric spreading in plumes and in the interplume region in coronal holes is calculated, using analytic and numerical theoretical models, between 1.0 and 5.0 R. We apply a two-scale approximation that permits the rapid local spreading at the base of plumes (f_l) to be evaluated separately from the global spreading (f_g) imposed by coronal hole geometry. We show that f_l can be computed from a potential-field model and f_g can be computed from global magnetohydrodynamic simulations of coronal structure. The approximations are valid when the plasma beta is small with respect to unity and for a plume separation small with respect to a solar radius.     

Planetary waves on the Sun?

Some recent observations of the Sun suggest a class of wave-like motions moving both eastward and westward at a uniform velocity with respect to the mean solar angular velocity. It is suggested that these may be hydromagnetic planetary waves. An estimate of the mean toroidal magnetic field is made, based on a theoretical treatment of such waves already in the literature, and a slight correction to the mean rate of rotation of the Sun is inferred.     

Phosphate regeneration from sediments of the Peru continental margin by dissolution of fish debris

Generally, oxidative regeneration of phosphate from anoxic sediments is by microbially mediated sulfate reduction processes. Stoichiometric modelling of such reactions takes into consideration varying proportions of ‘decomposable’ organically bound P to account for the ratios among nutrients in depth-concentration profiles of near-surface sediments. New results of interstitial water composition from sediments underlying the water masses influenced by coastal upwelling of the eastern boundary current system off Peru indicate that dissolution of phosphatic fish debris represents a mechanism for remineralization of phosphate comparable to or larger in magnitude than that by oxidative regeneration of organically bound P.Dissolved interstitial phosphate from fish debris is revealed by an excess amount of phosphate over that predicted from a simple stoichiometric oxidative regeneration model and by anomalously high dissolved interstitial fluoride concentrations. Phosphate flux estimates based on diffusion from the sediment suggest that this mechanism may generate up to 10% of the nutrient pool in the waters of the Peru undercurrent. Partitioning of P among the two sources reveals further that fish debris phosphate is about four times more important than organically bound P in nutrient generation from sediments of the Peru continental margin. Not only does this mechanism of regeneration affect the nutrient cycling but may also control widespread phosphorite formation in this area.     

Magnesium in the marine sedimentary environment: Mg---NH4 ion exchange

The release of exchangeable Mg in marine sediments from displacement by ammonium ions was estimated by way of experimentally determining the parameters that govern this ion-exchange equilibrium on solid geochemical phases: smectite, humic acid, illite and opal.

We showed that: (a) both the conditional selectivity constant as well as the solid concentration are important parameters in determining the relative contribution of ammonium-exchangeable Mg from smectite, organic matter, illite and opal; and (b) that, except in the cases where opal or organic matter concentrations are very high, the clays are the dominant carrier phases for labile Mg which is exchangeable by ammonium.

A model, based on the sum of the contributions from the major geochemical phases present in the sediment reliably predicts the amount of Mg released by exchange with ammonium in marine sediments.